3,3,3-trifluoro-1-(pyridine-2-yl)propen-2-ol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3,3-trifluoro-1-(pyridine-2-yl)propen-2-ol
• 英文别名: 3,3,3-Trifluoro-1-phenylprop-1-en-2-ol
• 化学式: C₉H₇F₃O
• 分子量: 188.149
• InChiKey: YZZSFCCGOKKDCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,3,3-trifluoro-1-(pyridine-2-yl)propen-2-ol 、 cobalt(II) diacetate tetrahydrate 以 乙醇 为溶剂， 反应 12.0h， 以72%的产率得到Co^III(PyCHCOCF₃)₃
  参考文献：
  名称：

  Molecular Co(II) and Co(III) Heteroarylalkenolates as Efficient Precursors for Chemical Vapor Deposition of Co₃O₄ Nanowires

  摘要：

  Two new cobalt precursors, Co-II(PyCHCOCF3)(2)(DMAP)(2) (1) and Co-III(PyCHCOCF3)(3) (2), based on Co(II) and Co(III) centers were synthesized using a redox active ligand system. The different chemical configurations of 1 and 2 and differential valence states of cobalt were confirmed by crystal structure determination and comprehensive analytical studies. Whereas 1 could not be studied by NMR due to the paramagnetic nature of the central atom, 2 was unambiguously characterized by multinuclear 1D and 2D NMR experiments in solution. Both compounds are efficient precursors for catalyst-free growth of Co3O4 nanowires on Si and Al2O3 substrates by a chemical vapor deposition process. The different valence states of cobalt species influenced their chemical decomposition pathways in the gas phase; for instance, 1 was partially oxidized (Co2+ -> Co3+), and 2 underwent reduction (Co3+ -> Co2+) to form pure cobaltite in both cases that verified the metal-ligand redox interplay. Co3O4 nanowires with nanometric diameters (50-100 nm) were obtained irrespective of the chosen cobalt precursor. Investigations on the humidity sensing behavior of CVD deposits demonstrated their potential as promising sensor materials.

  DOI：

  10.1021/ic501157e