2-[4-(5-phenyl-1,3,4-thiadiazole-2-yl)-phenoxy]ethyl methacrylate | 1214913-32-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-[4-(5-phenyl-1,3,4-thiadiazole-2-yl)-phenoxy]ethyl methacrylate
• 英文别名: 2-[4-(5-Phenyl-1,3,4-thiadiazol-2-yl)phenoxy]ethyl 2-methylprop-2-enoate；2-[4-(5-phenyl-1,3,4-thiadiazol-2-yl)phenoxy]ethyl 2-methylprop-2-enoate
• CAS: 1214913-32-2
• 化学式: C₂₀H₁₈N₂O₃S
• 分子量: 366.441
• InChiKey: NRNCXMOMCJOLMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  89.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-[4-(5-phenyl-1,3,4-thiadiazole-2-yl)-phenoxy] ethanol 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以91%的产率得到2-[4-(5-phenyl-1,3,4-thiadiazole-2-yl)-phenoxy]ethyl methacrylate
  参考文献：
  名称：

  The synthesis, electrochemical and fluorescent properties of monomers and polymers containing 2,5-diphenyl-1,3,4-thiadiazole

  摘要：

  Three, 2,5-diphenyl-1,3,4-thiadiazole-containing vinyl monomers and their polymers were synthesized and the HOMO and LUMO energies of the compounds, as estimated from cyclic voltammetry data, were -6.35 to -6.14 eV and -3.02 to -2.84 eV, respectively. The optical band gaps (E-g) were similar to those determined from cyclic voltammograms. The fluorescent emission spectra of all monomers and polymers displayed either blue or green light emission. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2009.07.007

文献信息

• The synthesis, electrochemical and fluorescent properties of monomers and polymers containing 2,5-diphenyl-1,3,4-thiadiazole
  作者：Yongxin Tao、Qingfeng Xu、Jianmei Lu、Xuebo Yang

  DOI：10.1016/j.dyepig.2009.07.007

  日期：2010.2

  Three, 2,5-diphenyl-1,3,4-thiadiazole-containing vinyl monomers and their polymers were synthesized and the HOMO and LUMO energies of the compounds, as estimated from cyclic voltammetry data, were -6.35 to -6.14 eV and -3.02 to -2.84 eV, respectively. The optical band gaps (E-g) were similar to those determined from cyclic voltammograms. The fluorescent emission spectra of all monomers and polymers displayed either blue or green light emission. (C) 2009 Elsevier Ltd. All rights reserved.