一氧化磷 | 14452-66-5

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 中文名称: 一氧化磷
• 英文名称: phosporus oxide
• 英文别名: phosphorus monoxide；phosphorus oxide；Oxophosphanyl
• CAS: 14452-66-5
• 化学式: OP
• 分子量: 46.9732
• InChiKey: LFGREXWGYUGZLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  一氧化磷 、 氧气 以 gaseous matrix 为溶剂， 生成 phosphorus oxide oxide
  参考文献：
  名称：

  Lifetimes and quenching of B ²Σ⁺ PO by atmospheric gases

  摘要：

  Pulsed laser excited fluorescence in the B 2Σ+ ← X 2π system of gas phase PO was used to measure the lifetime for v′=0 of the B state. Rotationally resolved measurements for a few selected J′ levels, at Ar or He carrier gas pressures of ∼2 Torr, reveal no dependence of the lifetime on the rotational level excited. Earlier measurements of relative fluorescence intensities in the v′=0 vibrational progression were reinterpreted to extract the dependence of the electronic transition moment on internuclear distance. Using this transition moment, no lifetime dependence on rotational level is to be expected, even at low pressures. Rate constants for quenching of the B state PO by N2, O2, CO2, and H2O, and upper limits thereof for He and Ar are reported. O2 was found to react with ground state PO. A crude measurement of the rate constant was performed. The result is compared to two other known measurements. The rate constant is in excellent agreement with the previous measurement, but in poor agreement with that of a concurrent study. Further work is required to determine the reason for the discrepancy. A cathode ray–vidicon type waveform digitizer was found to lend itself readily to the lifetime measurements, wherein a low repetition rate laser was used. Unfortunately, it was discovered that small nonlinearities (∼1% of full scale) in the digitizer response have a marked effect on the fits to the exponential lifetime decays and, especially, the quenching rate constants. We believe this problem is not commonly recognized. A simple method for calibration of this type of digitizer and removal of these effects is presented.

  DOI：

  10.1063/1.450136
• 作为产物：
  描述：

  三氯氧磷 以 gaseous matrix 为溶剂， 生成 一氧化磷
  参考文献：
  名称：

  PS自由基的红外二极管激光光谱

  摘要：

  摘要 利用塞曼和放电调制的二极管激光光谱仪观测了X 2 Π, 态中PS 自由基的基带。自由基是通过在 PSCl 3 和 He 混合物中放电产生的。根据对观测光谱的分析，谱带原点和平衡核间距离分别确定为 ν 0 = 733.5583(5) cm -1 和 re = 1.897 7405(45) A ，括号中为三个标准偏差。

  DOI：

  10.1016/0022-2852(88)90285-8
• 作为试剂：
  描述：

  5-甲基-1,3-二氢苯并咪唑-2-酮 、 三氯氧磷 在 盐酸 、 ice 、 水 、 2-氯-5-甲基-(9ci)-1H-苯并咪唑 、 甲醇 、 一氧化磷 作用下， 反应 15.0h， 生成 2-氯-5-甲基-(9ci)-1H-苯并咪唑
  参考文献：
  名称：

  Color liquid crystal display and compensation panel

  摘要：

  本发明的一个方面提供了一种具有光学各向异性补偿面板，其具有光谱可控的折射率色散。该补偿面板包括至少一层基于有序客体-宿主体系的光学各向异性层。客体-宿主体系包括一个各向异性宿主基质，其中包括一种在可见光谱范围内对电磁辐射透明的有机化合物，以及具有客体颗粒的客体组分。在本发明的另一个方面，提供了一种制备所述光学各向异性补偿面板的方法。在本发明的另一个实施例中，提供了一种具有所述补偿面板的液晶显示器。

  公开号：

  US08142863B2

文献信息

• Matrix reactions of P2 and O3 molecules
  作者：Zofia Mielke、Matthew McCluskey、Lester Andrews

  DOI：10.1016/0009-2614(90)85420-h

  日期：1990.1

  Matrix reactions of P2 and isotopic ozone molecules have been studied using both heated GaP and discharge of P4 as sources of P2. Isotopic shifts and multiplets support identification of PO, PO2, P2O, P2O2, P2O3, P2O4, P2O5 and PO2− in these experiments.

  已经使用加热的GaP和放电的P 4作为P 2的来源研究了P 2和同位素臭氧分子的基质反应。同位素位移和多重支持标识PO，PO的2，P 2 O，P 2 ö 2，P 2 ö 3，P 2 ö 4，P 2 ö 5和PO 2 -在这些实验中。
• A Study of the Products of the Reaction of Phosphorus and Dioxygen
  作者：Charles W. Bauschlicher、Mingfei Zhou、Lester Andrews

  DOI：10.1021/jp993623b

  日期：2000.4.1

  The products of the reaction of laser-ablated red phosphorus and dioxygen have been studied using experiment and theory. The bands at 480.3 and 1273.3 cm-l, previously attributed to PO3 in the matrix isolation IR experiments, are reassigned to PO3-. Also observed in experiment are PO2, PO2-, P2O, OPOPO, P4, and higher oxides.

  用实验和理论研究了激光烧蚀红磷和分子氧的反应产物。在 480.3 和 1273.3 cm-l 处，先前在基质隔离 IR 实验中归因于 PO3 的波段被重新分配给 PO3-。实验中还观察到 PO2、PO2-、P2O、OPOPO、P4 和更高的氧化物。
• Detection of the infrared laser spectrum of the PO2 radical in the gas phase
  作者：Hai-Bo Qian、Paul B. Davies、Imtiaz K. Ahmad、Peter A. Hamilton

  DOI：10.1016/0009-2614(95)00128-q

  日期：1995.3

  The infrared laser absorption spectrum of the PO2 free radical has been detected in the reaction of oxygen atoms with white phosphorus. Over 300 lines of the ν3 fundamental band of the 2A1 ground state have been measured and assigned between 1300 and 1345 cm−1. Rotational, centrifugal distortion and spin-rotation constants for the ν3 = 1 level have been obtained from fitting the lines to an asymmetric

  在氧原子与白磷的反应中已检测到PO 2自由基的红外激光吸收光谱。超过300行的ν 3所述的基本频带2阿1个基态已经测量和1300和1345厘米之间分配-1。旋转的，用于离心畸变和自旋旋转常数ν 3 = 1电平已经从线拟合到不对称转子哈密顿量，与在它们的微波/激光磁共振值所保持的基态常数而获得。带的原点是1327.53452（69）cm -1。
• Infrared diode laser spectroscopy of the PO radical
  作者：James E Butler、Kentarou Kawaguchi、Eizi Hirota

  DOI：10.1016/0022-2852(83)90013-9

  日期：1983.9

  Abstract Vibration-rotation transitions of the PO radical in the X 2 Π r state have been observed by a tunable infrared diode laser spectrometer. The analysis of the observed spectra gave the molecular constants in the v = 1 state and the band origin to be B = 0.7250107(36), D = 1.0253(60) × 10 −4 , A J = 0.997(24) × 10 −4 , p = 0.006323(33), A 1 - A 0 = 0.16354(78), and ν 0 = 1220.24901(43), all in

  摘要 PO 自由基在X 2 Π r 态的振动-旋转跃迁已被可调谐红外二极管激光光谱仪观测到。对观察到的光谱的分析给出了 v = 1 状态下的分子常数和带原点为 B = 0.7250107(36), D = 1.0253(60) × 10 -4 , AJ = 0.997(24) × 10 -4 , p = 0.006323(33), A 1 - A 0 = 0.16354(78), and ν 0 = 1220.24901(43)，均以 cm -1 为单位，括号内为三个标准误差，其中 v = 0 参数固定为先前报告的值。平衡核间距离确定为 re = 1.476370(15) A 。
• Kinetic studies of ground-state phosphorus atoms
  作者：Michael A. A. Clyne、Yoko Ono

  DOI：10.1039/f29827801149

  日期：——

  The kinetics of reactions (at 293 K) involving ground-state phosphorus atoms P(4S3/2) have been studied using resonance-fluorescence detection in a discharge–flow system for the first time. P atoms were formed by means of a discharge in helium with a trace of phosphorus trihalide. The rate constants k(cm3 molecule–1 s–1)(1σ) have been determined using pseudo-first-order kinetic analysis for the following

  涉及基态磷原子P（4 S 3/2）的反应动力学（在293 K下）是首次在放电-流动系统中使用共振荧光检测进行了研究。通过氦气中微量三卤化磷的放电形成P原子。速率常数k（cm 3分子–1 s –1）（1σ）已通过以下一级反应的拟一级动力学分析确定：[图形省略] k的值与先前发表的研究。已经对导致差异的可能原因进行了调查。