bis(diethyldithiocarbamato)manganese(II) | 57683-09-7

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: bis(diethyldithiocarbamato)manganese(II)
• 英文别名: manganese(II) diethyldithiocarbamate；manganese diethyldithiocarbamate；Fe(Et2dtc)2；Bis-(diethylaminodithiocarbamato)-mangan-(II)
• CAS: 57683-09-7
• 化学式: 2C₅H₁₀NS₂*Mn
• 分子量: 351.484
• InChiKey: BTPBXYKCCKXMGO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.16
• 重原子数：
  9.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  bis(diethyldithiocarbamato)manganese(II) 、 富勒烯 以 邻二氯苯 、 苯 为溶剂， 以70%的产率得到[Mn(diethyldithiocarbamate)2]2*C70
  参考文献：
  名称：

  C60 和 C70 配合物与金属二烷基二硫代氨基甲酸盐 M(R2dtc)x 的合成、晶体结构、磁性和光电导率，其中 M = CuII、CuI、AgI、ZnII、CdII、HgII、MnII、NiII 和 PtII；R = Me、Et 和 nPr

  摘要：

  富勒烯 C 60 和 C 70 与金属二烷基二硫代氨基甲酸盐的新配合物，[M(R 2 dtc) x ]·[C 60 ( 70 )]·[溶剂]，R = Et [M = Cu II (C 60 , 1; C 70, 2), Cu I (C 60, 3; C 70, 4), Ag I (C 60, 5), Zn II (C 60, 6), Cd II (C 60, 7; C 70, 8) , Hg II (C 60 , 9), Mn II (C 70, 10)], R = Et and Me [M = Cu II (C 60, 11), and Zn II (C 60, 12)], and R得到=nPr[M=Cu II (C 60, 13), Ni II (C 60, 14), 和Pt II (C 60, 15)]。M(R 2 dtc) x 与作为四面体单体 (6, 12)、二聚体 (1, 7

  DOI：

  10.1002/ejic.200501110
• 作为产物：
  描述：

  sodium N,N-diethyldithiocarbamate 、 manganese(II) chloride tetrahydrate 以 水 为溶剂， 生成 bis(diethyldithiocarbamato)manganese(II)
  参考文献：
  名称：

  Magnetic susceptibility study of bis(diethyldithiocarbamato)manganese(II). A sulfur-bridged linear-chain antiferromagnet

  摘要：

  DOI：

  10.1021/ic50224a064

文献信息

• Fullerene complexes with divalent metal dithiocarbamates: structures, magnetic properties, and photoconductivity
  作者：D. V. Konarev、S. S. Khasanov、D. V. Lopatin、V. V. Rodaev、R. N. Lyubovskaya

  DOI：10.1007/s11172-007-0339-y

  日期：2007.11

  A series of complexes of fullerenes C60 and C70 with metal dithiocarbamates MII(R2dtc)2}·Cm (m = 60 or 70) and metal dithiocarbamates coordinated to nitrogen-containing ligands (L), MII(R2dtc)2)x·L}·C60 (x = 1 or 2), where M = Cu, Zn, Cd, Hg, Mn, or Fe, R = Me, Et, Prn, Pri, or Bun, L is 1,4-diazabicyclo[2.2.2]octane (DABCO), N,N′-dimethylpiperazine, or hexamethylenetetramine, were synthesized. The

  富勒烯 C60 和 C70 与金属二硫代氨基甲酸酯 MII(R2dtc)2}·Cm (m = 60 或 70) 和金属二硫代氨基甲酸酯与含氮配体 (L) 配位的一系列配合物，MII(R2dtc)2)x· L}·C60 (x = 1 或 2)，其中 M = Cu、Zn、Cd、Hg、Mn 或 Fe，R = Me、Et、Prn、Pri 或 Bun，L 为 1,4-二氮杂双环[2.2 .2] 辛烷 (DABCO)、N,N'-二甲基哌嗪或六亚甲基四胺被合成。二硫代氨基甲酸酯分子的形状与 C60 的球形形状在空间上相容，导致它们的 π 系统之间有效相互作用。所得化合物的特征在于富勒烯分子的分层或三维堆积。在 C60 复合物中，二硫代氨基甲酸铁 (II) 和二硫代氨基甲酸锰 (II) 以高自旋状态 (S = 2 和 5/2) 存在。MII(Et2dtc)2}2·Cm (M = Fe or Mn, m
• Goldberg, David P.; Montalban, Antonio Garrido; White, Andrew J. P., Inorganic Chemistry, 1998, vol. 37, # 12, p. 2873 - 2879
  作者：Goldberg, David P.、Montalban, Antonio Garrido、White, Andrew J. P.、Williams, David J.、Barrett, Anthony G. M.、Hoffman, Brian M.

  DOI：——

  日期：——
• Symmetry-Controlled Colloidal Nanocrystals:  Nonhydrolytic Chemical Synthesis and Shape Determining Parameters
  作者：Young-wook Jun、Jae-Hyun Lee、Jin-sil Choi、Jinwoo Cheon

  DOI：10.1021/jp052257v

  日期：2005.8.1

  Since inorganic nanocrystals exhibit unique shape-dependent nanoscale properties and can be utilized as basic building blocks for futuristic nanodevices, a systematic study on the shape control of these nanocrystals remains an important subject in materials and physical chemistry. In this feature article, we overview the recent progress on the synthetic development of symmetry-controlled colloidal nanocrystals of semiconductor and metal oxide, which are prepared through nonhydrolytic chemical routes. We describe their shape-guiding processes and illustrate the detailed key factors controlling their growth by examining various case studies of zero-dimensional spheres and cubes, one-dimensional rods, and quasi multidimensional structures such as disks, multipods, and stars. Specifically, the crystalline phase of nucleating seeds, surface energy, kinetic vs thermodynamic growth, and selective adhesion processes of capping ligands are found to be most crucial for the determination of the nanocrystal shape.