cis-[Ru(SO3)(OH2)(bpy)2] | 116663-18-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: cis-[Ru(SO3)(OH2)(bpy)2]
• 英文别名: Ru(bpy)2(SO3)(H2O)；cis-[Ru(SO₃)(OH₂)(bpy)₂]
• CAS: 116663-18-4
• 化学式: C₂₀H₁₈N₄O₄RuS
• 分子量: 511.523
• InChiKey: JVDSAGXVZFUYSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Ru(SO3)(OH2)(bpy)2] 、 四氰基乙烯 以 水 、 丙酮 为溶剂， 反应 4.0h， 以83%的产率得到[Ru(SO₃)(bpy)₂(tetracyanoethylene)]
  参考文献：
  名称：

  Synthesis, characterization and dielectric properties of [Ru(SO3)(bpy)2(TCNX)] complexes

  摘要：

  Na[Ru(SO3)(TCNQ)(bpy)(2)] and [Ru(SO3)(bpy)(2)(TCNE)] complexes were synthesized and characterized by means of electrochemical techniques and electronic, vibrational and electron paramagnetic resonance (EPR) spectroscopies. Vibrational data indicated a metallocyclopropane configuration for TCNE while TCNQ ligand is coordinated through the nitrile fragment. EPR data indicated the reduced state for the metal centers and for the TCNQ ligand (TCNQ(-)). The values of the potentials assigned to the redox processes associated to the TCNX ligands indicated a decrease in the electron transfer barrier. Data of dielectric measurements hinted that TCNQ containing complex is more polarized than the TCNE containing compound. Impedance spectroscopy measurements indicated a temperature-dependent relaxation process for both the complexes. However, for TCNQ containing complex, the results suggested the transition from long-range to short-range mobility. In addition, two values of activation energy (2.0 and 0.6 eV) were calculated for this complex suggesting a phase transition process. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.06.004
• 作为产物：
  描述：

  水 、 顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 sodium sulfite 以 乙醇 为溶剂， 反应 1.0h， 以88%的产率得到cis-[Ru(SO3)(OH2)(bpy)2]
  参考文献：
  名称：

  Synthesis, characterization and dielectric properties of [Ru(SO3)(bpy)2(TCNX)] complexes

  摘要：

  Na[Ru(SO3)(TCNQ)(bpy)(2)] and [Ru(SO3)(bpy)(2)(TCNE)] complexes were synthesized and characterized by means of electrochemical techniques and electronic, vibrational and electron paramagnetic resonance (EPR) spectroscopies. Vibrational data indicated a metallocyclopropane configuration for TCNE while TCNQ ligand is coordinated through the nitrile fragment. EPR data indicated the reduced state for the metal centers and for the TCNQ ligand (TCNQ(-)). The values of the potentials assigned to the redox processes associated to the TCNX ligands indicated a decrease in the electron transfer barrier. Data of dielectric measurements hinted that TCNQ containing complex is more polarized than the TCNE containing compound. Impedance spectroscopy measurements indicated a temperature-dependent relaxation process for both the complexes. However, for TCNQ containing complex, the results suggested the transition from long-range to short-range mobility. In addition, two values of activation energy (2.0 and 0.6 eV) were calculated for this complex suggesting a phase transition process. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.06.004