(3-CH3CH2O2CC6H4)2Hg | 15245-46-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-CH3CH2O2CC6H4)2Hg
• 英文别名: bis-(3-ethoxycarbonyl-phenyl)-mercury；[Hg(3-carboxyethylphenyl)2]；3.3'-Mercurio-di-benzoesaeure-diaethylester；Bis-(3-aethoxycarbonyl-phenyl)-quecksilber
• CAS: 15245-46-2
• 化学式: C₁₈H₁₈HgO₄
• 分子量: 498.929
• InChiKey: YLHFOKUMGUDLBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.07
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (3-CH3CH2O2CC6H4)2Hg 在 氢氧化钾 作用下， 生成 bis-(3-carboxy-phenyl)-mercury
  参考文献：
  名称：

  Nesmejanow; Makarowa, Zhurnal Obshchei Khimii, 1931, vol. 1, p. 598,612

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 铜 、 丙酮 作用下， 生成 (3-CH3CH2O2CC6H4)2Hg
  参考文献：
  名称：

  Nesmejanow; Makarowa, Zhurnal Obshchei Khimii, 1931, vol. 1, p. 598,612

  摘要：

  DOI：

文献信息

• Facile syntheses of homoleptic diarylmercurials via arylboronic acids
  作者：David V. Partyka、Thomas G. Gray

  DOI：10.1016/j.jorganchem.2008.10.024

  日期：2009.1

  A general procedure for the syntheses of diarylmercurials is presented. Reactions proceeded in isopropanol in the presence of a base and arylboronic acid. With one exception, all reactions proceeded in good to excellent yields, and this procedure was applicable to a variety of aromatic and heteroaromatic boronic acids. Products were characterized by multinuclear NMR spectroscopy and microanalysis, and investigated by DFT calculations. The structure of di(4-pyridyl) mercury (6) was further authenticated by X-ray crystallography. Combined with previous work on the formation of arylgold(I) complexes via arylboronic acids, this procedure may be generally useful for the arylation of late transition metals. (C) 2008 Elsevier B. V. All rights reserved.
• Nesmeyanov, A. N.; Vanchikov, A. N.; Lisichkina, I. N., Doklady Chemistry, 1980, vol. 255, p. 594 - 598
  作者：Nesmeyanov, A. N.、Vanchikov, A. N.、Lisichkina, I. N.、Lazarev, V. V.、Tolstaya, T. P.

  DOI：——

  日期：——
• Nesmejanow; Makarowa, Zhurnal Obshchei Khimii, 1931, vol. 1, p. 598,612
  作者：Nesmejanow、Makarowa

  DOI：——

  日期：——