[MnCl₂(Py)₂] | 14872-18-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [MnCl₂(Py)₂]
• 英文别名: [MnCl₂(pyridine)₂]；bis(pyridine)manganese(II) chloride；Mn(py)2Cl2；Manganese(2+);pyridine;dichloride
• CAS: 14872-18-5
• 化学式: C₁₀H₁₀Cl₂MnN₂
• 分子量: 284.047
• InChiKey: DSKNRMAVTPVASP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.54
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [MnCl₂(Py)₂] 、 sodium N,N-diethyldithiocarbamate 以 甲醇 为溶剂， 以54%的产率得到Mn(II)(pyridine)2(diethyldithiocarbamato)2
  参考文献：
  名称：

  Synthesis, Characterization and Thermal Studies of Bipyridine Metal Complexes Containing Different Substituted Dithiocarbamates

  摘要：

  Complexes of the type [Mpy(2)(dedtc)(2)], and [Mpy(2)(dpdtc)(2)], where M = Mn(II), Fe(II), Co(II), Ni( II), Cu(II), Zn(II), py = pyridine, dedtc = diethyldithiocarbamate and dpdtc = diphenyl-dithiocarbamate, have been synthesized and characterized by elemental analyses, magnetic susceptibility, TGA/DSC and IR in the solid-state, and electronic spectroscopy and conductivity measurement studies in solution. The dithiocarbamato moiety has been found to be symmetrically bonded to the metal. The complexes are proposed to have a distorted-octahedral structure. The ligand field parameters 10 Dq, B and beta have also been evaluated. The value of b indicates a considerable orbital overlap in the complexes. A two-stage decomposition pattern leading to the formation of respective metal sulfide as the end-product has been observed in all the complexes. Their molar conductance indicated them to be non-electrolyte in nitrobenzene.

  DOI：

  10.1081/sim-200066980
• 作为产物：
  描述：

  dichloromanganese;pyridine 以 solid 为溶剂， 生成 [MnCl₂(Py)₂]
  参考文献：
  名称：

  摘要：

  The object of this work is the quantitative explanation of linear correlation between activation energy (E), initial decomposition temperature (Ti) and ionic potential (Vi), observed for thermal degradation of some complexes of transitional metals.The proposed model allowed the evaluation of characteristic parameter proportional to the activation free enthalpy and also the variation of effective electrical charge (DeltaQ*) of ligand, in the formation process of the activated complex.These results are satisfactory, taking into account that we utilized many simple hypotheses for deduction of Arrhenius equation.

  DOI：

  10.1023/a:1013177220283

文献信息

• Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands
  作者：Evan R. King、Theodore A. Betley

  DOI：10.1021/ja903997a

  日期：2009.10.14

  Transition metal complexes (Mn --> Zn) of the dipyrromethane ligand, 1,9-dimesityl-5,5-dimethyldipyrromethane (dpm), have been prepared. Arylation of the dpm ligand alpha to the pyrrolic nitrogen donors limits the accessibility of the pyrrole pi-electrons for transition metal coordination, instead forcing eta(1),eta(1) coordination to the divalent metal series as revealed by X-ray diffraction studies. Structural

  已经制备了二吡咯甲烷配体 1,9-二甲基-5,5-二甲基二吡咯甲烷 (dpm) 的过渡金属配合物 (Mn --> Zn)。X 射线衍射研究表明，dpm 配体 α 与吡咯氮供体的芳基化限制了吡咯 π 电子对过渡金属配位的可及性，而不是迫使 eta(1),eta(1) 与二价金属系列配位. (dpm)Mn(II)(py)(2)、(dpm)Fe(II)(py)(2) 和 (dpm)Co(2) 的双吡啶加合物的结构和磁性表征 (SQUID, EPR) II)(py)(2) 揭示每个二价离子在固态下是高自旋和假四面体，而 (dpm)Ni(II)(py)(2) 是低自旋并采用方形平面几何. (dpm)M(II)(py)(2) 系列上的差分脉冲伏安法揭示了一种完全基于配体的常见双电子氧化途径，对二价金属结合、其几何形状或在 dpm 框架内的自旋状态不变。后一种观察表明，来自 dpm 结构的完全填充的基于配体的轨道位于部分填充的金属
• Hydrosilylation of Aldehydes and Ketones Catalyzed by a 2-Iminopyrrolyl Alkyl-Manganese(II) Complex
  作者：Tiago F. C. Cruz、Luís F. Veiros、Pedro T. Gomes

  DOI：10.1021/acs.inorgchem.1c03621

  日期：2022.1.17

  that of complex 2 corresponds to a monomer with a distorted tetrahedral coordination geometry. Complex 2 proved to be a very active precatalyst for the atom-economic hydrosilylation of several aldehydes and ketones under very mild conditions, with a maximum turnover frequency of 95 min–1, via a silyl-Mn(II) mechanistic route, as asserted by a combination of experimental and theoretical efforts, the respective

  提出了一种定义明确且非常活跃的单组分锰 (II) 催化剂体系，用于醛和酮的氢化硅烷化。一、5-( 2,4,6- i Pr 3 C 6 H 2 )-2-[ N -( 2,6- i Pr 2 C 6 H 3 )甲亚氨基]吡咯钾( KL )与[ MnCl 2 (Py) 2 ] 得到双核 2-亚氨基吡咯基锰 (II) 氯化吡啶络合物 [Mn 2 κ 2 N , N' -5-(2,4,6- i Pr 3 C 6 H2 )-NC 4 H 2 -2-C(H)=N(2,6- i Pr 2 C 6 H 3 )} 2 (Py) 2 (μ-Cl) 2 ] 1。随后，配合物1与 LiCH 2 SiMe 3的烷基化反应得到相应的 (三甲基甲硅烷基)甲基-Mn(II)配合物 [Mnκ 2 N , N' -5-(2,4,6- i Pr 3 C 6 ) H 2 )-NC 4 H 2 -2-C(H)=N(2,6- i Pr
• Effects of methyl group substitution on metal-coordinated cyclopentadienyl rings. Core and valence ionizations of methylated tricarbonyl(.eta.5-cyclopentadienyl)metal complexes
  作者：David C. Calabro、John L. Hubbard、Charles H. Blevins、Andrew C. Campbell、Dennis L. Lichtenberger

  DOI：10.1021/ja00413a010

  日期：1981.11

  Gas-phase He I, He II, and Mg K..cap alpha.. photoelectron spectra are reported for molecules of the type (eta/sup 5/-C/sub 5/H/sub 5-n/-(CH/sub 3/)/sub n/)M(CO)/sub 3/ where n = 0, 1, 5 and M = Mn, Re. The influence of methyl groups on the cyclopentadienyl ring is monitored by shifts in both core and valence ionization energies. This enables effective separation of electron density transfer (inductive)

  报告了 (eta/sup 5/-C/sub 5/H/sub 5-n/-(CH/ sub 3/)/sub n/)M(CO)/sub 3/ 其中 n = 0, 1, 5 和 M = Mn, Re。甲基对环戊二烯基环的影响通过核和价电离能的变化来监测。这能够有效分离电子密度转移（感应）和环-甲基轨道重叠（超共轭）效应。虽然发现环 e/sub 1/'' 电离的转移主要是超共轭效应，但金属价电离的转移基本上完全是由电子密度向金属原子的转移引起的。与锰配合物相比，这种增加的密度的很大一部分转移到铼配合物中的羰基，表明第三排原子具有更大的反键能力。铼配合物的主要金属电离之一上存在振动精细结构，提供了广泛的 Re-CO 反键的进一步证据。这种结构是对称金属-碳（CO）伸缩模式的振动级数。在该频带中观察到的长振动进程和正离子中 MC 拉伸的频率是更多»相当大的..pi..从金属到羰基的反键的直接证据。在自旋轨道分裂铼
• Synthesis and Properties of Iron(II) and Manganese(II) Complexes Derived from a Topologically Constrained Pentadentate Ligand
  作者：Simon Collinson、Nathaniel W. Alcock、Ahasuya Raghunathan、Pawan K. Kahol、Daryle H. Busch

  DOI：10.1021/ic981410f

  日期：2000.2.1

  Because of its cross-bridged topology it exhibits a relatively rigid preorganized conformation especially appropriate to complex formation, as shown by the crystal structure of the monoprotonated ligand salt, HL1ClH2O [orthorhombic, P212121, a = 9.4405(5) A, b = 13.3617(5) A, c = 16.710(1) A]. The complexes of L1 with both iron(II) and manganese(II) have been characterized, including the crystal structures

  合成了新型的双环五齿配体5-甲基-1,5,9,24,25-五氮杂五环[7.7.7.5.5]戊二十烷11,13,15,18（25），20,22-己烯（L1）。由于其跨桥拓扑结构，它表现出相对较硬的预组织构象，特别适合于复合物的形成，如单质子化配体盐HL1ClH2O的晶体结构所示[斜方晶系，P212121，a = 9.4405（5）A，b = 13.3617（ 5）A，c = 16.710（1）A]。L1与铁（II）和锰（II）的配合物已被表征，包括[FeL1CH3CN] [FeCL4]和[MnL1Cl] [PF6]的晶体结构[单斜晶系，P21 / n，a = 10.0460（5） A，b = 19.237（9）A，c = 15.6254（8）A，beta = 95.97（2）度，a = 7.745（2）A，b = 22.786（4）A，c = 14.639（4）A， beta = 105.0
• Ligand-Centered Redox Activity: Redox Properties of 3d Transition Metal Ions Ligated by the Weak-Field Tris(pyrrolyl)ethane Trianion
  作者：Graham T. Sazama、Theodore A. Betley

  DOI：10.1021/ic100028y

  日期：2010.3.1

  First-row transition metal complexes of the tris(pyrrolyl)ethane (tpe) trianion have been prepared. The tpe ligand was found to coordinate in a uniform η1,η1,η1-coordination mode to the divalent metal series as revealed by X-ray diffraction studies. Magnetic and structural characterization for complexes of the type [(tpe)MII(py)][Li(THF)4] (M: Mn, Fe, Co, Ni) reveal each divalent ion to be high-spin

  制备了三（吡咯基）乙烷（tpe）三阴离子的第一行过渡金属配合物。所述配体TPE发现以均匀协调η 1，η 1，η 1种通过X射线衍射研究所揭示-coordination模式到二价金属系列。[[tpe] M II（py）] [Li（THF）4 ]（M：Mn，Fe，Co，Ni）型配合物的磁性和结构表征显示，每个二价离子具有高自旋性并具有畸变固态的三角-单锥体几何。吡啶配体由于与配体均基取代基的稳定的π-堆积相互作用而从分子C 3轴显着倾斜地结合。[（tpe）M II的循环伏安法（py）] -系列揭示了一个完全基于配体的不可逆的氧化途径，对于二价金属键是不变的。后一个观察结果表明，在tpe构建体中，完全填充的基于配体的轨道在能量上最接近电化学实验，类似于其二吡咯甲烷类似物。[（tpe）Fe II（py）] -的化学氧化产生一种产物，其中配体解离了一个吡咯（在tpe氧化和H原子抽象之后），并结合了第二当量的吡啶以形成中性的四面体Fe