bromo-chloro-acetyl chloride | 38282-29-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: bromo-chloro-acetyl chloride
• 英文别名: Brom-chlor-acetylchlorid；Chlor (Brom)acetylchlorid；2-bromo-2-chloroacetyl chloride
• CAS: 38282-29-0
• 化学式: C₂HBrCl₂O
• 分子量: 191.839
• InChiKey: YVUFDPUKVYAZNX-UHFFFAOYSA-N

物化性质

• 沸点：
  135.7±20.0 °C(Predicted)
• 密度：
  2.019±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bromo-chloro-acetyl chloride 在 氨 作用下， 生成 一溴一氯乙酰胺
  参考文献：
  名称：

  Bone Mineral Density Measurements in Dialysis Patients

  摘要：

  DOI：

  10.1046/j.1525-139x.2001.00057-2.x
• 作为产物：
  描述：

  (E)-1,2-dichloro-1-ethoxy-ethene 在 溴 作用下， 生成 bromo-chloro-acetyl chloride
  参考文献：
  名称：

  Vanderstichele, Journal of the Chemical Society, 1923, vol. 123, p. 1228

  摘要：

  DOI：

文献信息

• Temperature-dependent rate coefficient measurements for the reaction of bromine atoms with trichloroethene, ethene, acetylene, and tetrachloroethene in air
  作者：Bj�rn Ramacher、John J. Orlando、Geoffrey S. Tyndall

  DOI：10.1002/1097-4601(200103)33:3<198::aid-kin1014>3.0.co;2-z

  日期：2001.3

  In this article, rate coefficients for the reaction of Br atoms with a series of unsaturated species (trichloroethene, k(1); ethene, k(2); acetylene, k(3); and tetrachloroethene, k(4)) are reported in 700 Torr air over the temperature range 228-298 K. The data were obtained in a temperature-regulated environmental chamber/FTIR spectrometer system, using standard relative rate techniques, with the reaction of Br with CH2O and CH3CHO as the reference reactions. Room-temperature values for k(1) through k(4) were found to be 1.56 x 10(-13), 1.23 x 10(-13) 2.86 x 10(-14), and <1.2 x 10(-16) cm(3) molecule(-1) s(-1), respectively, in reasonable accord with previously available data. At 240 K, values of k(1) = 1.77 x 10(-12), k(2) = 5.76 x 10(-13), k(3) = 3.97 x 10(-14), and k(4) = 3.22 x 10(-15) cm(3) molecule(-1) s(-1) are reported. These k(2) and k(3) values are 2-3 times lower than those currently in use, which are obtained by extrapolation of previous measurements made over the range 298-350 K [Barnes et at.. 1989]. An investigation of the mechanism of the Br-atom-initiated oxidation of acetylene, trichloroethene, and tetrachloroethene was also conducted as a function of temperature. Although no temperature dependence to the product yields was observed for any of the systems studied, the product distributions were found to be altered by the presence of NOx in the case of trichloroethene and tetrachloroethene. An anomalously low rate coefficient for the reaction of Br with glyoxal (HC(O)CHO, a product of acetylene oxidation), k(17) = 1.1 x 10(-14) cm(3) molecule(-1) s(-1), is also reported. (C) 2001 John Wiley & Sons, Inc.
• FTIR study of the Cl- and Br-atom initiated oxidation of trichloroethylene
  作者：V. Catoire、P. A. Ariya、H. Niki (Deceased)、G. W. Harris

  DOI：10.1002/(sici)1097-4601(1997)29:9<695::aid-kin7>3.0.co;2-p

  日期：——
• CCXIV.—Dichloroacetates and chlorobromoacetates from αβ-dichlorovinyl ethyl ether
  作者：Holland Crompton、Phyllis Mary Triffitt

  DOI：10.1039/ct9211901874

  日期：——
• Backer; Mook, Journal of the Chemical Society, 1928, p. 2127
  作者：Backer、Mook

  DOI：——

  日期：——
• Bone Mineral Density Measurements in Dialysis Patients
  作者：Catherine Stehman‐Breen

  DOI：10.1046/j.1525-139x.2001.00057-2.x

  日期：2001.5