3-methylthiomethyloxy-1-adamantyl methacrylate

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: 3-methylthiomethyloxy-1-adamantyl methacrylate
• 英文别名: [3-(Methylsulfanylmethoxy)-1-adamantyl] 2-methylprop-2-enoate
• 化学式: C₁₆H₂₄O₃S
• 分子量: 296.431
• InChiKey: RDTXPUGHXMWVMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  60.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-羟基-1-金刚烷基甲基丙烯酸酯 、 二甲基亚砜 在 乙酸酐 、 4-甲氧基苯酚 作用下， 反应 48.0h， 以72.2%的产率得到3-methylthiomethyloxy-1-adamantyl methacrylate
  参考文献：
  名称：

  ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCING THE SAME, AND PHOTOSENSITIVE MATERIAL FOR PHOTORESIST

  摘要：

  本发明提供了一种新型的金刚烷衍生物，可用作产生功能性树脂的单体，例如用于光刻的光敏树脂，并提供了一种制备该衍生物的方法。该金刚烷衍生物具有由公式（I-a）表示的结构，制备该金刚烷衍生物的方法采用相应的金刚烷衍生物作为起始物质。在公式（I）中，R1代表H，CH3或CF3; R2a代表C1到C30烷基或含有C3到C30环烷基或C6到C30芳香基的碳氢基，该烷基或碳氢基具有杂原子; 每个X1和X2代表O或S; Y代表C1到C10烷基，卤素原子，OH或SH，或两个Y连接形成= O或= S; k表示0到14的整数; m和n各自是0到2的整数。

  公开号：

  EP1803708A1

文献信息

• Adamantane Derivative, Process for Producing the Same, and Photosensitive Material for Photoresist
  申请人：Hatakeyama Naoyoshi

  公开号：US20080009647A1

  公开（公告）日：2008-01-10

  The invention provides a novel adamantane derivative useful as a monomer for producing functional resins such as photosensitive resins particularly for use in lithography, and a method for producing the derivative. The adamantane derivative has a structure represented by formula (I-a) and the method for producing the adamantane derivative employs a corresponding adamantane derivative serving as a starting material. In formula (I), R 1 represents H, CH 3 , or CF 3 ; R 2a represents a C1 to C30 alkyl group or a hydrocarbon group containing a C3 to C30 cycloalkyl group or a C6 to C30 aryl group, the alkyl group or the hydrocarbon group having a hetero atom; each of X 1 and X 2 represents O or S; Y represents a C1 to C10 alkyl group, a halogen atom, OH, or SH, or two Ys are linked to form ═O or ═S; k represents an integer of 0 to 14; and each of m and n is an integer of 0 to 2.
• US7456311B2
  申请人：——

  公开号：US7456311B2

  公开（公告）日：2008-11-25
• ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCING THE SAME, AND PHOTOSENSITIVE MATERIAL FOR PHOTORESIST
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1803708A1

  公开（公告）日：2007-07-04

  The invention provides a novel adamantane derivative useful as a monomer for producing functional resins such as photosensitive resins particularly for use in lithography, and a method for producing the derivative. The adamantane derivative has a structure represented by formula (I-a) and the method for producing the adamantane derivative employs a corresponding adamantane derivative serving as a starting material. In formula (I), R1 represents H, CH3, or CF3; R2a represents a C1 to C30 alkyl group or a hydrocarbon group containing a C3 to C30 cycloalkyl group or a C6 to C30 aryl group, the alkyl group or the hydrocarbon group having a hetero atom; each of X1 and X2 represents O or S; Y represents a C1 to C10 alkyl group, a halogen atom, OH, or SH, or two Ys are linked to form =O or =S; k represents an integer of 0 to 14; and each of m and n is an integer of 0 to 2.

  本发明提供了一种新型的金刚烷衍生物，可用作产生功能性树脂的单体，例如用于光刻的光敏树脂，并提供了一种制备该衍生物的方法。该金刚烷衍生物具有由公式（I-a）表示的结构，制备该金刚烷衍生物的方法采用相应的金刚烷衍生物作为起始物质。在公式（I）中，R1代表H，CH3或CF3; R2a代表C1到C30烷基或含有C3到C30环烷基或C6到C30芳香基的碳氢基，该烷基或碳氢基具有杂原子; 每个X1和X2代表O或S; Y代表C1到C10烷基，卤素原子，OH或SH，或两个Y连接形成= O或= S; k表示0到14的整数; m和n各自是0到2的整数。