Pd2Cl2(phenylpyridinate)2 | 20832-86-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Pd2Cl2(phenylpyridinate)2
• 英文别名: [PdCl(2-phenylpyridinate)]2；[Pd(C6H4C5H4N)(μ-Cl)]2；[Pd(2-phenylpyridine-C(2),N')(μ-Cl)]2；palladium(2+);2-phenylpyridine;dichloride
• CAS: 20832-86-4
• 化学式: C₂₂H₁₆Cl₂N₂Pd₂
• 分子量: 592.128
• InChiKey: MRMLZQQDCFPCJH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Pd2Cl2(phenylpyridinate)2 、 potassium dihydrobis(pyrazol-1-yl)borate 以 丙酮 为溶剂， 以52%的产率得到Pd(2-phenylpyridine)(bis(pyrazol-1-yl)borate)
  参考文献：
  名称：

  Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)2-C,P}{(pz)3BH-N,N′} and Pd(C6H4C5H4N-C2,N′){(pz)3BH-N,N′}

  摘要：

  The cyclopalladated complexes Pd{2-CH2C6H4P(o-tol)(2)}{(pz)(n)BH4-n} and Pd(C6H4C5H4N-(C)2, N){(pz)(n)BH4-n} [n = 2. 3: pz = pyrazol-1-yl] have been synthesised from the corresponding halide bridged cyclometallated dimers: the crystal structures of the complexes for which n = 3 have been determined. The complexes Pd{2-CH2C6H4P(o-tol)(2)}{(pz)(n)BH4-n} (n = 2, 3) and [Pd{2-CH2C6H4P(o-tol)(2)}(mu-O2CMe)](2) are unreactive towards oxidation by alkyl halides, iodobenzene and 4-bromoanisole. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00576-7
• 作为产物：
  描述：

  盐酸 、 以 乙醚 为溶剂， 生成 Pd2Cl2(phenylpyridinate)2
  参考文献：
  名称：

  [Pd（E∩C）（C∩S）]型环金属化二硫代钯（II）钯配合物的合成与表征

  摘要：

  [Pd（E∩C）（S∩S）]类型的环金属化二硫化钯（II）配合物（其中E∩CH N，N'-二甲基苄胺，偶氮苯，4-MeOC 6 H 4 CHNC 6 H 4 Me -4，2-苯基吡啶或三- ö -tolylphosphine; S∩小号小号2 CNET 2或S 2 P（OR）2，R乙基，丙基ñ，镨我，卜ñ或卜小号）已经由合成[Pd（E∩C）（μX ）] 2（XCl，OAc）与二硫代磺酸钠或铵盐的反应。这些复合物通过元素分析来表征。红外，核磁共振（1 H和31 P）和质谱数据。的治疗[钯（N∩C）{S 2 P（OPR Ñ）2 }] [N∩ÇNC 5 H ^ 4 C 6 ħ 4或N（PH）NC 6 ħ 4 ]用无水HCl在二乙醚得到[Pd（EEC）（μ-Cl）] 2和游离的二硫代酸。当反应物与三苯基膦进行，被[钯（N∩C）{S之间建立动态平衡2 P（OPR Ñ）2 }]和[的Pd（PPh

  DOI：

  10.1016/s0022-328x(97)00361-6

文献信息

• Metal complexes of biologically important ligands, LXXXVII α-amino carboxylate complexes of palladium(II), iridium(III) and ruthenium(II) from chloro-bridged ortho-metallated metal compounds and [(OC)3Ru(Cl)(μ-Cl)]2
  作者：Reinhold Urban、Roland Krämer、Shahram Mihan、Kurt Polborn、Barbara Wagner、Wolfgang Beck

  DOI：10.1016/0022-328x(96)06166-9

  日期：1996.6

  azobenzene) and [(L)2Ir(μ-Cl)]2 (LH = 2-phenylpyridine) react with α-amino carboxylase to give the N,O-chelate complexes (L)Pd-t-NH2C(H)(R)CO2 and (L)2Ir-NH2C(H)(R)CO2. The chloro-bridged carbonyl complex [(OC)3Ru(Cl)(μ-Cl)]2 and prolinate afford the N,O-chelate (Cl)(OC)3Ru(prolinate). From the osmium complex [(OC)3Os(Cl)(μ-Cl)]2 and N,N-dimethylglycine methylester the ionic compound [HN(Me2)CH2CO2Et]+(Os(CO)3Cl3)−

  氯桥联的邻金属化化合物[（L）Pd（μ-Cl）] 2（HL = 2-苄基吡啶，2-苯基吡啶，偶氮苯）和[（L）2 Ir（μ-Cl）] 2（LH = 2-苯基吡啶）与α-氨基羧化酶反应生成N，O-螯合物（L）Pd-t-NH 2 C（H）（R）CO 2和（L）2 Ir-NH 2 C（H） （R）CO 2。氯桥联的羰基络合物[（OC）3 Ru（Cl）（μ-Cl）] 2和脯氨酸生成N，O-螯合物（Cl）（OC）3 Ru（脯氨酸）。由the络合物[（OC）3 Os（Cl）（μ-Cl）] 2和N，N得到-二甲基甘氨酸甲酯的离子性化合物[HN（Me 2）CH 2 CO 2 Et] +（Os（CO）3 Cl 3）-（25）。[2-（2-吡啶基甲基）苯基-C 1，N] Pd（脯氨酸盐），[（2-吡啶基苯基-C 1，N）2 Ir（脯氨酸盐）] a和25的结构由X-确定。射线衍射。
• Cyclometalated Complexes of Palladium(II) and Platinum(II):  <i>cis</i>-Configured Homoleptic and Heteroleptic Compounds with Aromatic C⌒N Ligands
  作者：Philippe Jolliet、Michel Gianini、Alex von Zelewsky、Gérald Bernardinelli、Helen Stoeckli-Evans

  DOI：10.1021/ic951466z

  日期：1996.1.1

  Pd(C&arcraise;N)(C'&arcraise;N'), were synthesized from Pd(C&arcraise;N)(2) bis-homoleptic complexes, which were converted by HCl into the dichloro-bridged compounds [Pd(C&arcraise;N)Cl](2). By addition of Et(2)S, the Pd(C&arcraise;N)(Et(2)S)Cl complexes were formed, which were allowed to react with Li(C'&arcraise;N'), yielding M(C&arcraise;N)(C'&arcraise;N') compounds. An alternative way for obtaining the

  钯（II）和铂（II）的双同位配合物M（C＆arcraise; N）（2），其中C＆arcraise; N是苯并[h]喹啉（H-bhq），2-苯基吡啶（H-phpy），2通过金属交换制备了-（2'-苯并噻吩基）吡啶（H-bpy），2-（2'-噻吩基）喹啉（H-thq）和2-（2'-噻吩基）吡啶（H-thpy） M（Et（2）S）（2）Cl（2）的锂化配体C＆arcraise; N。从Pd（C＆arcraise; N）（2）双同型配合物合成钯（II）双-杂合型配合物Pd（C＆arcraise; N）（C'＆arcraise; N'），然后将其通过HCl转化为二氯桥联化合物[Pd（C＆arcraise; N）Cl]（2）。通过添加Et（2）S，形成Pd（C＆arcraise; N）（Et（2）S）Cl络合物，使其与Li（C'＆arcraise; N'）反应，生成M（C＆arcraise; N ）（C'＆arcraise;
• Kulikova; Balashev; Kvam, Russian Journal of General Chemistry, 2000, vol. 70, # 2, p. 163 - 170
  作者：Kulikova、Balashev、Kvam、Songstad

  DOI：——

  日期：——
• New cyclometalated palladium(II) complexes with iminophosphines
  作者：Gregorio Sánchez、José L. Serrano、M.A. Moral、José Pérez、Elies Molins、Gregorio López

  DOI：10.1016/s0277-5387(99)00229-6

  日期：1999.10

  The synthesis of new cyclometalated compounds of palladium(Il) with the mixed-donor bidentate ligands o-Ph2PC6H4-CH=NR is described. Two series of complexes [Pd(CxN)(o-Ph2PC6H4-CH=NR)][PF6] have been prepared using either azobenzene or 2-phenylpyridine as cyclometalated ligands [CxN=azobenzene (azb); R=Me (1a), Et (2a), " Pr (39), 'Pr (4a), 'Bu (5a), Ph (6a), NH-Me (7a); CxN=2-phenylpyridine (phpy); R=Me (Ib), Et (2b)," Pr (3b),'Pr (4b),'Bu (5b), Ph (6b), NK-Me (7b)]. The new complexes were characterized by partial elemental analyses and spectroscopic methods (IR, FAB,H-1 and P-31 NMR). The molecular structures of compounds 2a (monoclinic, P 2(1)/n) and Ib (monoclinic, C 2/c) have been determined by a single-crystal diffraction study. In both cases this technique revealed the relative trans configuration between the phosphorus atom and the nitrogen atom of the ortho-metalated ligand. (C) 1999 Elsevier Science Ltd. All rights reserved.