2,2'-异亚丙基二苯酚 | 7559-72-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,2'-异亚丙基二苯酚
• 英文名称: 2,2-bis(2-hydroxyphenyl)-propane
• 英文别名: 2,2-bis(2-hydroxyphenyl)propane；2,2'-isopropylidenediphenol；2,2'-bisphenol A；2,2-bis-(hydroxyphenyl)-propane；2,2-di(hydroxyphenyl)propane；2,2-bis-(2-hydroxyphenyl)propane；2-[2-(2-hydroxyphenyl)propan-2-yl]phenol
• CAS: 7559-72-0
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.291
• InChiKey: MQXNNWDXHFBFEB-UHFFFAOYSA-N

物化性质

• 熔点：
  121-123°C
• 溶解度：
  可溶于氯仿（轻微）、DMSO（轻微）甲醇（轻微）

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2'-异亚丙基二苯酚 在 氘代甲醇-d 作用下， 生成
  参考文献：
  名称：

  Theortho effect in the mass spectra ofortho/para isomers of bisphenol a derivatives and related compounds

  摘要：

  AbstractNew examples of the ortho effect in bisphenol A derivatives including interaction of the hydrogen of the ortho‐hydroxy group with the neighbouring aromatic ring have been observed. The characteristic ions [M  PhOH]+middot; (m/z = 134) and [M  CH3  PhOH]+ (m/z = 119) were shown to form through the hydrogen transfer from hydroxy and isopropyl groups, respectively. The spectra of cyclic derivatives having ortho‐hydroxy functions show [M  43]+, [M  C8H9O]+, m/z = 147, m/z = 135 and [M  C9H10O]+ ions. The proposed mechanims of the corresponding transformations were supported by mass spectra of deuterated analogues, methyl and trimethyl silyl ethers.

  DOI：

  10.1002/oms.1210290105
• 作为产物：
  描述：

  2,2-Bis(O-methoxyphenyl)-propan 在 sodium hydroxide 、 乙硫醇 作用下， 以 N-甲基乙酰胺 为溶剂， 生成 2,2'-异亚丙基二苯酚
  参考文献：
  名称：

  Herbicidal 12-substituted 12H-dibenzo(D,G)(1,3)dioxocin-6-carboxylic

  摘要：

  二苯并[d,g][1,3]二噁喃-6-羧酸在12位被甲基或乙基或一种基团--CH.sub.2 CH.sub.2--取代，并且在其他位置可选择性地被取代，例如甲基4'-氯螺(cyclopropane-1,12'(12'H)-dibenzo[d,g][1,3]二噁喃)-6'-羧基酸，以及它们的农业可接受的酯、酰胺和盐对于控制不良植被是有用的。用于螺环丙烷化合物的1,1-二芳基环丙烷中间体可以通过与苯硫甲基锂试剂反应制备，该试剂由适当取代的1,1-二芳基乙烯前体制备而成。

  公开号：

  US04938790A1

文献信息

• Silylated polycarbonate polymers, method of making, and articles
  申请人：Lens Jan Pleun

  公开号：US20080306294A1

  公开（公告）日：2008-12-11

  A silylated dihydroxy aromatic compound of the formula (1a); wherein G a and G b are each independently C 1-12 alkyl, —OSi(C 1-12 alkyl) 3 , C 1-12 arylalkyl, or —OSi(C 1-12 arylalkyl) 3 ; Z a and Z b are each independently a straight or branched C 2-18 alkylene, a C 8-18 arylalkylene, or a C 8-18 alkylarylene, X a is a direct bond, a heteroatom-containing group, or a C 1-18 organic group, and r and s are each independently 1 or 2 is disclosed.

  一种具有式(1a)的硅烷化二羟基芳香族化合物；其中Ga和Gb各自独立地为C1-12烷基、—OSi(C1-12烷基)3、C1-12芳基烷基或—OSi(C1-12芳基烷基)3；Za和Zb各自独立地为直链或支链的C2-18亚烷基、C8-18芳基亚烷基或C8-18烷基芳基亚烷基，Xa为直接键、含杂原子基团或C1-18有机基团，且r和s各自独立地为1或2。
• Azine-based dimeric charge transport materials
  申请人：——

  公开号：US20040265717A1

  公开（公告）日：2004-12-30

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula 1 where R 1 , R 2 , R 3 , and R 4 comprise, each independently, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a ring group; X and X′ comprise, each independently, an aromatic group; Y and Y′ comprise, each independently, a (disubstituted)methylene group; and Z is a linking group; (b) a charge generating compound; and (c) an electrically conductive substrate on which said charge transport material and said charge generating compound are located. Corresponding electrophotographic apparatuses and imaging methods are also described.

  改进的有机光感受器包括一个电导基底和位于电导基底上的光电导元件，所述光电导元件包括： (a) 具有下列结构式1的电荷传输材料： 其中，R1、R2、R3和R4分别独立地包括烷基、烯基、芳香基、杂环基或环基的一部分； X和X'分别独立地包括芳香基； Y和Y'分别独立地包括(二取代)亚甲基基团； Z是一个连接基团； (b) 一个电荷生成化合物；以及 (c) 位于所述电导基底上的所述电荷传输材料和所述电荷生成化合物。 还描述了相应的电子照相设备和成像方法。
• PHOSPHORUS-CONTAINING COMPOUND AND CURING EPOXY RESIN COMPOSITION CONTAINING SAME
  申请人：ADEKA CORPORATION

  公开号：US20160200747A1

  公开（公告）日：2016-07-14

  Provided is a novel phosphorus-containing compound represented by general formula (I). The compound has reactivity with a glycidyl group and is therefore capable of providing a curing epoxy resin composition that is expected to achieve flame retardation and reduction of dielectric constant. wherein m is a number of 1 to 10; R 1 , R 2 , R 3 , and R 4 are each hydrogen, alkyl, or aryl; R 5 is alkyl, alkanediyl, alkanetriyl, alkanetetrayl, or an aromatic group; X is oxygen or sulfur; Y is oxygen, sulfur, or ═NR′; and R′ is hydrogen, alkyl, or aryl.

  提供的是一种由通式（I）表示的新型含磷化合物。该化合物与环氧乙烯基团具有反应性，因此能够提供一种预期能够实现阻燃和降低介电常数的固化环氧树脂组合物。其中m为1至10的数字；R1、R2、R3和R4分别为氢、烷基或芳基；R5为烷基、烷二基、烷三基、烷四基或芳基；X为氧或硫；Y为氧、硫或═NR′；R′为氢、烷基或芳基。
• Herbicidal and plant growth regulant activity of glyoxylates
  申请人：Fermenta ASC Corporation

  公开号：US04976770A1

  公开（公告）日：1990-12-11

  12H-dibenzo[d,g][1,3]dioxocin-6-carboxylic acid and certain derivatives thereof (glyoxylates) exhibit plant growth regulant and herbicidal activity when applied to a plant locus.

  12H-二苯并[d,g][1,3]二噁英-6-羧酸及其某些衍生物（乙二醛酸）在施加到植物位点时表现出植物生长调节剂和除草剂活性。
• [EN] SYNTHESIS OF 2,2-BIS(3-PHENYL-4-HYDROXYPHENYL) PROPANE (PHP)<br/>[FR] SYNTHÈSE DE 2,2-BIS (3-PHÉNYL -4-HYDROXYPHÉNYL)PROPANE (PHP)
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2016009359A1

  公开（公告）日：2016-01-21

  Disclosed herein are ortho aryl substituted bisphenol monomers that exhibit a lower binding energy to estradiol related receptors. The monomers are provided by the condensation of a ketone and phenol in the presence of an acid catalyst.

  本文披露了一种具有较低结合能与雌二醇相关受体的邻位芳基取代双酚单体。这些单体是通过在酸催化剂存在下对酮和酚进行缩聚得到的。