1,2,3,4,5,6,7,8-Octahydro-9,10-anthraquinone | 23585-26-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,2,3,4,5,6,7,8-Octahydro-9,10-anthraquinone
• 英文别名: 1,2,3,4,5,6,7,8-octahydro-anthraquinone；1,2,3,4,5,6,7,8-Octahydro-anthrachinon；9.10-Dioxo-1.2.3.4.5.6.7.8.9.10-dekahydro-anthracen；1,2,3,4,5,6,7,8-octahydroanthraquinone；octahydro-anthraquinone；1,2,3,4,5,6,7,8-Octahydroanthracene-9,10-dione
• CAS: 23585-26-4
• 化学式: C₁₄H₁₆O₂
• 分子量: 216.28
• InChiKey: SPUJCXKFUOZIGI-UHFFFAOYSA-N

物化性质

• 熔点：
  184 °C
• 沸点：
  364.4±17.0 °C(Predicted)
• 密度：
  1.17±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2,3,4,5,6,7,8-Octahydro-9,10-anthraquinone 以85.4%的产率得到蒽醌
  参考文献：
  名称：

  Process for the preparation of anthraquinone

  摘要：

  一种过程，包括在反应介质中加入可溶的一种碱性化合物和一种自由基反应抑制剂，将1,4,4a,5,8,8a,9a,10a-八氢蒽醌与硝基苯反应，生成蒽醌。

  公开号：

  US04152340A1
• 作为产物：
  描述：

  蒽醌 在 乙醇 、 镍 作用下， 生成 1,2,3,4,5,6,7,8-Octahydro-9,10-anthraquinone
  参考文献：
  名称：

  Prevalence of Undernutrition and Vitamin A Deficiency in the Dogon Region, Mali

  摘要：

  Objectives: A representative sample of 1510 preschool children living in the Bandiagra circle (Mopti Region, Mali) was examined between March and April 1997 to determine the level of vitamin A deficiency.Methods: Using a randomized two level cluster sampling, 20 clusters of 75 children aged six months to six years were selected for evaluating xerophthalmia (XN night blindness and/or X1B Bitot spot). Concurrently stature and weight were determined. A semiquantitative seven-day dietary questionnaire was applied to the mothers of 484 infants to assess consumption of vitamin A rich foodstuffs. The prevalence of biochemical deficiency was attested using the Modified Relative Dose Response test (MRDR) on a sub-sample of 192.Results: Of the studied children, 4.3% (95% Confidence interval [Cl]: 3.2-5.3) reported night blindness and 2% (95% Cl: 1.3-2.7) bad Bitot spots. Prevalence of xerophthalmia attested by at least one of these signs was 5.4% (95% Cl: 4.2-6.5). The prevalence reached 10.5% at three years of age. The MRDR test proved abnormal in 77.1% of the subjects (95% Cl: 70.3-82.7). Serum retinol was lower than 0.35 mumol/L, in 43.8% (95.6% Cl: 36.9-51.3) and less than 0.70 mumol/L in 92.7% of the children (95% Cl: 87.8-95.8). Weekly consumption of vitamin A rich food was rare: 75.8% had not eaten any animal vitamin A rich food, and 22.1% had consumed less than seven times a vitamin A rich food of either vegetable or animal origin.Conclusions: These data define vitamin A deficiency as a severe public health problem in the Bandiagara area of Mali.

  DOI：

  10.1080/07315724.2002.10719239

文献信息

• Convenient preparation of quinones via the catalytic autoxidation of hydroquinones with nitrogen oxides
  作者：Rajendra Rathore、Eric Bosch、Jay K. Kochi

  DOI：10.1016/s0040-4039(00)76211-3

  日期：1994.2

  An efficient, inexpensive, catalytic method for the autoxidation of hydroquinones utilizes the gaseous (NOx) catalyst which allows a simple workup procedure for quinone isolation merely by solvent removal.

  一种有效，廉价的对苯二酚自动氧化的催化方法利用了气态（NO x）催化剂，该方法允许简单的后处理步骤，仅通过去除溶剂即可分离出醌。
• Verfahren zur Herstellung von Anthron
  申请人：BAYER AG

  公开号：EP0007041A1

  公开（公告）日：1980-01-23

  Verfahren zur Herstellung von Anthron durch katalytische Hydrierung von Anthrachinon in einem inerten organischen Lösungsmittel in Gegenwart eines Katalysators, dadurch gekennzeichnet, daß man gegebenfalls auf Trägermaterialien aufgebrachte Katalysatoren verwendet, die wenigstens zwei Metalle mit den Atomnummern 23 bis 29, wovon wenigstens 1 Metall Ni oder Cu ist, in reduzierter oder oxidischer Form enthalten, mit Wasserstoff hydriert.

  一种在催化剂存在下，在惰性有机溶剂中通过催化氢化蒽醌制备蒽酮的工艺，其特征在于催化剂可选择性地应用于载体材料，并含有至少两种原子序数为23至29的金属，其中至少一种金属为镍或铜，以还原或氧化形式与氢氢化。
• Process for the delignification of lignocellulosic material and products thereof
  申请人：C.I.L. Inc.

  公开号：EP0010451A1

  公开（公告）日：1980-04-30

  There is disclosed a process for the delignification of lignocellulosic material by treatment with an alkaline liquor in the presence of a cyclic keto compound such as anthraquinone. The lignocellulosic material in subdivided form is first impregnated with the alkaline liquor containing a suitable amount of the cyclic keto compound whereafter any excess liquor is drained. The impregnated material is then cooked by heating. The delignified products are suitable for the manufacture of paper.

  本发明公开了一种木质纤维素材料的脱木素工艺，即在蒽醌等环酮化合物存在的情况下，用碱性液处理木质纤维素材料。首先用含有适量环酮化合物的碱性液体浸渍细分的木质纤维素材料，然后排出多余的液体。然后将浸渍过的材料加热蒸煮。脱木素产品适用于造纸。
• Verfahren zur Herstellung von 1.2.3.4.5.6.7.8-Octahydro-anthrahydrochinonen
  申请人：BAYER AG

  公开号：EP0153640A2

  公开（公告）日：1985-09-04

  Neues Verfahren zur Herstellung von 1.2.3.4.5.6.7.8-Octahydro-anthrahydrochinonen durch katalytische Hydrierung von Antrachinonen in Ethern.

  通过醚中蒽醌的催化加氢制备 1.2.3.4.5.6.7.8-八氢蒽醌的新工艺。
• Rathore, Rajendra; Bosch, Eric; Kochi, Jay K., Journal of the Chemical Society. Perkin transactions II, 1994, # 6, p. 1157 - 1166
  作者：Rathore, Rajendra、Bosch, Eric、Kochi, Jay K.

  DOI：——

  日期：——