[2,6-(2,6-xylyl)2C6H3Li]2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [2,6-(2,6-xylyl)2C6H3Li]2
• 英文别名: (Li(C6H3-2,6-(C6H3-2,6-Me2)2)2；Lithium;2-[3-(2,6-dimethylphenyl)benzene-2-id-1-yl]-1,3-dimethylbenzene
• 化学式: 2C₂₂H₂₁*2Li
• 分子量: 584.699
• InChiKey: KVSABXCBCOQBJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.06
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [2,6-(2,6-xylyl)2C6H3Li]2 、 cadmium(II) chloride 以 四氢呋喃 、 甲苯 为溶剂， 反应 12.0h， 以19%的产率得到[2,6-(2,6-xylyl)2C6H3]2Cd
  参考文献：
  名称：

  Ligand influences on homoleptic Group 12 m-terphenyl complexes

  摘要：

  对两配位12族元素双萘基配合物的三个系列进行的分析突显出，特别是配体性质（尤其是立体效应）和在较小程度上的电子效应对所采用的固态结构产生了巨大影响。

  DOI：

  10.1039/c4dt00647j

文献信息

• Dehydrocoupling of dimethylamine–borane promoted by manganese(<scp>ii</scp>) <i>m</i>-terphenyl complexes
  作者：Helen R. Sharpe、Ana M. Geer、Toby J. Blundell、Fiona R. Hastings、Michael W. Fay、Graham A. Rance、William Lewis、Alexander J. Blake、Deborah L. Kays

  DOI：10.1039/c7cy02086d

  日期：——

  Two- and three-coordinate manganese m-terphenyl complexes are precatalysts for the dehydrogenation of dimethylamine–borane (Me2NH·BH3) affording one equivalent of molecular hydrogen and half an equivalent of [Me2N–BH2]2. Experimental studies into the nature of the catalyst indicate that small changes in the coordination environment give rise to significant differences in the reaction mechanism, occurring

  两个和三个坐标锰米三联苯络合物是二甲胺-硼烷的脱氢预催化剂（ME 2 NH·BH 3），得到一个分子氢的当量和一半当量[我的2的N- BH 2 ] 2。对催化剂性质的实验研究表明，配位环境的细微变化会引起反应机理的显着差异，这是通过两坐标预催化剂的均相机理发生的，而对于三坐标物种而言，则发生了异质机理。纳米颗粒负责催化。
• Synthesis and Reactivity of Dimeric Ar‘TlTlAr‘ and Trimeric (Ar‘ ‘Tl)₃ (Ar‘, Ar‘ ‘ = Bulky Terphenyl Group) Thallium(I) Derivatives:  Tl(I)−Tl(I) Bonding in Species Ligated by Monodentate Ligands
  作者：Robert J. Wright、Andrew D. Phillips、Shirley Hino、Philip P. Power

  DOI：10.1021/ja0432259

  日期：2005.4.1

  The synthesis and characterization of three new organothallium(I) compounds are reported. Reaction of (Ar'Li)(2) (Ar' = C6H3-2,6-(C6H3-2,6-Pr'(2))(2)) and Ar"Li (Ar" = C6H3-2,6-(C6H3-2,6-Me-2)(2)) with TICI in Et2O afforded (Ar'TI)(2) (1) and (Ar"TI)(3) (2). The "dithallene" 1 is the heaviest group 13 dimetallene and features a planar, trails-bent structure with Ar'TI-TI = 119.74(14)degrees and TI-TI = 3.0936(8) angstrom. Compound 2 is the first structurally characterized neutral, three-membered ring species of formula c-(MR)(3) (M = AI-TI; R = organo group). The TI3 ring has TI-TI distances in the range ca. 3.21-3.37 angstrom as well as pyramidal TI geometries. The TI-TI bonds in 1 and 2 are outside the range (2.88-2.97 angstrom) of TI-TI single bonds in R2TITIR2 compounds. The weak TI-TI bonding in 1 and 2 leads to their dissociation into Ar'TI and Ar"TI monomers in hexane. The Ar'TI monomer behaves as a Lewis base and readily forms a 1:1 donor-acceptor complex with B(C6F5)(3) to give Ar'TIB(C6F5)(3), 3. Adduct 3 features an almost linear thallium C(ipso)-TI-B angle of 174.358(7)degrees and a TI-B distance of 2.311(2) angstrom, which indicates strong association. Treatment of 1 with a variety of reagents resulted in no reactions. The lower reactivity of 1 is in accord with the reluctance of TI(I) to undergo oxidation to TI(III) due to the unreactive character of the 6s(2) electrons.