1,2,3-tri-O-(2-propenyloxy)carbonylglycerol | 93345-75-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 1,2,3-tri-O-(2-propenyloxy)carbonylglycerol
• 英文别名: 1,2,3-tris-allyloxycarbonyloxy-propane；1,2,3-Tris-allyloxycarbonyloxy-propan；Glycerin-tris-allylcarbonat；1,3-Bis(prop-2-enoxycarbonyloxy)propan-2-yl prop-2-enyl carbonate；1,3-bis(prop-2-enoxycarbonyloxy)propan-2-yl prop-2-enyl carbonate
• CAS: 93345-75-6
• 化学式: C₁₅H₂₀O₉
• 分子量: 344.318
• InChiKey: OPHUBCXESLHATL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  24
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  甘油 、 氯甲酸烯丙酯 在 吡啶 作用下， 生成 1,2,3-tri-O-(2-propenyloxy)carbonylglycerol
  参考文献：
  名称：

  Unsaturated esters and polymers thereof

  摘要：

  公开号：

  US02385932A1

文献信息

• Selective Synthesis of Carbonates from Glycerol, CO2, and Alkyl Halides Using tert-Butyltetramethylguanidine
  作者：Masatoshi Mihara、Kaname Moroga、Tetsuo Iwasawa、Takeo Nakai、Takatoshi Ito、Toshinobu Ohno、Takumi Mizuno

  DOI：10.1055/s-0037-1610027

  日期：2018.8

  Herein, we describe the guanidine-promoted synthesis of carbonates from glycerol, CO2, and alkyl halides. Specifically, a linear tricarbonate (1,2,3-tri-O-butoxycarbonylglycerol), a dicarbonate [butyl (2-oxo-1,3-dioxolan-4-yl)methyl carbonate] containing a linear and a cyclic moiety, and a cyclic monocarbonate (4-hydroxymethyl-2-oxo-1,3-dioxolan) were selectively obtained in good yields, which were

  在此，我们描述了从甘油、CO2 和烷基卤化物中胍促进的碳酸酯合成。具体而言，直链三碳酸酯（1,2,3-三-O-丁氧基羰基甘油）、含有直链和环状部分的二碳酸酯[丁基（2-氧代-1,3-二氧戊环-4-基）甲基碳酸酯]，和环状单碳酸酯（4-羟甲基-2-氧代-1,3-二氧戊环）以良好的产率选择性获得，这受到胍基取代基的空间体积的强烈影响。所开发的方法具有高效、条件温和的优点，是从工业副产品合成高附加值产品的有力工具。
• Polymerizable composition for optical articles
  申请人：PPG Industries Ohio, Inc.

  公开号：US10294318B2

  公开（公告）日：2019-05-21

  A polymerizable composition includes at least one first monomer and at least one second monomer, wherein the at least one first monomer includes an isohexide bis(allyl carbonate) monomer, and wherein the at least one second monomer includes one or more ethylenic unsaturations. Another polymerizable composition includes the reaction product of an isohexide bischloroformate; at least one polyol; allyl alcohol; and, optionally, at least one polychloroformate. An exemplary polymerizable composition includes the transesterification reaction product of an isohexide; diallyl carbonate; and at least one polyol. A polymerizate including the polymerizable composition and an optical article including the polymerizable composition are also provided.

  一种可聚合组合物包括至少一种第一单体和至少一种第二单体，其中至少一种第一单体包括异己双（碳酸烯丙酯）单体，其中至少一种第二单体包括一种或多种乙烯基不饱和物。另一种可聚合组合物包括异己双氯甲酸酯、至少一种多元醇、烯丙基醇和可选的至少一种聚氯甲酸酯的反应产物。一种示例性的可聚合组合物包括异构体的酯交换反应产物、碳酸二烯丙酯和至少一种多元醇。还提供了一种包括可聚合组合物的聚合物和一种包括可聚合组合物的光学制品。
• Composition for optical articles and optical articles made therewith
  申请人：PPG Industries Ohio, Inc.

  公开号：US10407540B2

  公开（公告）日：2019-09-10

  An exemplary polymerizable composition includes the reaction product of (a) diethyleneglycol bischloroformate; (b) allyl alcohol; (c) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (d) optionally, ethyleneglycol bischloroformate; and (e) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups. Another exemplary polymerizable composition includes the reaction product of (a) allyl alcohol; (b) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (c) ethyleneglycol bischloroformate; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups is also described. A reaction product, a polymerizate including the polymerizable composition, and an optical article including the polymerizable composition are also provided.

  一种示例性的可聚合组合物包括以下物质的反应产物：(a) 二乙二醇双氯甲酸酯；(b) 烯丙醇；(c) 环状多元醇，该多元醇选自由至少具有一个仲羟基的环脂族多元醇、具有伯羟基和/或仲羟基的杂环多元醇及其混合物组成的组；(d) 可选的乙二醇双氯甲酸酯；以及 (e) 可选的至少一种具有 2 至 6 个羟基的直链或支链脂肪族多元醇。另一种示例性可聚合组合物包括以下物质的反应产物：(a) 烯丙醇；(b) 环状多元醇，该多元醇选自由具有至少一个仲羟基的环脂族多元醇、具有伯羟基和/或仲羟基的杂环多元醇及其混合物组成的组；(c) 乙二醇双氯甲酸酯；以及 (d) 可选的至少一种具有二至六个羟基的直链或支链脂肪族多元醇。还提供了一种反应产物、一种包括可聚合组合物的聚合物和一种包括可聚合组合物的光学制品。
• Preparation of carbonic acid esters
  申请人：PITTSBURGH PLATE GLASS CO

  公开号：US02370567A1

  公开（公告）日：1945-02-27
• Polybasic acid-polyhydric alcohol esters and polymers thereof
  申请人：PITTSBURGH PLATE GLASS CO

  公开号：US02384115A1

  公开（公告）日：1945-09-04