N,N'-bis-(4-methoxycarbonylbenzoyl)-1,4-butanediamine | 102810-33-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis-(4-methoxycarbonylbenzoyl)-1,4-butanediamine
• 英文别名: N,N'-butanediyl-bis-terephthalamic acid dimethyl ester；N,N'-Butandiyl-bis-terephthalamidsaeure-dimethylester；N,N'-Di(4-carbomethoxybenzoyl)-1,4-butanediamine；N,N'-Bis-(4-methoxycarbonyl-benzoyl)-tetramethylendiamin；Benzoic acid, 4,4'-[1,4-butanediylbis(iminocarbonyl)]bis-, dimethyl ester；methyl 4-[4-[(4-methoxycarbonylbenzoyl)amino]butylcarbamoyl]benzoate
• CAS: 102810-33-3
• 化学式: C₂₂H₂₄N₂O₆
• 分子量: 412.442
• InChiKey: OIPHSVWJGAJSDR-UHFFFAOYSA-N

物化性质

• 熔点：
  255-256 °C
• 沸点：
  662.2±50.0 °C(Predicted)
• 密度：
  1.213±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  30
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  111
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis-(4-methoxycarbonylbenzoyl)-1,4-butanediamine 在 potassium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 3.0h， 以99%的产率得到N,N'-bis-(4-carboxybenzoyl)-1,4-butanediamine
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES

  摘要：

  A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and tris-amides 4a-4e. The yields ranged from good to very good and showed that choosing the right acylating agent is a key point in this synthesis. All the compounds were characterized by elemental analysis, FTIR, and H-1 NMR.

  DOI：

  10.4067/s0717-97072012000300023
• 作为产物：
  描述：

  对甲酰基苯甲酸甲酯 在 4-二甲氨基吡啶 、 potassium permanganate 、 硫酸 、 三乙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 1,4-二氧六环 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 N,N'-bis-(4-methoxycarbonylbenzoyl)-1,4-butanediamine
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF BIS- AND TOS-(4-CARBOXYBENZOYL)-ALKANEAMINES

  摘要：

  A practical and efficient protocol to obtain bis- and tris-(4-carboxybenzoyl)alkaneamines based on monoprotected 1,4-benzenedicarboxylic acid is reported here. N-(4-methoxycarbonylbenzoyloxy)succinimide was treated with aliphatic diamines and triamines to form aliphatic hydrocarbon-linked bis- and tris-amides 4a-4e. The yields ranged from good to very good and showed that choosing the right acylating agent is a key point in this synthesis. All the compounds were characterized by elemental analysis, FTIR, and H-1 NMR.

  DOI：

  10.4067/s0717-97072012000300023

文献信息

• Stable amido peroxycarboxylic acids for bleaching
  申请人：Lever Brothers Company, Division of Conopco, Inc.

  公开号：US05268003A1

  公开（公告）日：1993-12-07

  An amido peroxyacid compound is provided having the formula: ##STR1## wherein R is selected from the group consisting of C.sub.1 -C.sub.12 alkylene, C.sub.5 -C.sub.12 cycloalkylene, C.sub.6 -C.sub.12 arylene and radical combinations thereof; R.sup.1 and R.sup.2 are independently selected from the group consisting of H, C.sub.1 -C.sub.16 alkyl and C.sub.6 -C.sub.12 aryl radicals and a radical that can form a C.sub.3 -C.sub.12 ring together with R.sup.3 and both nitrogens; R.sup.3 is selected from the group consisting of C.sub.1 -C.sub.12 alkylene, C.sub.5 -C.sub.12 cycloalkylene and C.sub.6 -C.sub.12 arylene radicals, and provided when R.sup.3 is arylene and when n' and m' are each zero, R is other than C.sub.5 alkylene; n and n' each are an integer chosen such that the sum thereof is 1; m and m' each are an integer chosen such that the sum thereof is 1; and M is selected from the group consisting of H, alkali metal, alkaline earth metal, ammonium, alkanolammonium cations and radicals and combinations thereof. The amido peroxyacid compound is useful for bleaching substrates such as stained laundry.

  提供一种具有以下式子的酰胺过氧酸化合物：##STR1## 其中，R被选择为由C.sub.1-C.sub.12烷基，C.sub.5-C.sub.12环烷基，C.sub.6-C.sub.12芳烃基和它们的基团组成的群体；R.sup.1和R.sup.2分别被选择为由H，C.sub.1-C.sub.16烷基和C.sub.6-C.sub.12芳基基团以及能够与R.sup.3和两个氮一起形成C.sub.3-C.sub.12环的基团组成的群体；R.sup.3被选择为由C.sub.1-C.sub.12烷基，C.sub.5-C.sub.12环烷基和C.sub.6-C.sub.12芳烃基团组成的群体，并且当R.sup.3是芳烃且n'和m'都为零时，R不是C.sub.5烷基；n和n'各自是选择的整数，使它们的和为1；m和m'各自是选择的整数，使它们的和为1；M被选择为由H，碱金属，碱土金属，铵，烷基铵阳离子和它们的基团组成的群体。该酰胺过氧酸化合物可用于漂白脏衣服等物质。
• Amido peroxycarboxylic acids for bleaching
  申请人：Lever Brothers Company, Division of Conopco, Inc.

  公开号：US05397501A1

  公开（公告）日：1995-03-14

  A bleaching composition and a method of using the same. The composition comprising: (i) from about 0.1 to about 50% by weight of an amido peroxyacid having the structure: ##STR1## wherein, R, R.sup.1, R.sup.2, R.sup.3, n, n', m, m', and M are as defined in the specification; and (ii) from about 0.5 to about 50% by weight of a surfactant.

  一种漂白组合物及其使用方法。该组合物包括：（i）约0.1至约50重量％的酰胺过氧酸，其具有结构式：##STR1## 其中，R，R.sup.1，R.sup.2，R.sup.3，n，n'，m，m'和M如规范中所定义；以及（ii）约0.5至约50重量％的表面活性剂。
• Copolyester amides
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0445548A1

  公开（公告）日：1991-09-11

  The invention deals with copolyester amides built up from units derived from terephtalic acid, 1,4-butane-diol and 1,4-butane diamine.

  本发明涉及由对苯二甲酸、1,4-丁二醇和 1,4-丁二胺衍生单元组成的共聚酯酰胺。
• Structured liquid detergent compositions containing amido and imido peroxy acids
  申请人：UNILEVER PLC

  公开号：EP0564250A2

  公开（公告）日：1993-10-06

  An aqueous cleaning composition is provided which includes an amido or imido organic peroxyacid having water solubility of less than 1 x 10⁻⁴M, a structuring surfactant and a pH-adjusting system for maintaining pH from 3.5 to 8.5 during storage and, upon dilution with a wash water, causing pH to rise by at least 0.5 pH units.

  本发明提供了一种水基清洁组合物，其中包括一种水溶性小于 1 x 10-⁴M 的氨基或亚氨基有机过氧酸、一种结构表面活性剂和一种 pH 值调节系统，用于在储存期间将 pH 值保持在 3.5 至 8.5 之间，并在用洗涤水稀释时使 pH 值上升至少 0.5 个 pH 单位。
• Amido peroxycarboxylic acids
  申请人：UNILEVER PLC

  公开号：EP0564251A2

  公开（公告）日：1993-10-06

  An amido peroxyacid compound is provided having the formula : wherein : R is selected from the group consisting of C1-C12 alkylene, C5-C12 cycloalkylene, C6-C12 arylene and radical combinations thereof ; R1 and R2 are independently selected from the group consisting of H, C1-C16alkyl and C6-C12 aryl radicals and a radical that can form a C3-C12 ring together with R3 and both nitrogens ; R3 is selected from the group consisting of C1-C12 alkylene, C5-C12 cycloalkylene and C6-C12 arylene radicals, and provided when R3 is arylene and when n' and m' are each zero, R is other than C5 alkylene ; n and n' each are an integer chosen such that the sum thereof is 1 ; m and m' each are an integer chosen such that the sum thereof is 1 ; and M is selected from the group consisting of H, alkali metal, alkaline earth metal, ammonium, alkanolammonium cations and radicals and combinations thereof. The amido peroxyacid compound is useful for bleaching substrates such as stained laundry.

  提供了一种酰胺基过氧酸化合物，其化学式为： 其中： R 选自由 C1-C12 亚烷基、C5-C12 环亚烷基、C6-C12 芳基及其自由基组合组成的组； R1 和 R2 独立地选自由 H、C1-C16 烷基、C6-C12 芳基以及能与 R3 和两个硝基一起形成 C3-C12 环的基组成的组； R3 选自 C1-C12 亚烷基、C5-C12 环亚烷基和 C6-C12 芳烯基组成的组，并且当 R3 为芳烯基，且 n' 和 m' 均为零时，R 不是 C5 亚烷基； n和n'各自为整数，其和为1； m和m'各自为整数，取其和为1；以及 M 选自 H、碱金属、碱土金属、铵、烷铵阳离子和自由基及其组合组成的组。 氨基过氧酸化合物可用于漂白染色衣物等基质。