benzoyl-phenylacetyl peroxide | 16644-08-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzoyl-phenylacetyl peroxide
• 英文别名: Benzoyl-phenylacetyl-peroxid；Benzoyl-phenylacetyl-peroxyd；Benzoyl-phenylacetylperoxid；Benzyl-phenylacetyl-peroxid；Benzoylphenylacetylperoxid；Peroxide, benzoyl phenylacetyl；(2-phenylacetyl) benzenecarboperoxoate
• CAS: 16644-08-9
• 化学式: C₁₅H₁₂O₄
• 分子量: 256.258
• InChiKey: DWCDIJFGUYALMH-UHFFFAOYSA-N

物化性质

• 沸点：
  376.3±35.0 °C(Predicted)
• 密度：
  1.231±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  benzoyl-phenylacetyl peroxide 在 三乙基膦 作用下， 生成 mixed anhydride of benzoic acid and phenylacetic acid
  参考文献：
  名称：

  Horner; Jurgeleit, Justus Liebigs Annalen der Chemie, 1955, vol. 591, p. 138,151

  摘要：

  DOI：
• 作为产物：
  描述：

  过氧化氢苯甲酰 、 苯乙酰氯 在 吡啶 作用下， 以 正己烷 为溶剂， 生成 benzoyl-phenylacetyl peroxide
  参考文献：
  名称：

  Polar and radical paths in the decomposition of diacyl peroxides

  摘要：

  DOI：

  10.1021/ja00719a028

文献信息

• Wieland; Ploetz; Indest, Justus Liebigs Annalen der Chemie, 1937, vol. 532, p. 166,179, 186
  作者：Wieland、Ploetz、Indest

  DOI：——

  日期：——
• CHEMICAL FUNCTIONALIZATION OF CARBON NANOTUBES
  申请人：National Research Council of Canada

  公开号：EP1989143A1

  公开（公告）日：2008-11-12
• Chemical Functionalization of Carbon Nanotubes
  申请人：Martinez-Rubi Yadienka

  公开号：US20090306427A1

  公开（公告）日：2009-12-10

  The invention relates to a process for chemically functionalizing carbon nanotubes. The process comprises dispersing carbon nanotube salts in a solvent; and chemically functionalizing the carbon nanotube salts to provide chemically functionalized carbon nanotubes.
• Method for Functionalizating Carbon Naontubes Utilizing Peroxides
  申请人：Khabashesku Valery N.

  公开号：US20100222536A1

  公开（公告）日：2010-09-02

  A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.
• US4618647A
  申请人：——

  公开号：US4618647A

  公开（公告）日：1986-10-21