2-hydroxyethyl ethyl-(2-hydroxyethyl)phosphinate | 53490-73-6

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: 2-hydroxyethyl ethyl-(2-hydroxyethyl)phosphinate
• 英文别名: 2,2'-(Ethylphosphinyliden)diethanol；2-[Ethyl(2-hydroxyethyl)phosphoryl]ethanol
• CAS: 53490-73-6
• 化学式: C₆H₁₅O₃P
• 分子量: 166.157
• InChiKey: IUEVEHOAFNLCTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-hydroxyethyl ethyl-(2-hydroxyethyl)phosphinate 、 六甲基二硅氮烷 在 三甲基氯硅烷 作用下， 生成 1-[Ethyl-(2-trimethylsilanyloxy-ethyl)-phosphinoyl]-2-trimethylsilanyloxy-ethane
  参考文献：
  名称：

  Valetdinov,R.K. et al., Journal of general chemistry of the USSR, 1977, vol. 47, p. 2020 - 2022

  摘要：

  DOI：
• 作为产物：
  描述：

  2,2'-(Ethylphosphiniden)diethanol 在 双氧水 作用下， 生成 2-hydroxyethyl ethyl-(2-hydroxyethyl)phosphinate
  参考文献：
  名称：

  Valetdinov,R.K.; Zaripov,Sh.I., Journal of general chemistry of the USSR, 1974, vol. 44, p. 1415 - 1417

  摘要：

  DOI：

文献信息

• Method for the production of monohydroxy-functionalized dialkylphosphinic acids, esters, and salts using ethylene oxide, and use thereof
  申请人：Hill Michael

  公开号：US08987490B2

  公开（公告）日：2015-03-24

  A method for producing monohydroxy-functionalized dialkylphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, b) the obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with alkylene oxides of formula (V) in the presence of a catalyst B to obtain a monofunctionalized dialkylphosphinic acid derivative (III), catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is a Lewis acid.

  一种生产单羟基功能化二烷基膦酸、酯和盐的方法，其特征在于a) 在催化剂A的存在下，将膦酸源(I)与烯烃(IV)反应，以获得烷基膦酸、其盐或酯(II)，b) 在催化剂B的存在下，将获得的烷基膦酸、其盐或酯(II)与化学式(V)的烷基氧化物反应，以获得单功能化的二烷基膦酸衍生物(III)，催化剂A代表过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物以及至少一种配体组成的催化剂系统，而催化剂B是一种路易斯酸。
• Flame-retardant flexible polyurethane foam
  申请人：Piotrowski Andrew M.

  公开号：US20090281205A1

  公开（公告）日：2009-11-12

  A flexible polyurethane foam-forming composition and the flexible polyurethane foam obtained therefrom contain, as flame-retardant additive, a halogen-free phosphonate compound which is substantially unreactive for isocyanate, contains at least about 5 weight percent phosphorus, has an acid value of about 2 mg KOH/g or less, a volatility as measured by thermogravimetric analysis not exceeding a 5.0 percent weight loss at a temperature of about 150° C., and a weight average molecular weight of from about 200 to about 2000.
• PHOSPHORUS-CONTAINING POLYCARBONATE POLYOL, METHOD FOR PRODUCTION THEREOF, AND PHOSPHORUS-CONTAINING POLYCARBONATE POLYURETHANE
  申请人：Takasawa Ryoichi

  公开号：US20100197887A1

  公开（公告）日：2010-08-05

  The phosphorus-containing polycarbonate polyol disclosed herein has a structural unit (I) represented by a formula: —OCOO— and a structural unit (II) represented by a residue A, wherein A denotes a n-valent residue in which n of alcoholic hydroxyl groups are removed from a phosphorus compound having at least n of alcoholic hydroxyl groups, in which n is an integer of 2 or larger, and wherein a terminal group of the polyol is a alcoholic hydroxyl group. The novel phosphorus-containing polycarbonate polyol, as a reactive flame-retardant agent, can provide flame-retardant properties easily to polyurethane or the like.
• US8058322B2
  申请人：——

  公开号：US8058322B2

  公开（公告）日：2011-11-15
• US8344096B2
  申请人：——

  公开号：US8344096B2

  公开（公告）日：2013-01-01