5-[4-(2,5-dimethylphenyl)phenyl]tetrazole | 955935-12-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-[4-(2,5-dimethylphenyl)phenyl]tetrazole
• 英文别名: 5-[4-(2,5-dimethylphenyl)phenyl]-2H-tetrazole
• CAS: 955935-12-3
• 化学式: C₁₅H₁₄N₄
• 分子量: 250.303
• InChiKey: LVGGWMBGVBIFGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  54.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-[4-(2,5-dimethylphenyl)phenyl]tetrazole 在 吡啶 、 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 苯 为溶剂， 生成 2-{4-[2,5-bis(bromomethyl)phenyl]phenyl}-5-[3-(3,7-dimethyloctyloxy)phenyl]-1,3,4-oxadiazole
  参考文献：
  名称：

  Synthesis and Characterization of a Light-Emitting Poly(p-phenylenevinylene)-Based Copolymer Containing 1,3,4-Oxadiazole Functionality

  摘要：

  A new class of high brightness and luminance efficiency of poly[2-{4-[5-(3-(3, 7-dimethyloctyloxy)phenyl)-1,3,4-oxadiazole-2-yl]phenyl}-1,4-phenylenevinylene] (C(10)PhOxa-PPV) was synthesized by Gilch polymerization. The weight average molecular weight (Mw) and the polydispersity of C(10)PhOxa-PPV were found to be 2.7 x 10(4) and 2.6, respectively. Double-layer light-emitting device with an ITO/ PEDOT/C(10)PhOxa-PPV/Al was fabricated and characterized. The maximum brightness, and luminance efficiency of C(10)PhOxa-PPV showed values of up to 8.3 cd/A and 4,426 cd/m(2), respectively.

  DOI：

  10.1080/15421400601010813
• 作为产物：
  描述：

  2.5-二甲基苯硼酸频呢醇酯 在 四(三苯基膦)钯 、 sodium azide 、 碳酸氢钠 、 氯化铵 作用下， 以 乙二醇二甲醚 、 N,N-二甲基甲酰胺 为溶剂， 生成 5-[4-(2,5-dimethylphenyl)phenyl]tetrazole
  参考文献：
  名称：

  Synthesis and Characterization of a Light-Emitting Poly(p-phenylenevinylene)-Based Copolymer Containing 1,3,4-Oxadiazole Functionality

  摘要：

  A new class of high brightness and luminance efficiency of poly[2-{4-[5-(3-(3, 7-dimethyloctyloxy)phenyl)-1,3,4-oxadiazole-2-yl]phenyl}-1,4-phenylenevinylene] (C(10)PhOxa-PPV) was synthesized by Gilch polymerization. The weight average molecular weight (Mw) and the polydispersity of C(10)PhOxa-PPV were found to be 2.7 x 10(4) and 2.6, respectively. Double-layer light-emitting device with an ITO/ PEDOT/C(10)PhOxa-PPV/Al was fabricated and characterized. The maximum brightness, and luminance efficiency of C(10)PhOxa-PPV showed values of up to 8.3 cd/A and 4,426 cd/m(2), respectively.

  DOI：

  10.1080/15421400601010813

文献信息

• Synthesis and Characterization of a Light-Emitting Poly(<i>p</i>-phenylenevinylene)-Based Copolymer Containing 1,3,4-Oxadiazole Functionality
  作者：Sung-Ho Jin、Sung-Chul Kim、Jong-Min Shim、Sung-Min Park、Eun-Jae Lee、Won Suk Shin、Jae-Wook Lee、Yeong-Soon Gal

  DOI：10.1080/15421400601010813

  日期：2006.12.25

  A new class of high brightness and luminance efficiency of poly[2-4-[5-(3-(3, 7-dimethyloctyloxy)phenyl)-1,3,4-oxadiazole-2-yl]phenyl}-1,4-phenylenevinylene] (C(10)PhOxa-PPV) was synthesized by Gilch polymerization. The weight average molecular weight (Mw) and the polydispersity of C(10)PhOxa-PPV were found to be 2.7 x 10(4) and 2.6, respectively. Double-layer light-emitting device with an ITO/ PEDOT/C(10)PhOxa-PPV/Al was fabricated and characterized. The maximum brightness, and luminance efficiency of C(10)PhOxa-PPV showed values of up to 8.3 cd/A and 4,426 cd/m(2), respectively.