二苯基氯化铅 | 2117-69-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二苯基氯化铅
• 英文名称: diphenyllead(IV) dichloride
• 英文别名: diphenyllead dichloride；diphenyllead chloride；Ph₂PbCl₂；Diphenylbleidichlorid
• CAS: 2117-69-3
• 化学式: C₁₂H₁₀Cl₂Pb
• 分子量: 432.317
• InChiKey: VCYWRKSVJFJVTB-UHFFFAOYSA-L

物化性质

• 熔点：
  249-251°C (dec.)

计算性质

• 辛醇/水分配系数(LogP)：
  2.72
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 安全说明：
  S45,S53
• 危险类别码：
  R20/22,R61,R50/53,R33
• 海关编码：
  2931900090
• 危险品运输编号：
  UN 2291

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : DICHLORODIPHENYLLEAD
CAS-No. : 2117-69-3
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Reproductive toxicity (Category 1A)
Acute toxicity, Inhalation (Category 4)
Acute toxicity, Oral (Category 4)
Specific target organ toxicity - repeated exposure (Category 2)
Acute aquatic toxicity (Category 1)
Chronic aquatic toxicity (Category 1)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
May cause harm to the unborn child. Possible risk of impaired fertility. Harmful by inhalation and if
swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H360Df May damage the unborn child. Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard none
Statements
Restricted to professional users.
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R61 May cause harm to the unborn child.
R20/22 Also harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R62 Possible risk of impaired fertility.
S-phrase(s)
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/ Safety
data sheets.
Restricted to professional users.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C12H10Cl2Pb
Molecular Weight : 432,31 g/mol
Component Concentration
DICHLORODIPHENYLLEAD
CAS-No. 2117-69-3 -
Index-No. 082-001-00-6

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Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas, Lead oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Avoid exposure - obtain special
instructions before use.
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Presumed human reproductive toxicant
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
no data available
Potential health effects
Inhalation Harmful if inhaled. May cause respiratory tract irritation.
Ingestion
Harmful if swallowed.
Skin Harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: TP4501000

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
Biodegradability Result: - According to the results of tests of biodegradability this product is not
readily biodegradable.
Remarks: no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: 2811 IMDG: 2811 IATA: 2811
UN proper shipping name
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (DICHLORODIPHENYLLEAD)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. (DICHLORODIPHENYLLEAD)
IATA: Toxic solid, organic, n.o.s. (DICHLORODIPHENYLLEAD)
Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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SECTION 15 - REGULATORY INFORMATION
N/A

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  二苯基氯化铅 在 C₄H₃OCHNNHCSNH₂ 作用下， 以 甲醇 为溶剂， 以70-80的产率得到diphenyllead(IV)(C4H3OCHNNCSNH2)2
  参考文献：
  名称：

  Dixit, Purnima; Singh, Kiran; Tandon, J. P., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1989, vol. 28, # 10, p. 909 - 911

  摘要：

  DOI：
• 作为产物：
  描述：

  diphenyldicyclopentadienylplumbane 在 HCl 作用下， 以 苯 为溶剂， 生成 二苯基氯化铅
  参考文献：
  名称：

  （环戊二烯基）苯基铅（IV）化合物的化学

  摘要：

  黄色空气稳定的（环戊二烯基）苯基-铅（IV）化合物，PbPh 4- Ñ（CP）ñ [ Ñ = 1或2，CP = C 5 H ^ 5 ]，已经通过相应的苯基的反应合成氯化铅（IV）和环戊二烯化锂在乙醚中的溶液。PbPh 3（cp）的晶体是单斜晶体，空间群P 2 1 / c，其中a = 9.5426，b = 12.3843，c = 16.1714Å，β= 102.3358°和Z＝ 4，并且包括具有扭曲的四面体几何形状的离散的非相互作用分子。Pb–C（cp）键的距离[2.30（2）Å]明显长于Pb–C（Ph）的距离[平均2.22（2）Å]，表明该键的强度明显减弱。环戊二烯基环（平面）的环内CC键与远离铅的碳原子上的π电子密度浓度一致。PbPh 3（cp）与乙酸，苯硫酚和咪唑的反应继续进行Pb–C（cp）键裂解，得到PbPh 3（O 2 CMe），PbPh 3（SPh）和PbPh 3（N 2 C 3

  DOI：

  10.1039/dt9820001055

文献信息

• Back to the Coordination Modes of the Thiosemicarbazonate Chain: New Insights from Diorganolead(IV) and Lead(II) Derivatives of Isatin‐3‐thiosemicarbazone
  作者：José S. Casas、Noelia Casanova、María S. García‐Tasende、Agustín Sánchez、José Sordo、Ángeles Touceda、Saulo Vázquez

  DOI：10.1002/ejic.201000669

  日期：2010.11

  kinetically controlled O,N 2 ,S isomer formed first due to the rigidity of the ligand. If the compound remains in solution, slow partial evolution to the O,N 3 ,S isomer occurs. DFT calculations predict that [Pb(OAc)(N 3 -L 1 )] is slightly more stable than [Pb(OAc)(N 2 -L 1 )] both in the gas phase and in DMSO solution. The calculations also modelled structures for the two isomers close to those obtained

  在赤道平面上具有顶端苯基和 O,N x ,S-配位的 L x- 和异双齿 AcO - 配体。在 [PbPh 2 (OAc)(N 2 -L 1 )]·MeOH·EtOH 中，(N 2 -L 1 ) - 配体与金属形成四元和六元螯合环，而在 PbPh 2 ( OAc)(N 3 -L 2 )]·H 2 O 由(N 3 -L 2 ) - 形成的两个螯合环是五元的。从同一溶液中分离出的 Pb II 复合物 [Pb(OAc)(N 2 -L 1 )] 和 [Pb(OAc)(N 3 -L 1 )] 是连接异构体。这些化合物具有相当不规则的立体化学，表明存在立体化学活性的孤电子对；在 [Pb(OAc)(N 2 -L 1 )] 中，(L 1 ) - 配体是 O,N 2 ,S-配位，在 [Pb(OAc)(N 3 -L 1 )] 中，该配体是 O， N 3 ,S-配位。通过 1 H 和 13 C NMR 光谱分析
• Permetalloplumbanes: Preparation of [Pb{Co(CO)3(L)}4] and [Pb{Fe(CO)2(NO)(L)}4].
  作者：Paul Hackett、A.R. Manning

  DOI：10.1016/s0277-5387(00)81066-9

  日期：1982.1

  The sole and unexpected products from the reactions of a variety of lead (II) and lead (IV) compounds with [Co2(CO)6(L)2] complexes (L = tertiary arsine, phosphine, or phosphite) in refluxing benzene solution are the blue, air-stable percobaltoplumbanes [PbCo(CO)3(L)}4]. These have also been obtained from the reaction of Na[Co(CO)3(L)] (L  PBu3n) with lead (II) acetate which with Na[Fe(CO)2(NO)(L)]

  各种铅（II）和铅（IV）化合物与[Co 2（CO）6（L）2 ]配合物（L =叔a，膦或亚磷酸酯）在回流的苯中反应的唯一且出乎意料的产物解决方案是蓝色的，空气稳定的过钴钴铝[Pb Co（CO）3（L）} 4 ]。这些也是从Na [Co（CO）3（L）]（LPBu 3 n）与乙酸铅（II）的反应中获得的，乙酸铅与Na [Fe（CO）2（NO）（L）]形成等电子[Pb Fe（CO）2（NO）（L）} 4 ] [LP（OPh）3 ]。复合物中的IR光谱v（CO）和v（NO）区域与四面体PbCo 4或PbFe 4片段，关于钴或铁原子的三角双锥体配位以及线性PbCoAs，PbCoP或PbFeP系统一致。与[Pb Co（CO）4 } 4 ]不同，当溶解在供体中时，我们的络合物不会解离为[Co（CO）3（L）] -或[Fe（CO）2（NO）（L）] -离子。溶剂。
• A Conspicuous Deprotonation in Complexes of Diphenyllead(IV) with Ligands Containing Both Semicarbazone and Thiosemicarbazone Chains
  作者：José S. Casas、Estefanía Castro‐Vidal、María S. García‐Tasende、Agustín Sánchez、José Sordo、Ángeles Touceda、Ezequiel M. Vázquez‐López

  DOI：10.1002/ejic.201001030

  日期：2011.2

  previously unknown [PbC2N3OS] kernel. In the H2L2 and H2L3 complexes the coordination for the diphenyllead(IV) moiety is the same, with the ligand N,N,S,O-bound, but these complexes differ in the protonation status of the SC chain. In [PbPh2(OAc)(HL2)]·MeOH the chain is not deprotonated, and in [PbPh2(L3)(dmso)]·2dmso it is deprotonated. Conspicuously, in [PbPh2(H0.5L3)(MeOH)](OAc)0.5 the SC “arm” is formally

  在寻找新的有机铅 (IV) 离子螯合剂的过程中，2,6-二乙酰基吡啶依次与氨基脲和 4-甲基氨基硫脲缩合得到 H2L1。根据 X 射线研究，该分子分别与缩氨基脲 (SC) 和缩氨基硫脲 (TSC) 链在“开臂”和“闭臂”方向上几乎呈平面。2,3-丁二酮与氨基脲和4-甲基氨基硫脲或与4-苯基氨基脲和4-苯基氨基硫脲的类似缩合分别提供H2L2和H2L3。H2Lx 与二乙酸二苯铅 (IV) 在甲醇中反应得到复合物 [PbPh2(HL1)](OAc)0.75Cl0.25·2.375H2O、[PbPh2(OAc)(HL2)]·MeOH 和 [PbPh2(H0.5L3) )(MeOH)](OAc)0.5。当后者从 dmso 中重结晶时，分离出新的衍生物 [PbPh2(L3)(dmso)]·2dmso。H2L1 复合物的 X 射线研究表明，TSC 链去质子化而 SC 链未去质子化的配体通过 N3、N4、N5、O1
• Structural analysis of phenyl-germanium, -tin, and -lead dithiocarboxylates [(RCSS) MPh4−, M=Ge, Sn, Pb; x=1–3]: affinity between thiocarbonyl sulfur and Group 14 elements
  作者：Shinzi Kato、Kazuyasu Tani、Nobuyuki Kitaoka、Kohzaburoh Yamada、Hiroyuki Mifune

  DOI：10.1016/s0022-328x(00)00453-8

  日期：2000.10

  or skewed trapezoidal bipyramid, where the two dithiocarboxylate groups are bound to the Sn atom as an anisobidentate ligand, and the tin tris(dithiocarboxylate) (5c) exhibits a seven-coordinated pentagonal bipyramid. The distance between the thiocarbonyl sulfur and the Sn atom in 4-CH3C6H4CSSMPh3 (M=Ge, Sn, Pb) is shorter than those in the corresponding germanium and lead derivatives. Based on these

  合成了一系列RCSSGePh 3，（RCSS）2 GePh 2，（RCSS）3 SnPh和（RCSS）2 PbPh 2，并合成了一些对甲苯基衍生物[RCSSMPh 3（R = 4-CH 3 C 6 H 4，M = Ge：1d，Sn：3d，Pb：6d）和（4-CH 3 C 6 H 4 CSS）2 SnPh 2（4d）]和邻甲苯基衍生物[（2-CH 3 C 6 H通过X射线分析了4 CSS）3 SnPh：（5c）]。结果表明，硫代羰基硫与第14组中心元素金属之间的分子内非键相互作用。单二硫代羧酸盐（1d，3d和6d）在第14组中心元素周围显示出扭曲的四面体结构。二苯基锡双（二硫代羧酸盐）（4d）表现为扭曲的八面体或偏斜梯形双金字塔，其中两个二硫代羧酸盐基团作为异双峰配体键合到Sn原子上，而锡三（二硫代羧酸盐）（5c）具有七配位的五边形双锥体。4-CH 3 C 6 H 4 CSSMPh 3（M =
• Synthesis and Structural Studies of Organotin(IV) and Organolead(IV) Thiophene‐2‐thiocarboxylate
  作者：Suryabhan Singh、Subrato Bhattacharya、Heinrich Nöth

  DOI：10.1002/ejic.201000692

  日期：2010.12

  A few organotin(IV) ([R 2 SnCl 2 ], [R 3 SnCl]; R = Me, Ph, nPr, or nBu) and organolead(IV) ([Ph 2 PbCl 2 ], [Ph 3 PbCl]) compounds that contain the thiophene-2-thiocarboxylate ligand have been synthesized and characterized by 1 H, 13 C, 119 Sn NMR; FTIR; and UV/Vis spectroscopy. The molecular structures of some of the compounds were studied by single-crystal X-ray diffraction. Structures and electronic

  一些有机锡 (IV)（[R 2 SnCl 2 ]、[R 3 SnCl]；R = Me、Ph、nPr 或 nBu）和有机铅 (IV)（[Ph 2 PbCl 2 ]、[Ph 3 PbCl]）已合成含有噻吩-2-硫代羧酸酯配体的化合物，并通过 1 H、 13 C、 119 Sn NMR 表征；红外光谱；和紫外/可见光谱。通过单晶X射线衍射研究了一些化合物的分子结构。结构和电子跃迁已在 DFT 计算的基础上进行了解释。