4-lithio-4-phenyl-4H-stannolo[2,3-c:4,5-c']dithiophene | 1201804-38-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-lithio-4-phenyl-4H-stannolo[2,3-c:4,5-c']dithiophene
• CAS: 1201804-38-7
• 化学式: C₁₄H₉LiS₂Sn
• 分子量: 367.008
• InChiKey: DDKMLRSKFZHACL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.93
• 重原子数：
  18.0
• 可旋转键数：
  1.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  4,4'-dilithio-3,3'-bithiophene 以 乙二醇二甲醚 、 乙醚 为溶剂， 生成 4-lithio-4-phenyl-4H-stannolo[2,3-c:4,5-c']dithiophene
  参考文献：
  名称：

  Synthesis and structure of the dithienostannole anion

  摘要：

  Novel dithienostannoles were synthesized by the reactions of the corresponding dilithiobithiophenes with dichlorodiphenylstannane. A unique byproduct, 10-membered ring compound was also obtained. Reduction of type A dithienostannole with lithium afforded 2,2'-dilithio-3,3'-bithiophene, while reduction of type B dithienostannole with lithium afforded the corresponding dithienostannole anion. The structure and aromaticity of the dithienostannole anion are also discussed. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.08.026