2-Methyl-1-(oxazetidin-2-yl)prop-2-en-1-one

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Methyl-1-(oxazetidin-2-yl)prop-2-en-1-one
• 英文别名: 2-methyl-1-(oxazetidin-2-yl)prop-2-en-1-one
• 化学式: C₆H₉NO₂
• 分子量: 127.14
• InChiKey: VPRBGRISVBHQRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• POLYOXYALKYLENE-MODIFIED VINYL ALCOHOL POLYMER AND USE THEREOF
  申请人：Kuraray Co., Ltd.

  公开号：EP2735577A1

  公开（公告）日：2014-05-28

  Provided is a polyoxyalkylene modified vinyl alcohol-based polymer comprising a polyoxyalkylene group in a side chain, wherein the polymer has a viscosity average degree of polymerization of not less than 150 and not more than 5000, a degree of saponification of not less than 40 mol% and not more than 99. 99 mol%, and a polyoxyalkylene group modification rate of not less than 0.05 mol% and not more than 10 mol%; and the polyoxyalkylene group is composed of a polyoxypropylene block and a (poly) oxyethylene block and is represented by the following general formula (I). Such polymer is excellent in temperature-sensitive thickening properties. (in the general formula (I), R1 denotes a hydrogen atom or an alkyl group having a carbon number of from 1 to 8; either one of R2 and R3 is a methyl group and the other is a hydrogen atom; and 10 ≤ m ≤ 40 and 1 ≤ n ≤ 50).

  本发明提供了一种聚氧亚烷基改性的乙烯醇基聚合物，其侧链中包含聚氧亚烷基，其中聚合物的粘度平均聚合度不小于 150 且不大于 5000，皂化度不小于 40 mol% 且不大于 99.99摩尔％，聚氧亚烷基改性率不小于0.05摩尔％，不大于10摩尔％；聚氧亚烷基由聚氧丙烯嵌段和(聚)氧乙烯嵌段组成，并由以下通式(I)表示。这种聚合物具有优异的温敏增稠性能。 (在通式(I)中，R1 表示氢原子或碳原子数为 1 至 8 的烷基；R2 和 R3 中的一个为甲基，另一个为氢原子；10≤m≤40，1≤n≤50)。