1-(5,5-Dimethylcyclohexen-1-yl)-5-hydroxy-4-methylpentan-2-one

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-(5,5-Dimethylcyclohexen-1-yl)-5-hydroxy-4-methylpentan-2-one
• 英文别名: 1-(5,5-dimethylcyclohexen-1-yl)-5-hydroxy-4-methylpentan-2-one
• 化学式: C₁₄H₂₄O₂
• 分子量: 224.34
• InChiKey: RVMVXJLQIVKXPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• SELECTIVE HYDROGENATION OF ALDEHYDES WITH RU/BIDENTATE LIGANDS COMPLEXES
  申请人：Firmenich SA

  公开号：EP2970067A1

  公开（公告）日：2016-01-20
• [EN] SELECTIVE HYDROGENATION OF ALDEHYDES WITH RU/BIDENTATE LIGANDS COMPLEXES<br/>[FR] HYDROGÉNATION SÉLECTIVE D'ALDÉHYDES AVEC DES COMPLEXES RU/LIGANDS BIDENTATES
  申请人：FIRMENICH & CIE

  公开号：WO2014139854A1

  公开（公告）日：2014-09-18

  The present invention relates to processes for the reduction by hydrogenation, using molecular H2, of a C5-C20 substrate containing one or two aldehydes functional groups into the corresponding alcohols or diol, characterized in that said process is carried out in the presence of - at least one catalyst or pre-catalyst in the form of a ruthenium complex having a coordination sphere of the N1P3O2, wherein the coordinating atom N and one coordinating atom P are provided by a first bidentate ligand, and the two other coordinating atoms P2 are provided by a second bidentate ligand and the coordinating atoms O2 are provided by two non- linear carboxylate ligands; and - optionally of an acidic additive.