Embodiments herein relates to a Bisphenol A-free multi-layer biaxially oriented polyester (BOPET) film, for lamination on metal sheets, which could be used for food containers. The BOPET film has at least one outer release layer, which aids in the release of food, such as a high protein food source, when food is cooked and sterilized in direct contact with the outer release layer. The BOPET film can be laminated to metals used in the manufacture of food containers with the outer release layer being exposed to allow a direct food contact between the surface of the outer release layer and food. More particularly, the invention relates to a novel outer release layer resin composition comprising an ultra high molecular weight siloxane polymer and a polyethylene trephthalate resin; and an alkali-metal phosphate and a phosphoric acid compound added, during polymerization of the outer release layer resin composition, as a catalyst/additive package to the ingredients forming the outer release layer resin composition. A wax component can be added in the outer release layer, for more robust release performance.
本实施例涉及一种不含双
酚 A 的多层双向拉伸聚酯(BOPET)薄膜,用于在
金属板上层压,可用于食品容器。这种 BOPET 薄膜至少有一层外脱模层,当食物与外脱模层直接接触进行烹饪和消毒时,外脱模层有助于食物(如高蛋白食物源)的脱模。BOPET 薄膜可与用于制造食品容器的
金属层压,外脱模层暴露在外,使外脱模层表面与食物直接接触。更具体地说,本发明涉及一种新型外脱模层
树脂组合物,该组合物包括一种超高分子量
硅氧烷聚合物和一种聚
对苯二甲酸乙二醇酯
树脂;以及一种碱
金属
磷酸盐和一种
磷酸化合物,在外层脱模层
树脂组合物的聚合过程中,作为催化剂/添加剂包添加到形成外脱模层
树脂组合物的成分中。外脱模层中还可添加蜡成分,以获得更强的脱模性能。