butyl 2-methyl-5-phenylpenta-2,4-dienoate | 1314026-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: butyl 2-methyl-5-phenylpenta-2,4-dienoate
• 英文别名: butyl (2E,4E)-2-methyl-5-phenylpenta-2,4-dienoate
• CAS: 1314026-03-3
• 化学式: C₁₆H₂₀O₂
• 分子量: 244.334
• InChiKey: CUYNFAROHHHRHB-MXOVAJDFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯乙烯 、 甲基丙烯酸丁酯 在 silver hexafluoroantimonate 、 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 copper diacetate 作用下， 以 1,4-二氧六环 为溶剂， 反应 16.0h， 生成 butyl 2-methyl-5-phenylpenta-2,4-dienoate 、 butyl 2-methyl-5-phenylpenta-2,4-dienoate
  参考文献：
  名称：

  乙烯基类的C RhIII催化氧化烯化？H键：有效且选择性地获得二不饱和α-氨基酸衍生物和其他线性1,3-丁二烯

  摘要：

  烯烃在一起！开发了Rh III催化的不同烯烃的氧化交叉偶联反应，从而形成了有价值的线性丁二烯产物，尤其是二不饱和α-氨基酸衍生物。1,1-二，1,2-二和1,1,2-三取代的烯烃可以与苯乙烯和丙烯酸酯偶联。在这些反应中，获得了很高的化学，区域和立体选择性，这使其成为一种有价值的合成工具。

  DOI：

  10.1002/chem.201101340

文献信息

• POLYMER NANOPARTICLES
  申请人：Gruetzmacher Hansjoerg

  公开号：US20120115963A1

  公开（公告）日：2012-05-10

  A process for the preparation of a polymer nanoparticle by a photoinduced emulsion polymerization includes preparing an emulsion comprising at least one surfactant, a dispersed phase and a continuous phase. The dispersed phase comprises at least one polymerizable monomer and the continuous phase comprises water and at least one photoinitiator. The at least one polymerizable monomer is polymerized by exposing the emulsion to an electromagnetic radiation having a wavelength so as to induce a generation of radicals from the at least one photoinitiator. The at least one photoinitiator is selected from at least one compound of formula (I)

  通过光诱导乳液聚合制备聚合物纳米粒子的方法包括制备乳液，该乳液包括至少一种表面活性剂、分散相和连续相。分散相包括至少一种可聚合单体，连续相包括水和至少一种光引发剂。至少一种可聚合单体通过将乳液暴露于具有波长的电磁辐射而聚合，以诱导至少一种光引发剂产生自由基。至少一种光引发剂从公式（I）中的至少一种化合物中选择。
• Toner compositions
  申请人：XEROX CORPORATION

  公开号：EP0185509A1

  公开（公告）日：1986-06-25

  A toner composition comprised of resin particles, and pigment particles surface-treated with charge-enhancing additives selected from homopolymers of amine-containing monomers, copolymers containing amine monomers, quaternary ammonium salt compounds, polymeric amines, polymeric quaternary ammonium compounds, telomeric amines and telomeric quaternary ammonium salt compositions, wherein the charge-enhancing additives are associated with, or attached to, the pigment particles.

  一种墨粉组合物，由树脂颗粒和经电荷增强添加剂表面处理的颜料颗粒组成，电荷增强添加剂选自含胺单体的均聚物、含胺单体的共聚物、季铵盐化合物、聚合胺、聚合季铵盐化合物、端聚胺和端聚季铵盐组合物，其中电荷增强添加剂与颜料颗粒相关联或附着在颜料颗粒上。
• Uintaite-derived toners and printing inks
  申请人：AMERICAN GILSONITE COMPANY

  公开号：EP0632335A1

  公开（公告）日：1995-01-04

  A composition useful in copying and printing is described. In one embodiment, the composition comprises a purified fraction of uintaite and a thermoplastic polymer. Preferably, the composition comprises a maltene-enriched fraction of uintaite derived by solvent extraction, a thermoplastic polymer and a colorant. In another embodiment, the present invention is an electrophotographic method comprising the steps of generating a latent electrostatic image; developing said latent image with a toner comprising a purified fraction of uintaite; and fixing said toner. The present invention is also a printing ink emulsion comprising a maltene-enriched fraction of uintaite.

  本文描述了一种可用于复印和印刷的组合物。在一个实施方案中，该组合物由经过提纯的乌金土馏分和热塑性聚合物组成。优选地，该组合物包括通过溶剂萃取获得的富含麦芽烯的乌金土馏分、热塑性聚合物和着色剂。在另一个实施方案中，本发明是一种电子照相方法，包括以下步骤：生成潜伏静电图像；用包含uintaite纯化馏分的墨粉显影所述潜伏图像；以及固定所述墨粉。本发明也是一种印刷油墨乳剂，包含富含麦芽烯的uintaite馏分。
• Polyolefin dispersions, froths, and foams
  申请人：Dow Global Technologies LLC

  公开号：EP2399615A1

  公开（公告）日：2011-12-28

  Polyolefin dispersions, froths, and foams and articles manufactured therefrom are disclosed. Also disclosed is a method for generating a thermoplastic foam from an aqueous dispersion. The aqueous dispersion may include a thermoplastic resin, water, and a stabilizing agent. The method may include adding at least one frothing surfactant to the aqueous dispersion to form a mixture, adding a flame retardant and/or a phase change material, frothing the mixture to create a froth, and removing at least a portion of the water to produce the foam.

  本发明公开了聚烯烃分散体、泡沫和泡沫塑料以及用其制造的物品。还公开了一种从水性分散体生成热塑性泡沫的方法。水分散体可包括热塑性树脂、水和稳定剂。该方法可包括向水性分散液中添加至少一种起泡表面活性剂以形成混合物，添加阻燃剂和/或相变材料，使混合物起泡以产生泡沫，并除去至少一部分水以产生泡沫。
• Aqueous dispersions disposed on glass-based fibers and glass-containing substrates
  申请人：Dow Global Technologies LLC

  公开号：EP2433772A1

  公开（公告）日：2012-03-28

  The present invention relates to an article comprising: at least one layer of a compound disposed on at least a portion of a glass-containing substrate, wherein the compound comprises: (a) a polyolefin having a deformation temperature of less than 110°C; and (b) a dispersion stabilizing agent; and wherein the compound imparts a modified property to the substrate; and wherein the substrate is formable.

  本发明涉及一种物品，该物品包括：在含玻璃基底的至少一部分上设置的至少一层化合物，其中该化合物包括： (a) 聚烯烃，其变形温度低于 110°C；以及 (b) 一种分散稳定剂；以及 其中化合物赋予基底改性特性；以及基底可成型。