2,6-di(2-ethylhexyloxy)anthracene | 332083-43-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,6-di(2-ethylhexyloxy)anthracene
• 英文别名: 2,6-Bis[(2-ethylhexyl)oxy]anthracene；2,6-bis(2-ethylhexoxy)anthracene
• CAS: 332083-43-9
• 化学式: C₃₀H₄₂O₂
• 分子量: 434.662
• InChiKey: LLKIMPGBYPXOIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  32
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-di(2-ethylhexyloxy)anthracene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 DMF (N,N-dimethyl-formamide) 为溶剂， 以30%的产率得到9,10-dibromo-2,6-di(2-ethylhexyloxy)anthracene
  参考文献：
  名称：

  NOVEL SOLUBLE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICES

  摘要：

  一种新型可溶性化合物，是一种具有可溶性取代基和特定中心基团的二亚基芳烃衍生物，在有机溶剂中在20°C时的溶解度为0.5%或更高；以及具有有机薄膜层的有机电致发光器件，该有机薄膜层具有单层或多层，位于阴极和阳极之间，并且至少包含一层含有该新型可溶性化合物。有机薄膜层可以根据湿法工艺形成，可以轻松生产出具有良好发光效率的有机电致发光器件。

  公开号：

  EP1440959A1
• 作为产物：
  描述：

  2,6-di-(2'-ethylhexyloxy)-9,10-anthraquinone 在 tin 、 sodium tetrahydroborate 作用下， 以 溶剂黄146 、 异丙醇 为溶剂， 反应 2.0h， 以78%的产率得到2,6-di(2-ethylhexyloxy)anthracene
  参考文献：
  名称：

  NOVEL SOLUBLE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICES

  摘要：

  一种新型可溶性化合物，是一种具有可溶性取代基和特定中心基团的二亚基芳烃衍生物，在有机溶剂中在20°C时的溶解度为0.5%或更高；以及具有有机薄膜层的有机电致发光器件，该有机薄膜层具有单层或多层，位于阴极和阳极之间，并且至少包含一层含有该新型可溶性化合物。有机薄膜层可以根据湿法工艺形成，可以轻松生产出具有良好发光效率的有机电致发光器件。

  公开号：

  EP1440959A1

文献信息

• Electroluminescent devices having diarylanthracene polymers
  申请人：Eastman Kodak Company

  公开号：US20030082402A1

  公开（公告）日：2003-05-01

  An electroluminescent device comprises an anode, a cathode, and an emissive layer having a polymer luminescent material disposed between the anode and cathode, the polymer luminescent material includes diarylanthracene-based conjugated polymer having a repeating unit of the following formula: 1 wherein: Ar 1 , Ar 2 , and Ar are each individually aryl or substituted aryl of from 6 to 40 carbon atoms; or Ar 1 , Ar 2 , and Ar are each individually substituted heteroaryl or unsubstituted heteroaryl having 4 to 40 carbons.

  一种电致发光装置包括阳极、阴极和发光层，该发光层具有聚合物发光材料，该聚合物发光材料位于阳极和阴极之间，其中聚合物发光材料包括具有以下式的重复单元的二苯基蒽基共轭聚合物： 其中：Ar1、Ar2和Ar分别为6至40个碳原子的芳基或取代芳基；或者Ar1、Ar2和Ar分别为4至40个碳的取代杂环芳基或未取代杂环芳基。
• Novel soluble compound and organic electroluminescent devices
  申请人：Hosokawa Chishio

  公开号：US20050014017A1

  公开（公告）日：2005-01-20

  A novel soluble compound which is a distyrylarylene derivative having a soluble substituent and a specific central group and having a solubility of 0.5% by weight or greater at 20° C. in an organic solvent; and an organic electroluminescence device having an organic thin film layer which has a single layer or a plurality of layers, is disposed between a cathode and an anode and has at least one layer containing the novel soluble compound. The organic thin film layer can be formed in accordance with a wet process, and the organic electroluminescence device exhibiting a great efficiency of light emission can be produced easily.

  一种新型的可溶化合物，是一种具有可溶性取代基和特定中心基团的二苯乙烯衍生物，其在20℃时在有机溶剂中的溶解度为0.5%或更高；以及一种有机电致发光器件，其具有一个有机薄膜层，该有机薄膜层具有单层或多层，在阴极和阳极之间设置，并且至少包含一层含有该新型可溶化合物的层。该有机薄膜层可以通过湿法工艺形成，并且可以轻松地制造出具有高发光效率的有机电致发光器件。
• Electroluminescent devices having phenylanthracene-based polymers
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1088875A2

  公开（公告）日：2001-04-04

  An electroluminescent device comprises an anode, a cathode, and polymer luminescent materials disposed between the anode and cathode, the polymeric luminescent materials includes 9-(4-adamantanyl)phenyl)-10-phenylanthracene-based polymers of the following formula: wherein: substituents R, R1, R2, R3, R4 and R5 are each individually hydrogen, or alkyl or alkoxy of from 1 to 24 carbon atoms; aryl or substituted aryl of from 6 to 28 carbon atoms; or heteroaryl or substituted heteroaryl of from 4 to 40 carbons; or F, Cl, Br; or a cyano group; or a nitro group; wherein the ratio of n/(m+n) is between 0 to 1 wherein m and n are integers but m cannot be 0; and Y are divalent linking groups.

  一种电致发光装置包括阳极、阴极和置于阳极与阴极之间的聚合物发光材料，聚合物发光材料包括下式的9-(4-金刚烷基)苯基)-10-苯基蒽基聚合物： 其中 取代基 R、R1、R2、R3、R4 和 R5 分别为氢、或 1 至 24 个碳原子的烷基或烷氧基；或 6 至 28 个碳原子的芳基或取代芳基；或 4 至 40 个碳原子的杂芳基或取代杂芳基；或 F、Cl、Br；或氰基；或硝基； 其中 n/(m+n) 的比率介于 0 至 1 之间，其中 m 和 n 为整数，但 m 不能为 0；以及 Y 为二价连接基团。
• Electroluminescent devices having naphthylanthracene-based polymers
  申请人：EASTMAN KODAK COMPANY

  公开号：EP1094101A2

  公开（公告）日：2001-04-25

  An electroluminescent device comprises an anode, a cathode, and polymer luminescent materials disposed between the anode and cathode, the polymeric luminescent materials includes 9,10-di-(2-naphthyl)anthracene-based polymers of the following formula: wherein: R, R1, R2, R3, and R4 are each individually hydrogen, or alkyl, or alkoxy of from 1 to 24 carbon atoms; aryl or substituted aryl of from 6 to 28 carbon atoms; or heteroaryl or substituted heteroaryl of from 4 to 40 carbons; or F, Cl, or Br; or a cyano group; or a nitro group; X is a linking group; and Y includes one or more comonomer units that are a substituted or unsubstituted alkyl, alkenyl, aryl, or heteroaryl or a conjugated group.

  一种电致发光装置包括阳极、阴极和置于阳极与阴极之间的聚合物发光材料，聚合物发光材料包括下式的 9,10-二(2-萘基)蒽基聚合物： 其中 R、R1、R2、R3 和 R4 分别是氢、或烷基、或 1 至 24 个碳原子的烷氧基；或 6 至 28 个碳原子的芳基或取代芳基；或 4 至 40 个碳原子的杂芳基或取代杂芳基；或 F、Cl 或 Br；或氰基；或硝基； X 是连接基团 Y 包括一个或多个共聚单体单元，它们是取代或未取代的烷基、烯基、芳基、杂芳基或共轭基团。
• Synthesis, Thermal, and Light-Emitting Properties of Anthracene Derivatives
  作者：Pradip K. Bhowmik、Alexi K. Nedeltchev、Haesook Han

  DOI：10.1080/15421400802697707

  日期：2009.3.19

  Several anthracene derivatives were prepared by a single-step reaction and characterized their thermal properties by differential scanning calorimetry (DSC) and thermogravimetric analyses. Their photoluminescence properties were examined in a large number of organic solvents of increased polarity that included toluene, chloroform, tetrahydrofuran, acetone, methanol, acetonitrile, and dimethyl sulfoxide. Some compounds exhibited emission spectra with vibrational fine structures in organic solvents; and other compounds exhibited structureless emission spectra in organic solvents.