1,3-di-O-oleoyl-2-O-palmitoylglycerol | 2190-24-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 1,3-di-O-oleoyl-2-O-palmitoylglycerol
• 英文别名: glycerol 1,3-distearate 2-palmitate；1,3-distearol-2-palmitoyl glycerol；1,3-dioctadecanoyl-2-palmitoyl-glycerol；TG(18:0/16:0/18:0)；2-Palmitoyloxy-1,3-bis-stearoyloxy-propan；α,α'-Distearoyl-β-palmitoin；2-palmitoyloxy-1,3-bis-stearoyloxy-propane；α-Palmitoyl-distearin；2-Palmito-distearin；OPO；1,3-Distearoyl-2-palmitoylglycerol；(2-hexadecanoyloxy-3-octadecanoyloxypropyl) octadecanoate
• CAS: 2190-24-1
• 化学式: C₅₅H₁₀₆O₆
• 分子量: 863.443
• InChiKey: ZGVGTPFSVCXVNJ-UHFFFAOYSA-N

物化性质

• 溶解度：
  氯仿：微溶；甲醇：微溶
• 物理描述：
  Solid
• 熔点：
  68°C

计算性质

• 辛醇/水分配系数(LogP)：
  24.1
• 重原子数：
  61
• 可旋转键数：
  54
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  78.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  sodium stearate 生成 1,3-di-O-oleoyl-2-O-palmitoylglycerol
  参考文献：
  名称：

  Kreis; Hafner, Chemische Berichte, 1903, vol. 36, p. 2767

  摘要：

  DOI：

文献信息

• Selection of surfactant‐modified lipases for interesterification of triglyceride and fatty acid
  作者：Ken‐ichi Mogi、Mitsutoshi Nakajima

  DOI：10.1007/bf02523517

  日期：1996.11

  Interesterification of tripalmitin and stearic acid inn‐hexane was investigated with surfactant‐modified lipases. Various kinds of lipases and surfactants were screened for high interesterification activity of the modified lipases. The modified‐lipase hydrophile‐lipophile balance value and fatty acid group of the surfactants. The modified lipase obtained fromRhizopus japonicus with sorbitan monostearate as surfactant had the highest activity in then‐hexane system. The interesterification activity of the selected modified lipase in molten substrates at 75°C without solvents was the same as that in then‐hexane system at 40°C.

  摘要 利用表面活性剂修饰的脂肪酶研究了三棕榈酸和硬脂酸在己烷中的酯化。筛选了各种类型的脂肪酶和表面活性剂，发现改性脂肪酶具有较高的酯化活性。研究了改性脂肪酶的亲水-亲脂平衡值和表面活性剂的脂肪酸基团。以山梨醇酐单硬脂酸酯为表面活性剂的日本根霉改性脂肪酶在当时的正己烷体系中活性最高。在不使用溶剂的情况下，所选改性脂肪酶在 75°C 的熔融底物中的酯化活性与在 40°C 的正己烷体系中的活性相同。
• Synthesis of triglycerides from 1,3-dibromopropan-2-ol
  作者：Asharam Bhati、Richard J. Hamilton、David A. Steven、Rajender Aneja、Frederick B. Padley

  DOI：10.1039/p29830001553

  日期：——

  1,3-Dibromopropan-2-ol (I) was converted into an acyl derivative (VI) by reaction with an appropriate acyl chloride in the presence of pyridine. The acyl derivative (VI) was subjected to nucleophilic substitution with 3 mol. equiv. tris(decyl)methylammonium carboxylate in refluxing hexane. This led to symmetrical diacid triglycerides in 90–94% yield. Substitution with an equimolar amount of the carboxylate

  通过在吡啶存在下与适当的酰氯反应，将1，3-二溴丙烷-2-醇（I）转化为酰基衍生物（VI）。对酰基衍生物（VI）进行3摩尔亲核取代。当量 在回流己烷中的羧酸三（癸基）甲基铵。这导致对称的二酸甘油三酯收率达到90-94％。用等摩尔量的羧酸取代，主要提供1,2-双酰氧基-3-溴丙烷（VII），可以轻松地将其分离并进一步取代，从而得到约不对称的二酸和三酸三甘油酯。产率96％。脂解显示合成的甘油三酸酯为约。纯度为99％。
• Improvements in edible fats
  申请人：UNILEVER N.V.

  公开号：EP0498487A1

  公开（公告）日：1992-08-12

  The processability of a margarine or other edible spread fat blends and the properties of the resulting products are to a large extent determined by the crystallisation behaviour of the fat blend. Problems of delayed crystallisation are known in the art of margarine or other spread manufacture, in particular, it is common knowledge in margarine blend formulation that interesterification of fats quite often results in slower crystallising fat blends and often fat blends which are impractically or inconveniently slow to crystallise. We have now determined that the crystallisation of margarine fats from a supercooled melt can be accelerated by the use of a triglyceride having a trans fatty acid at the 2-position, preferably a 1,3-saturated-2-trans-unsaturated (FTF) tempering accelerator. These include, in particular the HTH TAGs where H is stearic or palmitic, and especially PEP.

  人造奶油或其他可食用涂抹油脂混合物的可加工性以及所得产品的特性在很大程度上取决于混合物的结晶特性。在人造奶油或其他涂抹酱的制造工艺中，延迟结晶的问题是众所周知的，特别是在人造奶油混合配方中，脂肪的酯化通常会导致脂肪混合物的结晶速度减慢，而且通常脂肪混合物的结晶速度慢得不切实际或不方便。我们现在已经确定，通过使用在 2 位有反式脂肪酸的甘油三酯，最好是 1,3-饱和-2-反式不饱和（FTF）调质促进剂，可以加速人造奶油脂肪从过冷熔体中的结晶。这些甘油三酯尤其包括 HTH TAG（其中 H 为硬脂酸或棕榈酸），特别是 PEP。
• Malkin; Meara, Journal of the Chemical Society, 1939, p. 104
  作者：Malkin、Meara

  DOI：——

  日期：——
• Zapesochnaya,G.G.; Preobrazhenskii,N.A., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3826 - 3828
  作者：Zapesochnaya,G.G.、Preobrazhenskii,N.A.

  DOI：——

  日期：——