o-bensoic acid | 57617-72-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-bensoic acid
• 英文别名: o-(di(p-tolyl)arsino)benzoic acid；o-Di(p-tolyl)arsino-benzoic acid；2-bis(4-methylphenyl)arsanylbenzoic acid
• CAS: 57617-72-8
• 化学式: C₂₁H₁₉AsO₂
• 分子量: 378.302
• InChiKey: PTXUTXOPOFBGBU-UHFFFAOYSA-N

物化性质

• 沸点：
  482.8±45.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.52
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  o-bensoic acid 在 三氯化磷 作用下， 以 氯仿 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  Parmar, Swarn S.; Bathla, Harinder K.; Saluja, Harveen K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1990, vol. 29, # 5, p. 405 - 406

  摘要：

  DOI：

文献信息

• Stabilisation of copper(II) tertiary-phosphine or -arsine complexes—II. Role of inductive effect and reaction conditions in stabilising copper(II)-arsine complexes of hybrid oxygen-arsenic ligands from o-R2AsC6H4CO2H
  作者：Swarn S. Parmar、Harkeerat K. Bharaj、Manohar L. Sehgal

  DOI：10.1016/s0277-5387(00)84064-4

  日期：1985.1

  Abstract The characterization of the products of reactions between anhydrous/hydrated copper(II) acetate and the title acids having R = Me, C6H11, Ph and p-tolyl in different solvents and at different temperatures with the help of elemental analysis, TGA, DTA, room temperature magnetic susceptibility, IR, and UV-VIS and EPR spectral data reveal that a competition exists between the chelation of arsine

  摘要借助元素分析，TGA，DTA表征了在不同溶剂和不同温度下无水/水合乙酸铜（II）与标题酸R = Me，C6H11，Ph和对甲苯基之间的反应产物，室温磁化率，IR，UV-VIS和EPR光谱数据表明，在一侧side与铜（II）的螯合与铜（II）还原为铜（I）及其后续反应之间存在竞争rs与铜（I）的螯合和/或oxide氧化铁与铜（II）的螯合。 预期通常由基团R的诱导作用控制的竞争被反应条件的改变所干扰，从而得出结论：反应条件而不是基团R的诱导作用控制了反应方式。
• Metal complexes of hybrid oxygen-arsenic ligands—III
  作者：Swarn S. Parmar、Harkeerat Kaur

  DOI：10.1016/s0277-5387(00)81047-5

  日期：1982.1
• Parmar, Swarn S.; Bathla, Harinder K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 12, p. 1035 - 1038
  作者：Parmar, Swarn S.、Bathla, Harinder K.

  DOI：——

  日期：——
• Metal Complexes of Hybrid Oxygen- Arsenic Ligands-VII IR, Reflectance and EPR Spectral Studies of Oxo-manganese (II)-Arsine Complexes Using Ligands from o-R2AsC6H4CO2H
  作者：S.S. Parmar、A. Aggarwal、M. L. Sehgal、Midas Tsai、S. Mittal

  DOI：10.13005/ojc/360106

  日期：2020.2.28

  This paper describes four oxo-manganese(II)-mono-tertiary arsine complexes: [Mn2O[(o-Ph2AsC6H4CO2)(2)(H2O)(5)}center dot(H2O)(structure:4), [Mn-2(o-Ph2AsC6H4CO2)(2)(H2O)(4)], and two isomeric compounds of [Mn2O((o-(p-tolyl)(2)AsC6H4CO2)(2)}center dot(H2O)(4)] (structure 5) by reacting Mn(O2CMe)(3). nH(2)O, (where "n" represents the number of water molecules, n=0 and n= 4) with the ligands o-R2As C6H4CO2H having only the aryl substituents (R=Ph, p-tolyl). This work extends the argument further that deoxygenated anhydrous conditions are not a prerequisite to stabilize As(III)-Mn(II) bond with the hybrid (As-O) chelates. The prepared complexes were characterized by IR, reflectance and EPR spectral studies and were confirmed by elemental analysis and thermogravimetric studes br their structures.