ethyl 3-(2,2,2-trichloroethoxycarbonylamino)benzoate | 847622-58-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethyl 3-(2,2,2-trichloroethoxycarbonylamino)benzoate
• CAS: 847622-58-6
• 化学式: C₁₂H₁₂Cl₃NO₄
• 分子量: 340.591
• InChiKey: BEPWLLGNVZFPIA-UHFFFAOYSA-N

物化性质

• 沸点：
  372.9±42.0 °C(Predicted)
• 密度：
  1.455±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ethyl 3-(2,2,2-trichloroethoxycarbonylamino)benzoate 、 硫酸二甲酯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以79%的产率得到ethyl 3-[N-methyl-N-(2,2,2-trichloroethoxycarbonyl)amino]benzoate
  参考文献：
  名称：

  INSECTICIDE FOR AGRICULTURAL OR HORTICULTURAL USE AND METHOD OF USE THEREOF

  摘要：

  公开号：

  EP1661886B1
• 作为产物：
  描述：

  3-氨基苯甲酸乙酯 、 氯甲酸-2,2,2-三氯乙酯 在 吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以91%的产率得到ethyl 3-(2,2,2-trichloroethoxycarbonylamino)benzoate
  参考文献：
  名称：

  INSECTICIDE FOR AGRICULTURAL OR HORTICULTURAL USE AND METHOD OF USE THEREOF

  摘要：

  公开号：

  EP1661886B1

文献信息

• Insecticide for agricultural or horticultural use and method of use thereof
  申请人：Yoshida Kei

  公开号：US20070027154A1

  公开（公告）日：2007-02-01

  An object of the present invention is to provide insecticides having high effectiveness. The present invention provides compounds represented by formula (1): wherein A 1 , A 2 , A 3 , and A 4 independently represent a carbon atom, a nitrogen atom, or an oxidized nitrogen atom; R 1 represents a C1-C6 alkyl group which may be substituted, a phenyl group which may be substituted, or a heterocyclic group which may be substituted; R 2 and R 3 independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, or a C1-C4 alkylcarbonyl group which may be substituted; G 1 , G 2 , and G 3 independently represent an oxygen atom or a sulfur atom; Xs may be the same or different and each represent a hydrogen atom, a halogen atom, a C1-C4 alkyl group which may be substituted, or an amino group which may be substituted; n represents an integer of 0 to 4; Q represents a phenyl group which may be substituted, a naphthyl group which may be substituted, a tetrahydronaphthyl group which may be substituted, or a heterocyclic group which may be substituted, insecticides containing the compounds as active ingredients, and a method for producing the compounds. The compounds represented by formula (1) exhibit an excellent preventive effect as insecticides and also exhibit an excellent preventive effect when being combined with another insecticide, an acaricide, a nematocide, a fungicide, a herbicide, a plant growth regulator, or a biological pesticide.

  本发明的目的是提供具有高效性的杀虫剂。本发明提供了由公式（1）表示的化合物：其中，A1、A2、A3和A4独立地表示碳原子、氮原子或氧化氮原子；R1表示可以被取代的C1-C6烷基、可以被取代的苯基或可以被取代的杂环基；R2和R3独立地表示氢原子、可以被取代的C1-C4烷基或可以被取代的C1-C4烷基羰基；G1、G2和G3独立地表示氧原子或硫原子；X可以相同也可以不同，每个X表示氢原子、卤素原子、可以被取代的C1-C4烷基或可以被取代的氨基；n表示0到4的整数；Q表示可以被取代的苯基、可以被取代的萘基、可以被取代的四氢萘基或可以被取代的杂环基，以及以该化合物为活性成分的杀虫剂和制备该化合物的方法。公式（1）所表示的化合物在作为杀虫剂时表现出优异的预防效果，并且在与其他杀虫剂、杀螨剂、杀线虫剂、杀菌剂、除草剂、植物生长调节剂或生物农药组合时也表现出优异的预防效果。
• AGRICULTURAL/HORTICULTURAL INSECTICIDE AND METHOD FOR USING THE SAME
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20140303377A1

  公开（公告）日：2014-10-09

  An object of the present invention is to provide insecticides having high effectiveness. The present invention provides compounds represented by formula (1): wherein A 1 , A 2 , A 3 , and A 4 independently represent a carbon atom, a nitrogen atom, or an oxidized nitrogen atom; R 1 represents a C1-C6 alkyl group which may be substituted, a phenyl group which may be substituted, or a heterocyclic group which may be substituted; R 2 and R 3 independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, or a C1-C4 alkylcarbonyl group which may be substituted; G 1 , G 2 , and G 3 independently represent an oxygen atom or a sulfur atom; Xs may be the same or different and each represent a hydrogen atom, a halogen atom, a C1-C4 alkyl group which may be substituted, or an amino group which may be substituted; n represents an integer of 0 to 4; Q represents a phenyl group which may be substituted, a naphthyl group which may be substituted, a tetrahydronaphthyl group which may be substituted, or a heterocyclic group which may be substituted, insecticides containing the compounds as active ingredients, and a method for producing the compounds. The compounds represented by formula (1) exhibit an excellent preventive effect as insecticides and also exhibit an excellent preventive effect when being combined with another insecticide, an acaricide, a nematocide, a fungicide, a herbicide, a plant growth regulator, or a biological pesticide.

  本发明的目的是提供高效的杀虫剂。本发明提供了由式（1）表示的化合物：其中A1，A2，A3和A4分别独立表示碳原子，氮原子或氧化氮原子；R1表示可以被取代的C1-C6烷基，可以被取代的苯基或可以被取代的杂环基；R2和R3独立表示氢原子，可以被取代的C1-C4烷基或可以被取代的C1-C4烷基羰基；G1，G2和G3独立表示氧原子或硫原子；X可以相同或不同，每个表示氢原子，卤素原子，可以被取代的C1-C4烷基或可以被取代的氨基；n表示0到4的整数；Q表示可以被取代的苯基，可以被取代的萘基，可以被取代的四氢萘基或可以被取代的杂环基，以及含有该化合物作为活性成分的杀虫剂和制备该化合物的方法。式（1）所表示的化合物具有优异的杀虫预防效果，并且在与另一种杀虫剂，螨虫剂，线虫剂，杀菌剂，除草剂，植物生长调节剂或生物农药组合时也具有优异的预防效果。
• Agricultural/horticultural insecticide and method for using the same
  申请人：MITSUI CHEMICALS, INC.

  公开号：US09101135B2

  公开（公告）日：2015-08-11

  An object of the present invention is to provide insecticides having high effectiveness. The present invention provides compounds represented by formula (1): wherein A1, A2, A3, and A4 independently represent a carbon atom, a nitrogen atom, or an oxidized nitrogen atom; R1 represents a C1-C6 alkyl group which may be substituted, a phenyl group which may be substituted, or a heterocyclic group which may be substituted; R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, or a C1-C4 alkylcarbonyl group which may be substituted; G1, G2, and G3 independently represent an oxygen atom or a sulfur atom; Xs may be the same or different and each represent a hydrogen atom, a halogen atom, a C1-C4 alkyl group which may be substituted, or an amino group which may be substituted; n represents an integer of 0 to 4; Q represents a phenyl group which may be substituted, a naphthyl group which may be substituted, a tetrahydronaphthyl group which may be substituted, or a heterocyclic group which may be substituted, insecticides containing the compounds as active ingredients, and a method for producing the compounds. The compounds represented by formula (1) exhibit an excellent preventive effect as insecticides and also exhibit an excellent preventive effect when being combined with another insecticide, an acaricide, a nematocide, a fungicide, a herbicide, a plant growth regulator, or a biological pesticide.

  本发明的目的是提供高效的杀虫剂。本发明提供了由公式（1）表示的化合物：其中A1、A2、A3和A4分别独立表示碳原子、氮原子或氧化氮原子；R1表示可以被取代的C1-C6烷基、可以被取代的苯基或可以被取代的杂环基；R2和R3分别表示氢原子、可以被取代的C1-C4烷基或可以被取代的C1-C4烷基酰基；G1、G2和G3分别表示氧原子或硫原子；Xs可以相同也可以不同，每个表示氢原子、卤素原子、可以被取代的C1-C4烷基或可以被取代的氨基；n表示0到4的整数；Q表示可以被取代的苯基、可以被取代的萘基、可以被取代的四氢萘基或可以被取代的杂环基，杀虫剂含有化合物作为活性成分，以及制备化合物的方法。由公式（1）表示的化合物表现出出色的杀虫预防效果，并且与另一种杀虫剂、杀螨剂、杀线虫剂、杀菌剂、除草剂、植物生长调节剂或生物农药结合时也表现出出色的预防效果。
• Agricultural/Horticultural Insecticide and Method for Using the Same
  申请人：MITSUI CHEMICALS AGRO, INC.

  公开号：EP2423188A1

  公开（公告）日：2012-02-29

  An aniline derivative of formula: useful in synthesis of insecticides.

  式中的苯胺衍生物： 用于合成杀虫剂。
• Intermediates in the preparation of agricultural/horticultural insecticides and method for using the same
  申请人：Mitsui Chemicals Agro, Inc.

  公开号：EP2423188B1

  公开（公告）日：2021-03-10