10H-苯并噻嗪,10-乙烯基- | 19210-66-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 中文名称: 10H-苯并噻嗪,10-乙烯基-
• 英文名称: 10-vinyl-10H-phenothiazine
• 英文别名: N-vinylphenothiazine；10-vinyl-phenothiazine；10-Vinyl-phenothiazin；10H-phenothiazine, 10-ethenyl-；10-ethenylphenothiazine
• CAS: 19210-66-3
• 化学式: C₁₄H₁₁NS
• 分子量: 225.314
• InChiKey: GMRFWZHQMKFNIQ-UHFFFAOYSA-N

物化性质

• 熔点：
  200 °C(Solv: chlorocyclohexane (542-18-7))
• 沸点：
  338.5±25.0 °C(Predicted)
• 密度：
  1.269±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  10H-苯并噻嗪,10-乙烯基- 在 对苯醌 作用下， 以 乙醇 为溶剂， 反应 10.0h， 以94%的产率得到吩噻嗪
  参考文献：
  名称：

  Vinylation of alcohols by 10-vinylphenothiazine

  摘要：

  DOI：

  10.1007/bf00953941
• 作为产物：
  描述：

  吩噻嗪 、 乙炔 在 氢化钾 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以14%的产率得到10H-苯并噻嗪,10-乙烯基-
  参考文献：
  名称：

  Kaupp, Gerd; Luebben, Doris; Sauerland, Olaf, Phosphorus, Sulfur and Silicon and the Related Elements, 1990, vol. 53, # 1-4, p. 109 - 120

  摘要：

  DOI：

文献信息

• Multifunctional Type II photoinitiators and curable compositions
  申请人：AGFA Graphics NV

  公开号：EP2130818A1

  公开（公告）日：2009-12-09

  A multifunctional Type II photoinitiator according to Formula (I): wherein X represents a structural moiety according to Formula (II): wherein: A represents a Norrish Type II initiating group; and L represents a divalent linking group positioning the Norrish Type II initiating group A and the CR2R3-group in a 1-5 to a 1-9 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 9 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks including the multifunctional Type II photoinitiator are also disclosed.

  根据公式(I)，一种多功能的二类光引发剂，其中X代表根据公式(II)的结构基团，其中：A代表Norrish Type II引发基团；L代表二价连接基团，定位Norrish Type II引发基团A和CR2R3基团在1-5到1-9位置，其中位置1被定义为A的芳香环或脂环中与L共价结合的第一个原子，位置5到9被定义为CR2R3基团的碳原子，L与之共价结合，但L不含胺基。还公开了包括这种多功能二类光引发剂的辐射固化组合物和油墨。
• AQUEOUS RESIN BASED INKJET INKS
  申请人：AGFA GRAPHICS NV

  公开号：US20170029639A1

  公开（公告）日：2017-02-02

  An inkjet ink includes a) an aqueous medium; and b) capsules composed of a polymeric shell surrounding a core; wherein the capsules are dispersed in the aqueous medium using a dispersing group covalently bonded to the polymeric shell; the core contains one or more chemical reactants capable of forming a reaction product upon application of heat and/or light; the polymeric shell includes a-polymer selected from the group consisting of polyureas, polyesters, polycarbonates, polyamides, and melamine based polymers and copolymers thereof; and the capsules have an average particle size of no more than 4 μm as determined by dynamic laser diffraction.

  一种喷墨墨水包括：a) 水性介质；和 b) 由聚合物壳包围的核心组成的胶囊；其中，使用共价键结合到聚合物壳上的分散基将胶囊分散在水性介质中；核心含有一个或多个化学试剂，能够在加热和/或光照作用下形成反应产物；聚合物壳包括从聚氨酯、聚酯、聚碳酸酯、聚酰胺和三聚氰胺基聚合物及其共聚物组成的α-聚合物；胶囊的平均粒径不超过4μm，通过动态激光衍射确定。
• NON-AQUEOUS PIGMENTED INKJET INKS
  申请人：Hoogmartens Ivan

  公开号：US20090270537A1

  公开（公告）日：2009-10-29

  A non-aqueous inkjet ink includes C.I. Pigment Yellow 150 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)A n - represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: W TPOAC >57 and N Amide ≧65 mol % wherein W TPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; N Amide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of W TPOAC and N Amide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH 3 COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.

  一种非水性喷墨墨水，包括C.I. Pigment Yellow 150和根据公式（I）的聚合物分散剂： 其中，T代表氢或聚合物终止基团；Z代表具有至少100的数均分子量的聚乙烯亚胺的残基；A代表氧烷基羰基基团；T-C（O）An-代表通过酰胺键与Z结合的TPOAC链；而n和m是整数，其中m至少为2，n为2至100之间； 聚合物分散剂满足以下条件： WTPOAC > 57，NAmide≧65 mol％ 其中，WTPOAC代表聚合物分散剂中TPOAC链的重量百分比与酰胺键的重量百分比之比；NAmide代表聚合物分散剂总氮含量基础上的酰胺键摩尔百分比；WTPOAC和NAmide的值是通过干燥燃烧聚合物分散剂确定的总氮含量以及在CH3COOH：THF（14.5：0.5）混合物中用0.1N的高氯酸水溶液进行电位滴定测定的胺含量计算出来的。
• POLYMERIZABLE TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110063388A1

  公开（公告）日：2011-03-17

  A polymerizable Type II photoinitiator according to Formula (I): wherein: A represents a Norrish Type II initiating group; L represents a divalent linking group positioning the Norrish Type II initiating group A and the CR2R3-group in a 1-5 to a 1-8 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 8 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks include the multifunctional Type II photoinitiator.

  一种可聚合的二型光引发剂，其化学式为（I）：其中：A代表Norrish二型引发基团；L代表二价连接基团，将Norrish二型引发基团A和CR2R3基团定位在1-5到1-8位置之间，其中位置1定义为A芳香或螺环的第一个原子，与L共价键合，位置5到8定义为CR2R3基团的碳原子，与L共价键合，但L不含胺基。辐射可固化组合物和油墨包括多功能二型光引发剂。
• MULTIFUNCTIONAL TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110069130A1

  公开（公告）日：2011-03-24

  A multifunctional Type II photoinitiator according to Formula (I): wherein X represents a structural moiety according to Formula (II): wherein: A represents a Norrish Type II initiating group; and L represents a divalent linking group positioning the Norrish Type II initiating group A and the CR2R3-group in a 1-5 to a 1-9 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 9 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks include the multifunctional Type II photoinitiator.

  一种多功能的二型光引发剂，其化学式为(I)：其中X代表化学式(II)的结构基团：其中：A代表Norrish二型引发基团；L代表二价连结基团，将Norrish二型引发基团A和CR2R3基团定位于1-5到1-9的位置，其中位置1定义为A芳香环或脂环中与L共价结合的第一个原子，位置5到9定义为CR2R3基团中与L共价结合的碳原子，但L不包含胺基。辐射可固化组合物和油墨包括该多功能二型光引发剂。

表征谱图