1-Phenyl-3-oxa-1,5-pentanediol | 16775-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Phenyl-3-oxa-1,5-pentanediol
• 英文别名: 2-Phenyl-2-hydroxyethyl-(2-hydroxyethyl)ether；3-Oxa-1-phenyl-pentandiol-(1.5)；1-Phenyl-3-oxapentan-1,5-diol；2-(2-Hydroxyethoxy)-1-phenylethanol
• CAS: 16775-57-8
• 化学式: C₁₀H₁₄O₃
• 分子量: 182.219
• InChiKey: XBYQTDHLXJVHRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-Oxa-5-oxo-5-phenyl-pentansaeure, Phenylacyloxyessigsaeure 在 lithium aluminium tetrahydride 作用下， 以 乙二醇二甲醚 为溶剂， 生成 1-Phenyl-3-oxa-1,5-pentanediol
  参考文献：
  名称：

  Soulier,R.; Soulier,J., Bulletin de la Societe Chimique de France, 1969, p. 2048 - 2054

  摘要：

  DOI：

文献信息

• An adhesive composition
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0241027A2

  公开（公告）日：1987-10-14

  A method of profile lapping adhesion which comprises: coating on a film or sheet, or a substrate, or both of these an adhesive composition which comprises: (a) an epoxy resin or an isocyanate compound, (b) a curing agent for the epoxy resin or the isocyanate compound, and (c) a photopolymerizable vinyl compound; irradiating the adhesive composition; laminating the sheet or film to the substrate while the sheet or film is wrapped around the substrate; and curing the adhesive composition. An adhesive composition especially suitable for use in the profile lapping adhesion is provided, which comprises: (a) a photopolymerizable compound which has a number average molecular weight of not less than about 3000 and at least one photopolymerizable double linkage in the molecule; (b) a photopolymerizable monomer which has a molecular weight of about 200-800; and (c) an isocyanate compound. The photopolymerizable compound may be in part or in total displaced by a non-photopolymerizable compound which has a number average molecular weight of not less than about 5000. The adhesive composition develops a large primary adhe­sive strength by being irradiated, and further the adhesive develops a strong adhesion by chemical cure of the isocyanate compound.

  一种轮廓碾压粘合方法，包括 在薄膜或薄片或基材或两者上涂覆粘合剂组合物，该组合物包括 (a) 环氧树脂或异氰酸酯化合物、 (b) 环氧树脂或异氰酸酯化合物的固化剂，以及 (c) 可光聚合的乙烯基化合物； 照射粘合剂组合物； 在片材或薄膜包裹基材时，将片材或薄膜层压到基材上；以及 固化粘合剂组合物。 本发明提供了一种特别适用于型材碾压粘合的粘合剂组合物，它包括 (a) 可光聚合的化合物，其平均分子量不小于约 3000，分子中至少有一个可光聚合的双链； (b) 可光聚合单体，其分子量约为 200-800；及 (c) 异氰酸酯化合物。 可光聚合化合物可部分或全部被平均分子量不小于约 5000 的不可光聚合化合物取代。 通过辐照，粘合剂组合物产生较大的初粘强度，通过异氰酸酯化合物的化学固化，粘合剂进一步产生较强的粘合力。
• Production of laminated film
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0383015A2

  公开（公告）日：1990-08-22

  A process of producing laminated films which have stable and strong adhesive strength and heat resistance immediately after the lamination has been carried out, which comprises: coating a photocurable adhesive on a first synthetic resin film or a metal foil, the adhesive comprising a polyurethane poly(meth)acrylate and a coupling agent selected from the group consisting of silane coupling agents, titanate coupling agents and aluminum coupling agents; laminating the first synthetic resin film or metal foil to a second synthetic resin film or metal foil; and applying ultraviolet ray or radiant ray to the resultant laminated film.

  一种生产层压薄膜的工艺，这种薄膜在层压后立即具有稳定而强大的粘合强度和耐热性，该工艺包括 在第一层合成树脂薄膜或金属箔上涂一层光固化粘合剂，粘合剂包括聚氨酯聚（甲基）丙烯酸酯和一种偶联剂，偶联剂选自硅烷偶联剂、钛酸酯偶联剂和铝偶联剂组成的组； 将第一层合成树脂薄膜或金属箔层压到第二层合成树脂薄膜或金属箔上；以及 将紫外线或辐射线照射到由此产生的层压薄膜上。
• Photocurable adhesive and production of laminated articles using the same
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0423713A2

  公开（公告）日：1991-04-24

  A photocurable adhesive which comprises: (a) a polyurethene poly(meth)acrylate having a polyurethane structure which contains α, α, α′, α′-­tetramethylxylylenediisocyanate as a main polyisocyanate component; and (b) an adhesive coupling agent in an amount of 0.05-­10 parts by weight in relation to 100 parts by weight of the polyurethene poly(meth)acrylate. A process of producing a laminated film is also disclosed which comprises: coating the photocurable adhesive on a first substrate; laminating the first substrate to a second substrate; and applying ultraviolet ray or radiant ray to the resultant laminated film.

  一种光固化粘合剂，包括 (a) 具有聚氨酯结构的聚氨酯聚(甲基)丙烯酸酯，其主要多异氰酸酯成分为 α，α，α′，α′-四甲基二异氰酸酯；以及 (b) 相对于 100 份聚氨酯聚(甲基)丙烯酸酯而言，粘合偶联剂的用量为 0.05-10 份(重量)。 还公开了一种生产层压薄膜的工艺，其中包括：在第一基材上涂布光固化粘合剂；将第一基材层压到第二基材上；以及对由此产生的层压薄膜施加紫外线或辐射光线。
• Water soluble photocurable polyurethane poly(meth-)acrylate, adhesives containing the same, and production of laminated articles
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0443537A2

  公开（公告）日：1991-08-28

  There is disclosed a water soluble photocurable polyurethene poly(meth)acrylate which contains in the molecule (meth)acryloyl groups and water soluble groups composed of carboxyls of a salt structure with ammoniums or amino nitrogens. There is further disclosed an aqueous photocurable adhesive which comprises: (a) the water soluble photocurable polyurethene poly(meth)acrylate; (b) an adhesive coupling agent; and (c) water as a solvent. The adhesive is suitable for use in the production of laminated articles.

  本发明公开了一种水溶性光固化聚氨酯聚(甲基)丙烯酸酯，其分子中含有 (甲基)丙烯酰基和由盐结构的羧基与铵或氨基硝基组成的水溶性基团。 还公开了一种水性光固化粘合剂，它包括：(a) 水溶性光固化聚氨酯聚（甲基）丙烯酸酯；(b) 粘合剂偶联剂；(c) 作为溶剂的水。该粘合剂适用于生产层压制品。
• METHACRYLIC ACID ESTER POLYMER, METHOD FOR PRODUCING SAME, ACTIVE ENERGY RAY-CURABLE COMPOSITION, AND OPTICAL RECORDING MEDIUM
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP2792691A1

  公开（公告）日：2014-10-22

  A cured product that is reduced in warping and has high hardness can be obtained from an active energy ray-curable resin composition which uses a methacrylic acid ester polymer that has an acid value of 50 mg KOH/g or less and a transition metal content of 1 ppm or less, while containing 80% by mole or more of a polymer that has a double bond-terminated structure represented by formula (1). (In formula (1), R represents an alkyl group, a cycloalkyl group or an aryl group.)

  使用甲基丙烯酸酯聚合物的活性能量射线固化树脂组合物，其酸值不小于 50 毫克 KOH/克，过渡金属含量不小于 1 ppm，同时含有 80%（以摩尔计）或更多的具有式（1）表示的双键末端结构的聚合物，可以获得翘曲减少且硬度高的固化产品。(在式 (1) 中，R 代表烷基、环烷基或芳基）。