(2,6-Ditert-butyl-4-methylphenoxy)-(2,4,6-tritert-butylphenyl)iminophosphane | 188851-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,6-Ditert-butyl-4-methylphenoxy)-(2,4,6-tritert-butylphenyl)iminophosphane
• CAS: 188851-84-5；111252-28-9
• 化学式: C₃₃H₅₂NOP
• 分子量: 509.756
• InChiKey: IVTPVYXXAMTSAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  21.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2,6-Ditert-butyl-4-methylphenoxy)-(2,4,6-tritert-butylphenyl)iminophosphane 在 PPh₃ 作用下， 以 二氯甲烷 、 氘代甲苯 为溶剂， 生成 [Ph3PP.tplbond.NC6H2Bu(t)3-2,4,6][(C6H2(Bu(t)2-2,4,6)(Me)O)AlCl3]
  参考文献：
  名称：

  Synthesis and characterization of new phosphanylium and phosphanetriylammonium salts. Molecular structures of [(Me₂N)PN(AlCl₃)R] and [P(NPrⁱ₂)(NHR)]⁺[CF₃SO₃]^–(R = C₆H₂Bu^t₃-2,4,6)

  摘要：

  The new internal salts [(R(1)R(2)N)PN(ECl(3))R] (E = Al or Ga; R = 2,4,6-Bu(3)(t)C(6)H(2)) and phosphanylium salts [P(NR(1)R(2))(NHR)](+)[C6(3)SO(3)](-) have been synthesized by treating aminoiminophosphanes (R(1)R(2)N)P=NR with AlCl3, GaCl3 or CF3SO3H. Protonation of RHN-P=NR with trifluoromethanesulfonic acid led to the first stable phosphanylium salt [P(NHR)(2)](+)[CF3SO3](-) with two primary amino groups. In contrast, the reaction of AlCl3 with the (aryloxy) iminophosphane (R'O) P=NR (R' = 4.Me-2,6-Bu(2)(t)C(6)H(2)) led to the new aryl(phosphanetriyl)ammonium complex [PNR](+)[(R'O)AlCl3](-). All compounds were characterized by multinuclear NMR spectroscopy. The crystal structures of [(Me(2)N)PN(AlCl3)R] and [P(NPr2i)(NHR)](+)[(CFSO3)-S-3](-) have been determined by single-crystal X-ray diffractometry.

  DOI：

  10.1039/dt9940002925
• 作为产物：
  描述：

  P-chloro-O-(2,6-di-tert-butyl-4-methylphenyl)-N-trimethylsilyl-N-<2,4,6-tri(tert-butyl)phenyl>amidophosphite 生成 (2,6-Ditert-butyl-4-methylphenoxy)-(2,4,6-tritert-butylphenyl)iminophosphane
  参考文献：
  名称：

  Markovsky, L. N.; Romanenko, V. D.; Ruban, A. V., Phosphorus, Sulfur and Silicon and the Related Elements, 1990, vol. 49/50, p. 329 - 332

  摘要：

  DOI：

文献信息

• Markovski, L.N.; Romanenko, V.D.; Ruban, A.V., Phosphorus and Sulfur and the Related Elements, 1987, vol. 30, p. 447 - 450
  作者：Markovski, L.N.、Romanenko, V.D.、Ruban, A.V.

  DOI：——

  日期：——
• Markovskii, L. N.; Romanenko, V. D.; Ruban, A. V., Journal of general chemistry of the USSR, 1988, vol. 58, # 2, p. 255 - 258
  作者：Markovskii, L. N.、Romanenko, V. D.、Ruban, A. V.、Drapailo, A. B.、Chernega, A. N.、et al.

  DOI：——

  日期：——
• Romanenko, V. D.; Ruban, A. V.; Drapailo, A. B., Journal of general chemistry of the USSR, 1987, vol. 57, p. 206 - 207
  作者：Romanenko, V. D.、Ruban, A. V.、Drapailo, A. B.、Povolotskii, M. I.、Markovskii, L. N.

  DOI：——

  日期：——
• MARKOVSKIJ, L. N.;ROMANENKO, V. D.;RUBAN, A. V.;DRAPAJLO, A. B.;CHERNEGA,+, ZH. OBSHCH. XIMII, 58,(1988) N 2, 291-295
  作者：MARKOVSKIJ, L. N.、ROMANENKO, V. D.、RUBAN, A. V.、DRAPAJLO, A. B.、CHERNEGA,+

  DOI：——

  日期：——
• POMAHEHKO V. D.; RUBAN A. V.; DRAPAJLO A. B.; POVOLOTSKIJ M. I.; MARKOVSK+, ZH. OBSHCH. XIMII, 57,(1987) N 1, 235
  作者：POMAHEHKO V. D.、 RUBAN A. V.、 DRAPAJLO A. B.、 POVOLOTSKIJ M. I.、 MARKOVSK+

  DOI：——

  日期：——