[1-(Benzenesulfinyl)ethyl](tributyl)stannane | 185145-44-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1-(Benzenesulfinyl)ethyl](tributyl)stannane
• 英文别名: 1-(benzenesulfinyl)ethyl-tributylstannane
• CAS: 185145-44-2
• 化学式: C₂₀H₃₆OSSn
• 分子量: 443.281
• InChiKey: PHFRTZMUWZPGGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.57
• 重原子数：
  23
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [1-(Benzenesulfinyl)ethyl](tributyl)stannane 以 二氯甲烷 为溶剂， 反应 22.25h， 生成 1-Bromoethylsulfanylbenzene
  参考文献：
  名称：

  Cleavage of Carbon--Sulfur Bonds in the Synthesis of alpha-Haloalkyl Carbonates.

  摘要：

  alpha-Chloroalkyl and alpha-bromoalkyl carbonates have been prepared by cleavage of alpha-arylthioalkyl carbonates with sulfuryl chloride or bromine, respectively. The alpha-arylthioalkyl carbonates are prepared by reaction of the hemithioacetal 1 with chloroformates or by a destannylative tin-Pummerer rearrangement of alpha-stannyl sulfoxides.

  DOI：

  10.3891/acta.chem.scand.50-1041

文献信息

• Tin-Pummerer Rearrangement in the Synthesis of O,S-Acetal Derivatives.
  作者：Jostein Hatlelid、Tore Benneche、Kjell Undheim、Frode Rise、Michael P. Hartshorn、Manuela Merchán、Ward T. Robinson、Björn O. Roos、Claire Vallance、Bryan R. Wood

  DOI：10.3891/acta.chem.scand.51-1092

  日期：——

  alpha-Thioalkyl esters and carbonates have been prepared by a tin-Pummerer rearrangement in reactions of alpha-stannylated sulfoxides with acid chlorides or chloroformates, respectively. Acid chlorides have a higher reactivity than chloroformates in this reaction.
• Cleavage of Carbon--Sulfur Bonds in the Synthesis of alpha-Haloalkyl Carbonates.
  作者：Jostein Hatlelid、Tore Benneche、Kjell Undheim、Neucírio Ricardo de Azevedo、Pedro Henrique Ferri、Kristian Rønning Pedersen、Muhammed Nour Homsi、Frank K. H. Kuske、Monika Haugg、Nathalie Trabesinger-Rüf、Elmar G. Weinhold

  DOI：10.3891/acta.chem.scand.50-1041

  日期：——

  alpha-Chloroalkyl and alpha-bromoalkyl carbonates have been prepared by cleavage of alpha-arylthioalkyl carbonates with sulfuryl chloride or bromine, respectively. The alpha-arylthioalkyl carbonates are prepared by reaction of the hemithioacetal 1 with chloroformates or by a destannylative tin-Pummerer rearrangement of alpha-stannyl sulfoxides.