5-tert-butyl-3-methyl-1,2-phenylene diethyl dicarbonate | 1308327-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-tert-butyl-3-methyl-1,2-phenylene diethyl dicarbonate
• 英文别名: (4-tert-butyl-2-ethoxycarbonyloxy-6-methylphenyl) ethyl carbonate
• CAS: 1308327-40-3
• 化学式: C₁₇H₂₄O₆
• 分子量: 324.374
• InChiKey: SLEHSEMESCSGDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  23
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  5-叔丁基-3-甲基-1,2-苯二酚 、 氯甲酸乙酯 在 silica gel 作用下， 以to yield a sticky colorless oil (81.4%)的产率得到5-tert-butyl-3-methyl-1,2-phenylene diethyl dicarbonate
  参考文献：
  名称：

  Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture

  摘要：

  一种固体、烃类不溶性催化剂成分，可用于聚合烯烃，该催化剂成分含有镁、钛和卤素，并进一步含有具有以下结构的内部电子给体：[R1—O—C(O)—O—]xR2，其中R1在每次出现时独立地是1-20个碳原子的脂肪族或芳香族烃或取代烃基；x为2-4；R2是1-20个碳原子的脂肪族或芳香族烃或取代烃基，前提是第一个R1—O—C(O)—O—基团和第二个R1—O—C(O)—O—基团之间的最短链中有2个原子。

  公开号：

  US08263520B2

文献信息

• TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE
  申请人：Coalter, III Joseph N.

  公开号：US20130245306A1

  公开（公告）日：2013-09-19

  A compound suitable for use as an internal electron donor having a structure: wherein R 1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; R 2 is independently at each occurrence, a hydrogen atom or aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; and R3 is an aliphatic hydrocarbyl group having 1 to 3 carbon atoms.

  一种适合用作内电子给体的化合物，其结构为：其中R1在每次出现时独立地为含有1至20个碳原子的脂肪族或芳香族烃或取代烃基团；R2在每次出现时独立地为氢原子或含有1至20个碳原子的脂肪族或芳香族烃或取代烃基团；而R3为含有1至3个碳原子的脂肪族烃基团。
• CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
  申请人：Basell Poliolefine Italia S.r.l.

  公开号：EP3122788A1

  公开（公告）日：2017-02-01
• US8263520B2
  申请人：——

  公开号：US8263520B2

  公开（公告）日：2012-09-11
• [EN] TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE<br/>[FR] COMPOSÉS DICARBONATES PONTÉS PAR DEUX ATOMES, COMME DONNEURS INTERNES DANS DES CATALYSEURS POUR LA FABRICATION DE POLYPROPYLÈNE
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2011068770A1

  公开（公告）日：2011-06-09

  A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1-O-C(O)-O-]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are 2 atoms in the shortest chain connecting a first R1 O C(O)-O- group and a second R1-O-C(O)-O- group.
• [EN] CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS<br/>[FR] COMPOSANTS CATALYTIQUES POUR LA POLYMÉRISATION D'OLÉFINES
  申请人：BASELL POLIOLEFINE SRL

  公开号：WO2015144668A1

  公开（公告）日：2015-10-01

  A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I), where each Q is a group –COOR1 in which R1 is selected from C1-C15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; or a group –CON(R2)2 in which R2 groups, equal to or different from each other, are hydrogen or R1 groups which can be fused together to form one or more cycles, and A is a bivalent bridging group with the proviso that Q groups cannot be simultaneously a group – COOR1 or –CON(R2)2.