benzyl 2,2,3,3-tetrafluoropropyl sulfide | 205521-85-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyl 2,2,3,3-tetrafluoropropyl sulfide
• 英文别名: Benzyl 2,2,3,3-tetrafluoropropyl sulphide；2,2,3,3-tetrafluoropropylsulfanylmethylbenzene
• CAS: 205521-85-3
• 化学式: C₁₀H₁₀F₄S
• mdl: MFCD00841265
• 分子量: 238.249
• InChiKey: YSIJRFWDPJAZBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  benzyl 2,2,3,3-tetrafluoropropyl sulfide 在 phosphorus pentoxide 作用下， 以90%的产率得到2,2,3,3-tetrafluoropropyl mercaptan
  参考文献：
  名称：

  含氟硫醇和硫酰卤的合成及反应性

  摘要：

  提出了在五氧化二磷作用下通过苄基多氟烷基硫化物的热裂解制备α-氢多氟烷硫醇和多氟硫酰卤的路线。获得的硫醇用作合成α-氢多氟烷亚磺酰氯的原料。研究了所得含 F,S 化合物的性质。

  DOI：

  10.1007/s11172-006-0399-4
• 作为产物：
  描述：

  对甲苯磺酸四氟丙酯 、 苄硫醇 在 sodium hydroxide 作用下， 生成 benzyl 2,2,3,3-tetrafluoropropyl sulfide
  参考文献：
  名称：

  三种部分氟化的链烷磺酸的合成作为潜在的燃料电池电解质

  摘要：

  DOI：

  10.1021/je00025a039

文献信息

• 1,1-Dichloropolyfluoroalkanesulfenamides and Their Dehydrochlorination Effected by Triethylamine
  作者：V. M. Timoshenko、A. V. Rudnichenko、A. V. Tkachenko、Yu. G. Shermolovich

  DOI：10.1007/s11178-005-0155-5

  日期：2005.2

  Reactions of 1,1-dichloropolyfluoroalkanesulfenyl chlorides with ammonia afford 1,1-dichloropolyfluoroalkanesulfenamides that under the action of triethylamine are converted into 3,5-bispolyfluoroalkyl-1,2,4-thiadiazoles.

  1,1-Dichloropolfluoroalkanesulfenyl chlorides 与氨反应生成 1,1-Dichloropolfluoroalkanesulfenamides，在三乙胺的作用下转化为 3,5-双聚氟烷基-1,2,4-噻二唑。
• Asymmetric induction in thia-Diels-Alder reactions of chiral polyfluoroalkylthionocarboxylates
  作者：Vadim M. Timoshenko、Sergiy A. Siry、Alexander B. Rozhenko、Yuriy G. Shermolovich

  DOI：10.1016/j.jfluchem.2009.11.011

  日期：2010.2

  A series of chiral S- or O-alkyl thionoesters have been synthesized by treatment of trifluorothioacetyl- or 2,2,3,3-tetrafluorothiopropionyl chloride with corresponding thiols or alcohols. The thia-Diels-Alder reaction of the thionoesters with symmetrical 1,3-dienes proceeds with diastereoselectivity up to 60%. Structures of cycloaddition products and corresponding transition states have been studied at the DFT level of approximation. The experimentally observed diastereomeric excess has been referred to differences in activation energies of transition states, preceding formation of the diastereomeric cycloaducts. (C) 2009 Elsevier B.V. All rights reserved.
• Shermolovich; Timoshenko; Listvan, Russian Journal of Organic Chemistry, 1998, vol. 34, # 8, p. 1112 - 1116
  作者：Shermolovich、Timoshenko、Listvan、Markovskii

  DOI：——

  日期：——
• Synthesis of three partially fluorinated alkanesulfonic acids as potential fuel-cell electrolytes
  作者：Chaiyun Bunyagidj、Hanna Piotrowska、Mary H. Aldridge

  DOI：10.1021/je00025a039

  日期：1981.7
• Synthesis and reactivity of fluorine-containing thiols and thioacyl halides
  作者：A. Yu. Sizov、A. N. Kovregin、R. N. Serdyuk、M. V. Vorob’ev、V. A. Porosyatnikov、A. A. Tsvetkov、D. O. Korneev、A. F. Ermolov

  DOI：10.1007/s11172-006-0399-4

  日期：2006.7

  α-hydropolyfluoroalkanethiols and polyfluorothioacyl halides via thermal splitting of benzyl polyfluoroalkyl sulfides under the action of phosphorus pentoxide was proposed. The thiols obtained were used as starting materials for the synthesis of α-hydropolyfluoroalkanesulfenyl chlorides. The properties of the resulting F,S-containing compounds were studied.

  提出了在五氧化二磷作用下通过苄基多氟烷基硫化物的热裂解制备α-氢多氟烷硫醇和多氟硫酰卤的路线。获得的硫醇用作合成α-氢多氟烷亚磺酰氯的原料。研究了所得含 F,S 化合物的性质。