2,6-di(1-methyl-1H-imidazol-2-yl)isonicotinic acid | 600728-01-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,6-di(1-methyl-1H-imidazol-2-yl)isonicotinic acid
• 英文别名: 2,6-Bis(1-methylimidazol-2-yl)pyridine-4-carboxylic acid
• CAS: 600728-01-6
• 化学式: C₁₄H₁₃N₅O₂
• 分子量: 283.29
• InChiKey: GRSUBHRPTOCIFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  85.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  硬脂醇 、 2,6-di(1-methyl-1H-imidazol-2-yl)isonicotinic acid 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 以89%的产率得到octadecyl 2,6-di(1-methyl-1H-imidazol-2-yl)isonicotinate
  参考文献：
  名称：

  Synthesis of 4-functionalized terdendate pyridine-based ligands

  摘要：

  Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.

  DOI：

  10.1016/s0040-4020(03)00753-1
• 作为产物：
  描述：

  2,6-二溴吡啶-4-羧酸乙酯 在 四(三苯基膦)钯 氢氧化钾 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 14.0h， 生成 2,6-di(1-methyl-1H-imidazol-2-yl)isonicotinic acid
  参考文献：
  名称：

  Synthesis of 4-functionalized terdendate pyridine-based ligands

  摘要：

  Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.

  DOI：

  10.1016/s0040-4020(03)00753-1

文献信息

• PHOTOELECTRIC CONVERSION ELEMENT, PHOTOELECTROCHEMICAL CELL, AND METAL COMPLEX DYE USED THEREIN
  申请人：FUJIFILM Corporation

  公开号：US20140209172A1

  公开（公告）日：2014-07-31

  A photoelectric conversion element having a laminate structure including, provided on an electrically conductive support, a photoconductor layer having a layer of dye-adsorbed semiconductor fine particles, a charge transfer layer, and a counter electrode, wherein the dye is a metal complex dye represented by the following formula (1): M 1 L 1 L 2 Z 1 (1) wherein, in formula (1), M 1 represents a metal atom; Z 1 represents a monodentate ligand; L 1 represents a specific tridentate ligand; and L 2 represents a specific bidentate ligand.
• US9087642B2
  申请人：——

  公开号：US9087642B2

  公开（公告）日：2015-07-21
• Synthesis of 4-functionalized terdendate pyridine-based ligands
  作者：Tina Vermonden、Danuta Branowska、Antonius T.M Marcelis、Ernst J.R Sudhölter

  DOI：10.1016/s0040-4020(03)00753-1

  日期：2003.6

  Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine :group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. (C) 2003 Published by Fisevier Science Ltd.