{Pten(CNS)2} | 20960-48-9

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: {Pten(CNS)2}
• CAS: 20960-48-9
• 化学式: C₄H₈N₄PtS₂
• 分子量: 371.346
• InChiKey: ZOFSPWRXASAIIX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Pten(CNS)2} 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Kukushkin, Yu. N.; Vrublevskaya, L. V.; Isachkina, T. S., Russian Journal of Inorganic Chemistry, 1982, vol. 27, p. 701 - 703

  摘要：

  DOI：
• 作为产物：
  描述：

  dipotassium tetrathiocyanatoplatinate(II) 、 乙二胺 以 not given 为溶剂， 生成 {Pten(CNS)2}
  参考文献：
  名称：

  Gruenberg, A. A., Izvestia Sektora platiny i drugih blagorodnyh metallov., 1928, vol. 6, p. 122 - 177

  摘要：

  DOI：

文献信息

• Gel'fman; Salishcheva, Russian Journal of Inorganic Chemistry, 2000, vol. 45, # 5, p. 707 - 709
  作者：Gel'fman、Salishcheva

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pt: MVol.D, 120, page 272 - 275
  作者：

  DOI：——

  日期：——
• Hantzsch, A.; Rosenblatt, F., Zeitschrift fur anorganische Chemie, 1930, vol. 187, p. 241 - 265
  作者：Hantzsch, A.、Rosenblatt, F.

  DOI：——

  日期：——
• Clark, Robin J. H.; Croud, Vincent B., Journal of the Chemical Society, Dalton Transactions, 1988, p. 73 - 78
  作者：Clark, Robin J. H.、Croud, Vincent B.

  DOI：——

  日期：——
• Structure of the mixed-valence platinum complexes [PtII(en)(SCN)2][PtIV(en)(SCN)2I2] and cis-[PtII(NH3)2(SCN)2][PtIV(NH3)2(SCN)2I2] studied by the method of radial distribution functions of atoms
  作者：V.I. Korsunsky、G.S. Muraveiskaya、A.A. Sidorov

  DOI：10.1016/s0020-1693(00)82973-4

  日期：1991.9

  Using the method of radial distribution functions of atoms obtained by Fourier transform of powder X-ray patterns it has been shown directly that the structures of the mixed-valence complexes cis-[Pt(II)(NH3)2(SCN)2][Pt(IV)(NH3)2(SCN)2I2] (I) and [Pt(II)(en)(SCN)2][Pt(IV)(en)(SCN)2I2] (II) (en = ethylenediamine) contain the linear chains ...I-Pt(IV)-I...Pt(II)...I-Pt(IV)-I...I-, wherein square-planar complexes of Pt(II) alternate with octahedral complexes of Pt(IV). Such a structure for I had earlier been proposed only on the basis of indirect spectroscopical data. The distances Pt(IV)-I and Pt(II)...I have been determined. The first one is 2.70 angstrom in both the complexes and the second is 3.50 angstrom in I and 3.23 angstrom in II. The distances Pt(II)...I are considerably longer than corresponding distances in the similar mixed-valence complex of known structure [Pt(II)(en)2][Pt(IV)(en)2I2](ClO4)4 (IV) (about 3.10 angstrom). The elongation of the Pt(II)...I contact corresponds to the smaller bridge role of I atoms in the thiocianate complexes, to the smaller electron delocalization over the chain of Pt and I atoms and, hence, to a more pronounced division of the system into true complexes of Pt(II) and Pt(IV) than in IV.