2-联苯基碘化镁 | 23533-35-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-联苯基碘化镁
• 英文名称: 2-biphenylylmagnesium iodide
• 英文别名: biphenyl-2-ylmagnesium iodide；2-Biphenylylmagnesiumiodid；Biphenylyl-(2)-magnesiumjodid；Biphenyl-2-ylmagnesiumjodid
• CAS: 23533-35-9
• 化学式: C₁₂H₉IMg
• 分子量: 304.413
• InChiKey: FNIKBCFXZYFIGZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.03
• 重原子数：
  14.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  2-联苯基碘化镁 在 potassium dichromate 、 乙醚 、 硫酸 、 溶剂黄146 作用下， 生成 1-(2-联苯基)乙酮
  参考文献：
  名称：

  Vinyl Aromatic Compounds. II. o-, m- and p-Vinylbiphenyls

  摘要：

  DOI：

  10.1021/ja01210a060
• 作为产物：
  描述：

  2-碘联苯 生成 2-联苯基碘化镁
  参考文献：
  名称：

  STILLINGS M. R.; WELBOURN A. P.; WALTER D. S., J. MED. CHEM., 29,(1986) N 11, 2280-2284

  摘要：

  DOI：
• 作为试剂：
  描述：

  占吨酮 在 2-联苯基碘化镁 作用下， 生成 9-biphenyl-2-yl-xanthen-9-ol; compound with xanthen-9-one
  参考文献：
  名称：

  SPIRANS WITH FOUR AROMATIC RADICALS ON THE SPIRO CARBON ATOM¹

  摘要：

  DOI：

  10.1021/ja01370a048

文献信息

• Substituted 1,3,4-thiadiazoles with anticonvulsant activity. 2. Aminoalkyl derivatives
  作者：Michael R. Stillings、Anthony P. Welbourn、Donald S. Walter

  DOI：10.1021/jm00161a025

  日期：1986.11

  This paper describes the synthesis and pharmacological evaluation of a number evaluation of a number of substituted 1,3,4-thiadiazoles. The first member of the series, 2-(aminomethyl)-5-(2-biphenylyl)-1,3,4-thiadiazole (7) was found to possess potent anticonvulsant properties in rats and mice and compared favorably with the standard anticonvulsant drugs phenytoin, phenobarbital, and carbamazepine in

  本文描述了许多取代的1,3,4-噻二唑的合成和药理学评估。该系列的第一个成员2-（氨基甲基）-5-（2-联苯甲酰基）-1,3,4-噻二唑（7）在大鼠和小鼠中具有强大的抗惊厥特性，与标准抗惊厥药物相比具有优势苯妥英钠，苯巴比妥和卡马西平在许多试验情况下均如此。当侧链氮原子烷基化时，化合物7的效力得以维持。然而，芳基取代或链延长导致效能下降。用苯基或苄基取代2-联苯基会导致惰性化合物。
• Dipyridine-based compound and the use thereof
  申请人：Luminescence Technology Corp.

  公开号：US07282586B1

  公开（公告）日：2007-10-16

  The present invention discloses a dipyridine-based compound which can be used as electron-transporting and/or hole blocking material or phosphorous host in organic electroluminescence devices is disclosed. The mentioned dipyridine-based compound is represented by the following formula: wherein R1 and R2 are identical or different, and R1 and R2 are independently selected from the group consisting of: hydrogen atom, aryl moiety, hetero cycle, multiple fused ring, multiple fused ring with hetero atom(s); A is selected from the following group: wherein R3 and R4 are identical or different, R5 and R6 are identical or different, R7 and R8 are identical or different, R3, R4, R7, R8 are independently selected from the group consisting of: alkyl moiety and aryl moiety, and R5, R6 are independently selected from the group consisting of: alkyl moiety, aryl moiety and arylamine moiety.

  本发明公开了一种以二吡啶为基础的化合物，可用作有机电致发光器件中的电子传输和/或阻挡孔的材料或磷宿主。所述的二吡啶基化合物由以下公式表示：其中R1和R2相同或不同，R1和R2独立地选自以下组：氢原子，芳基，杂环，多重融合环，带有杂原子的多重融合环；A选自以下组：其中R3和R4相同或不同，R5和R6相同或不同，R7和R8相同或不同，R3、R4、R7、R8独立地选自以下组：烷基基团和芳基基团，R5、R6独立地选自以下组：烷基基团，芳基基团和芳胺基团。
• Organoboron compounds. Part VI. Photochemical reactions of aryl and alkyl halides with boron halides
  作者：R. A. Bowie、O. C. Musgrave

  DOI：10.1039/j39660000566

  日期：——

  The photolysis of aryl iodides in the presence of boron halides results in the formation of arylboron dihalides and diarylboron halides by free-radical substitution reactions. Hydrolysis of the products gives the corresponding boronic and borinic acids. Alkyl iodides and di-iodo-compounds behave in a similar manner. The photolysis and subsequent hydrolysis of mixtures of bromo- or chloro-benzene with

  在卤化硼存在下光解芳基碘化物会通过自由基取代反应形成芳基硼二卤化物和二芳基硼卤化物。产物的水解得到相应的硼酸和硼酸。烷基碘化物和二碘化合物的行为相似。溴苯或氯苯与三溴化硼的混合物进行光解和随后的水解也可得到硼酸。副产物表明二溴硼基（Br 2 B·）自由基参与了这些反应。
• Structurally robust phosphorescent [Pt(O^N^C^N)] emitters for high performance organic light-emitting devices with power efficiency up to 126 lm W⁻¹ and external quantum efficiency over 20%
  作者：Gang Cheng、Steven C. F. Kui、Wai-Hung Ang、Man-Ying Ko、Pui-Keong Chow、Chun-Lam Kwong、Chi-Chung Kwok、Chensheng Ma、Xiangguo Guan、Kam-Hung Low、Shi-Jian Su、Chi-Ming Che

  DOI：10.1039/c4sc01105h

  日期：——

  A series of robust, bulky and strongly emissive platinum(II) complexes supported by tetradentate O^N^C^N ligands with tert-butyl groups (1–4), a bridging tertiary amine (5) or a biphenyl group with a spiro linkage (6) at the periphery of the [O^N^C^N] ligand scaffold have been prepared. Their photophysical properties were examined by absorption and emission spectroscopy, density functional theory calculations

  由具有叔丁基（1-4），桥联叔胺（5）或带有螺环的联苯基的四齿O ^ N ^ C ^ N配体支持的一系列坚固，庞大且强发射的铂（II）配合物已经制备了在[O ^ N ^ C ^ N]配体支架的外围的连接键（6）。通过吸收和发射光谱，密度泛函理论计算和超快时间分辨发射测量，检查了它们的光物理性质。这些复合物显示高达95％的发射量子产率，具有发射最大值λ最大为522至570纳米的范围内，并且具有向上的良好的热稳定性，以Ť d> 423°C。值得注意的是，ķ q的值4-6是在8.5×10的范围内6〜2.0×10 7摩尔-1分米3个小号-1，比（〜10小8至10 9摩尔-1分米3个小号-其他已报告的Pt（II）的1））复合体。[O 2 N 2 C 2 N]配体外围的庞大基团不利于分子间相互作用，因此在溶液中形成准分子。这些络合物是用于OLED的良好发光材料（掺杂剂），因为即使在高掺杂剂浓度下，三重
• 4,5-Diazafluorene-Incorporated Ter(9,9-diarylfluorene): A Novel Molecular Doping Strategy for Improving the Electron Injection Property of a Highly Efficient OLED Blue Emitter
  作者：Ken-Tsung Wong、Ruei-Tang Chen、Fu-Chuan Fang、Chung-chih Wu、Yu-Ting Lin

  DOI：10.1021/ol050547o

  日期：2005.5.1

  A more efficient OLED device with blue emission characteristic of terfluorene has been achieved by using a novel molecular doping strategy, in which 4,5-diazafluorene was incorporated as the substitution group of terfluorene to facilitate electron injection from the metal cathode yet without altering emission characteristics.

  通过使用一种新型的分子掺杂策略，已经获得了一种具有三氟芴蓝色发射特性的更有效的OLED器件，其中将4,5-二氮杂芴作为三氟芴的取代基团加入，以促进电子从金属阴极注入而又不改变发射特性。