8,8'-dihydroxy-4,4'-dimethoxy-6,6'-dimethyl-2,2'-binaphthylidene-1,1'-quinone | 135759-62-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8,8'-dihydroxy-4,4'-dimethoxy-6,6'-dimethyl-2,2'-binaphthylidene-1,1'-quinone
• 英文别名: 8,8'-Dihydroxy-4,4'-dimethoxy-6,6'-dimethyl-2,2'-binaphthyliden-1,1'dion；diosindigo A；diosindigo-A；(2E)-8-hydroxy-2-(8-hydroxy-4-methoxy-6-methyl-1-oxonaphthalen-2-ylidene)-4-methoxy-6-methylnaphthalen-1-one
• CAS: 135759-62-5
• 化学式: C₂₄H₂₀O₆
• 分子量: 404.419
• InChiKey: WIZRPQYWANTMOT-BUHFOSPRSA-N

物化性质

• 沸点：
  739.8±60.0 °C(Predicted)
• 密度：
  1.41±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  8,8'-dihydroxy-4,4'-dimethoxy-6,6'-dimethyl-2,2'-binaphthylidene-1,1'-quinone 在 高氯酸 、 硝酸 作用下， 反应 0.03h， 生成 Mamegakinon-diacetat
  参考文献：
  名称：

  Laatsch, Hartmut, Liebigs Annalen der Chemie, 1980, # 8, p. 1321 - 1347

  摘要：

  DOI：
• 作为产物：
  描述：

  4-氯-3-甲基苯酚 在 10% palladium on active carbon 盐酸 、 sodium hydroxide 、 三氯化铝 、 sodium dithionite 、 水 、 氢气 、 sodium acetate 、 lead dioxide 、 sodium chloride 、 silver(l) oxide 、 锌 作用下， 以 1,4-二氧六环 、 吡啶 、 甲醇 、 乙醚 、 氯仿 、 水 为溶剂， 反应 19.0h， 生成 8,8'-dihydroxy-4,4'-dimethoxy-6,6'-dimethyl-2,2'-binaphthylidene-1,1'-quinone
  参考文献：
  名称：

  Laatsch, Hartmut, Liebigs Annalen der Chemie, 1980, # 8, p. 1321 - 1347

  摘要：

  DOI：

文献信息

• Oxidative coupling of methoxynaphthylenediols
  作者：Bhim C. Maiti、Oliver C. Musgrave、Douglas Skoyles

  DOI：10.1016/j.tet.2005.04.058

  日期：2005.7

  5-naphthylenediol using lead(IV) oxide gives the symmetrical bisnaphthalene indigos diosindigo A and diosindigo B together with the corresponding unsymmetrical isomer. Oxidation of the first two by nitric acid gives the binaphthyldiquinones mamegakinone and biramentaceone, respectively; the third gives the unsymmetrical diquinone rotundiquinone. Similar oxidations of related naphthylenediols are described.

  使用氧化铅（IV）氧化1-甲氧基-7-甲基-4,5-萘二醇和4-甲氧基-7-甲基-1,5-萘二醇的混合物，得到对称的双萘靛蓝靛蓝A和靛蓝B以及相应的不对称异构体。前两个被硝酸氧化，分别得到双萘基二醌类马格基酮和双歧ra酮；第三个给出了不对称的对苯二酚罗通二醌。描述了相关萘二醇的类似氧化。
• Ebenaceae extractives. Part IV. Diosindigo A, a blue pigment from several Diospyros species
  作者：Oliver C. Musgrave、Douglas Skoyles

  DOI：10.1039/p19740001128

  日期：——

  The wood of seven of the eighteen species of Diospyros examined contains small amounts of a blue pigment, diosindigo A [8,8′-dihydroxy-4,4′-dimethoxy-6,6′-dimethyl-2,2′-binaphthylidene-1,1′-quinone(I; R1= Me, R2= OH)]. Other extractives include plumbagin, 7-methyljuglone, isodiospyrin, mamegakinone, bergenin, lupeol, betulin, betulinic acid, oleanolic acid, β-sitosterol, and stigmasterol. Diosindigo

  检查的18种Diospyros中的7种木材含有少量的蓝色颜料diosindigo A [8,8'-dihydroxy-4,4'-dimethoxy-6,6'-dimethyl-2,2'-binaphthylidene- 1,1'-醌（I； R 1 = Me，R 2 = OH）]。其他提取物包括李子，7-甲基juglone，异二嘧啶，mamegakinone，卑尔根，卢佩欧，白桦蛋白，桦木酸，齐墩果酸，β-谷甾醇和豆甾醇。靛蓝A已通过氧化由7-甲基胡胶制得的4-甲氧基-6-甲基萘-1,8-二醇合成。
• Kumari, L. Krishna; Babu, M. Hari; Pardhasaradhi, M., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1982, vol. 21, p. 755 - 756
  作者：Kumari, L. Krishna、Babu, M. Hari、Pardhasaradhi, M.

  DOI：——

  日期：——
• COMPOSITION COMPRISING A HYDROPHOBIC DYE, A PARTICULAR ORGANIC AND/OR MINERAL ALKALINE AGENT, A PARTICULAR COMPOUND (I) AND A PARTICULAR ORGANIC COMPOUND (II), AND DYEING USE THEREOF
  申请人：Lalleman Boris

  公开号：US20120204357A1

  公开（公告）日：2012-08-16

  Composition comprising a hydrophobic dye, a particular organic and/or mineral alkaline agent, a particular compound (I) and a particular organic compound (II), and dyeing use thereof. The present invention relates to a dye composition comprising one or more hydrophobic direct dyes with a log P of greater than or equal to 2, one or more organic alkaline agents, and/or one or more mineral alkaline agents chosen from carbonates, hydrogen carbonates, sodium hydroxide and potassium hydroxide, and mixtures thereof, one or more compounds (I) comprising in their structure a sequence: and one or more organic compounds (II) with a Hansen solubility parameter δH of less than or equal to 16 MPa 1/2 and with a molecular weight of less than 250 g/mol. The invention also relates to a dyeing process that consists in applying such a composition to keratin fibers.
• US8551188B2
  申请人：——

  公开号：US8551188B2

  公开（公告）日：2013-10-08