5-bromo-5-butylnonane | 67035-62-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 5-bromo-5-butylnonane
• 英文别名: Tributylbrommethan；5-Brom-5-butyl-nonan
• CAS: 67035-62-5
• 化学式: C₁₃H₂₇Br
• 分子量: 263.261
• InChiKey: VQGOIINCSJEJOJ-UHFFFAOYSA-N

物化性质

• 沸点：
  282.7±8.0 °C(Predicted)
• 密度：
  1.026±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-bromo-5-butylnonane 生成 氢溴酸
  参考文献：
  名称：

  Karrer; Ferri, Helvetica Chimica Acta, 1934, vol. 17, p. 361

  摘要：

  DOI：
• 作为产物：
  描述：

  三丁基甲醇 在 lithium bromide monohydrate 、 氢溴酸 作用下， 以 二氯甲烷 、 水 为溶剂， 以20%的产率得到5-bromo-5-butylnonane
  参考文献：
  名称：

  缺电子活化烯烃的镍催化三组分还原烷基化

  摘要：

  在本文中，我们提出了缺电子活化烯烃与叔烷基溴化物和酸酐的镍催化三组分还原烷基酰化反应。该方法能够从简单的前体开始有效制备具有广泛底物范围和高功能耐受性的各种酮。在初步的机理研究的基础上，提出了涉及镍，锌和MgCl 2协同相互作用的催化循环作为主要反应途径。

  DOI：

  10.1021/acs.orglett.0c03210

文献信息

• Triton-B Catalyzed, Green and Efficient Method for the Synthesis of Dithiocarbazates
  作者：Sadaf Zaidi、Mridula Saxena

  DOI：10.14233/ajchem.2019.21973

  日期：2019.6.10

  A novel, solvent free and high yielding method was accomplished for one-pot synthesis of dithiocarbazates by the reaction of various alkyl halides (primary, secondary and tertiary) with variety of substituted hydrazines using Triton-B (benzyl-trimethylammonium hydroxide) and carbon di sulphide. This new method of synthesizing dithiocarbazates involves mild conditions, simple procedures and high yields of the products as compared to previously used methods.

  一种新颖的无溶剂高产率的方法被成功实现，用于通过不同烷基卤化物（初级、次级和三级）与多种取代肼的反应，进行一步法合成二硫 Carbazates，所使用的试剂为 Triton-B（苄基三甲基铵氢氧化物）和二硫化碳。与之前采用的方法相比，这种新方法在合成二硫 Carbazates 方面具有温和的反应条件、简单的操作过程和高产率的优势。
• METHOD FOR PRODUCING POLYMER, POLYMER, COMPOSITION FOR FORMING INSULATING FILM, METHOD FOR PRODUCING INSULATING FILM, AND INSULATING FILM
  申请人：JSR Corporation

  公开号：EP1705206A1

  公开（公告）日：2006-09-27

  There are provided a method for producing a polymer, a polymer, an insulating-film-forming composition, a method for producing an insulating film, and an insulating film capable of forming a film which is suitably used as an interlayer dielectric for semiconductor devices or the like and exhibits a low relative dielectric constant, excellent mechanical strength and adhesion, and uniform quality. A method for producing a polymer of the invention comprises hydrolyzing and condensing (B) a hydrolyzable-group-containing silane monomer in the presence of (A) a polycarbosilane, the polycarbosilane (A) being a polymer (I) obtained by reacting (a) a compound shown by the following general formula (1) and (b) at least one compound selected from the group consisting of a compound shown by the following general formula (2) and a compound shown by the following general formula (3) in an organic solvent in the presence of at least one of an alkali metal and an alkaline earth metal,         R1kCX4-k     (1)         R2kSiY4-k     (2)         R3mY3-mSiCR4nX3-n     (3) wherein R1 to R4 individually represent a monovalent organic group or a hydrogen atom, X represents a halogen atom, Y represents a halogen atom or an alkoxy group, k represents an integer from 0 to 3, and m and n individually represent integers from 0 to 2.

  本发明提供了一种聚合物的生产方法、一种聚合物、一种绝缘成膜组合物、一种绝缘膜的生产方法，以及一种能够形成薄膜的绝缘膜，该薄膜适合用作半导体器件或类似器件的层间电介质，并具有较低的相对介电常数、优异的机械强度和附着力以及均匀的质量。 生产本发明聚合物的方法包括在（A）聚碳酸酯硅烷存在下水解和缩合（B）含可水解基团的硅烷单体、聚碳硅烷(A)为聚合物(I)，由(a)下式(1)所示化合物和(b)至少一种选自下式(2)所示化合物和下式(3)所示化合物组成的组的化合物在有机溶剂中，在碱金属和碱土金属中至少一种存在下反应而得、 R1kCX4-k (1) R2kSiY4-k (2) R3mY3-mSiCR4nX3-n (3) 其中 R1 至 R4 分别代表一价有机基团或氢原子，X 代表卤素原子，Y 代表卤素原子或烷氧基，k 代表 0 至 3 的整数，m 和 n 分别代表 0 至 2 的整数。
• Petrow; Tschernyschew, Doklady Akademii Nauk SSSR, 1949, vol. 67, p. 1047
  作者：Petrow、Tschernyschew

  DOI：——

  日期：——
• Triton-B catalyzed, efficient one-pot synthesis of carbazates
  作者：Devdutt Chaturvedi、Amit K. Chaturvedi、Nisha Mishra、Virendra Mishra

  DOI：10.1007/s00706-008-0955-8

  日期：2008.12

  A quick and efficient, one-pot synthesis of carbazates was accomplished in high yields by the reaction of various primary, secondary, and tertiary alkyl halides with a variety of substituted hydrazines using the benzyltrimethylammonium hydroxide (Triton-B)/CO2 system. The reaction conditions are mild with simpler work-up procedures than the reported methods.
• Triton-B catalyzed, efficient one-pot synthesis of dithiocarbazates
  作者：Devdutt Chaturvedi、Nisha Mishra、Virendra Mishra

  DOI：10.1007/s00706-008-0873-9

  日期：2008.9

  A quick and efficient, one-pot synthesis of dithiocarbazates was accomplished in high yields by the reaction of various primary, secondary, and tert. alkyl halides with a variety of substituted hydrazines using the benzyl-trimethylammonium hydroxide (Triton-B)/CS2 system. The reaction conditions are mild with simpler work-up procedures than the reported methods.