N-Pentafluorophenyl(C-pentafluorophenyl)imidoyl chloride | 71153-92-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Pentafluorophenyl(C-pentafluorophenyl)imidoyl chloride
• 英文别名: N-(pentafluorophenyl)pentafluorobenzimidoyl chloride；N-(Pentafluorphenyl)(pentafluorphenyl)carbonimidoylchlorid；2,3,4,5,6-pentafluoro-N-(2,3,4,5,6-pentafluorophenyl)benzenecarboximidoyl chloride
• CAS: 71153-92-9
• 化学式: C₁₃ClF₁₀N
• 分子量: 395.587
• InChiKey: YHODJHNBIDZHGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  N-Pentafluorophenyl(C-pentafluorophenyl)imidoyl chloride 在 cesium fluoride 作用下， 生成 N-Pentafluorophenyl(C-pentafluorophenyl)imidoyl fluoride
  参考文献：
  名称：

  Savchenko,T.I. et al., Journal of Organic Chemistry USSR (English Translation), 1979, vol. 15, p. 915 - 919

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3,4,5,6-五氟-N-(五氟苯基)苯甲酰胺 在 五氯化磷 作用下， 以 二氯甲烷 为溶剂， 生成 N-Pentafluorophenyl(C-pentafluorophenyl)imidoyl chloride
  参考文献：
  名称：

  Fluorinated Bis(phenoxyketimine)titanium Complexes for the Living, Isoselective Polymerization of Propylene:  Multiblock Isotactic Polypropylene Copolymers via Sequential Monomer Addition

  摘要：

  A series of bis(phenoxyketimine)titanium dichloride complexes were synthesized and evaluated as catalysts for living, isoselective propylene polymerization upon activation with methylaluminoxane (MAO). Catalysts bearing phenoxyketimine ligands with different substituents at the ortho and para. positions of the phenolate ring and substituents at the ketimine carbon were investigated. The identity of the ketimine substituent had the largest effect on the activity and isoselectivity of propylene polymerization. Complex 12/MAO promoted the living, isoselective polymerization of propylene ([m(4)] = 0.73, alpha = 0.94). This catalyst system was used for the synthesis of a number of block copolymers featuring isotactic polypropylene semicrystalline blocks and poly(ethylene-co-propylene) amorphous blocks. Several triblock samples with varying block lengths, a pentablock, and a heptablock copolymer were synthesized. Mechanical testing has revealed that each is elastomeric with elongations at break between similar to 790-1000%.

  DOI：

  10.1021/ja077772g

文献信息

• Polyfluoroarylcarbonimidoyl dichlorides and chlorides. A new method of obtaining such compounds from polyfluoroaromatic amines and compounds of the CCl3R-type in the presence of AlCl3
  作者：T.I. Savchenko、I.V. Kolesnikova、T.D. Petrova、V.E. Platonov

  DOI：10.1016/s0022-1139(00)81166-5

  日期：1983.5

  polyfluorinated amines of the benzene, diphenyl, naphthalene and pyridine series with CCl4 in the presence of AlCl3 have been Investigated. A new method is proposed for producing polyfluoroarylcarbonimidoyl dichlorides ArfNCCl2. The reaction is shown to be sufficiently general and applicable in the series of polychlorinated anilines and low-base anilines of the hydrocarbon series as well. The possibility

  研究了在AlCl 3存在下苯，联苯，萘和吡啶系列的一些多氟胺与CCl 4的反应。提出了一种新的制备聚氟芳基碳亚氨基二氯化物Ar f N = CCl 2的方法。该反应显示出足够普遍，并且适用于烃系列的多氯苯胺和低碱苯胺系列。已经研究了反应中可能包含其他类型的CCl 3 R化合物和其他路易斯酸的可能性。讨论了影响反应过程的因素以及多氟芳基碳亚氨基二氯化物的形成机理。
• New route to fluorinated arylcarbonimidoyl chlorides: Interaction of polyfluoroaryl-amines with halomethanes in the presence of lewis acids
  作者：T.I. Savchenko、T.D. Petrova、I.V. Kolesnikova、V.E. Platonov

  DOI：10.1016/s0022-1139(00)84039-7

  日期：1980.12

  the preparation of polyfluoroarylcarbonimidoyl chlorides by high-temperature copyrolysis of polyfluoroaromatic amines with CCl4 or pentafluorobenzotrichloride. In presented paper we wish to report a new and convenient route to carbonimidoyl chlorides by interaction of polyfluoroaromatic amines with CCl4 or pentafluorobenzotrichloride in the presence of AlCl3 at ordinary temperature. This method gives

  近来，我们已经描述了通过用CCl 4或五氟苯并三氯化物对聚氟芳族胺进行高温共水解来制备聚氟芳基碳亚氨基氯化物。在提出的论文中，我们希望报告在常温下，在AlCl 3存在下，多氟芳族胺与CCl 4或五氟苯并三氯化物的相互作用，从而获得一种新的简便的方法来制备碳亚氨基酰氯。该方法以高收率得到碳亚氨基酰氯。
• Reactions of polyfluoroaromatic imidoyl chloride derivatives with S-nucleophilic reagents
  作者：T.D. Petrova、V.E. Platonov、L.N. Shchegoleva、A.M. Maksimov、A. Haas、M. Schelvis、M. Lieb

  DOI：10.1016/0022-1139(96)03465-3

  日期：1996.7

  N-pentafluorophenylcarbonimidoyl dichloride, N-pentafluorophenylbenzimidoyl chloride and N-pentafluorophenyl (C-pentafluorophenyl) imidoyl chloride with the S-nucleophilic reagents thiourea, sodiumN,N-diethyldithiocarbamate, thiocarbonyl difluoride and bis(trifluoromethyl)trithiocarbonate in the presence of CsF or AgSCF3, or thiophenol and polyfluorinated thiophenols in the presence of anhydrous K2CO3, were studied

  的相互作用Ñ -pentafluorophenylcarbonimidoyl二氯化物，Ñ -pentafluorophenylbenzimidoyl酰氯和Ñ -pentafluorophenyl（C-五氟苯基）亚氨酰氯与S-亲核试剂硫脲，钠盐N，N- -diethyldithiocarbamate，在存在硫代羰基二氟化物和双（三氟甲基）三硫代碳酸酯研究了在无水K 2 CO 3存在下的CsF或AgSCF 3，或苯硫酚和多氟化苯酚。在碱的存在下，与带电荷的S-亲核试剂和与S-亲核试剂的反应进行，从而在反应产物中保留了NC多重键。通过改变反应条件N-五氟苯基-汽车-亚氨基二氯可以取代一个或两个氯，得到一或二硫代亚氨酸酯。当C 6 ˚F 5或SC 6 ˚F 5个基团存在于该NC多重键的C原子，所述的优先的取代对位-氟原子发生。半经验PM3计算数据用于解释这些反应的方向。N-五氟苯基碳亚氨基二氯与N
• Kryuchkova, E. N.; Kolesnikova, I. V.; Drizhd, L. P., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 10, p. 1840 - 1844
  作者：Kryuchkova, E. N.、Kolesnikova, I. V.、Drizhd, L. P.、Savelova, V. A.、Petrova, T. D.、Platonov, V. E.

  DOI：——

  日期：——
• Reactions of pentafluoroaniline with aromatic trihalomethyl derivatives in the presence of AlCl3
  作者：T. D. Petrova、I. S. Popova、I. V. Kolesnikova、V. E. Platonov

  DOI：10.1007/bf01558072

  日期：1994.6

  The reactions of pentafluoroaniline with aromatic CX(3)-derivatives (X = F, Cl) in the presence of AlCl3 were studied. It was shown that compounds with a CF3 group can be used 3 in reactions with polyfluoroaromatic amines instead of CCl3-derivatives for the synthesis of imidoyl chlorides. In the case of compounds with several CX(3) groups, the formation of the 3 imidoyl chloride moiety predominantly involves one of the CX(3) groups under the conditions studied. The introduction of a second CX(3) group can be carried out only under more drastic conditions.