n-amyl angelate | 229344-98-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: n-amyl angelate
• 英文别名: Pentyl 2-methylbut-2-enoate
• CAS: 229344-98-3
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: XJWDRSSGOHXOLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  dioctyl laurate 、 mmφ PEG 、 2-甲基-2-丁烯酸甲酯 生成 n-amyl angelate
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Manufacture of optical fiber and optical fiber tape
  申请人：——

  公开号：US20020028287A1

  公开（公告）日：2002-03-07

  An optical fiber having one or more resin coatings is manufactured by applying at least one electron beam-curable resin composition to a bare optical fiber, and exposing the resin composition to electron beams to cure the resin composition. The EB-curable resin composition contains (A) 10-90% by weight of a urethane (meth)acrylate oligomer and (B) 90-10% by weight of a reactive diluent. The exposure to electron beams is done under conditions including (a) an acceleration voltage of 50-150 kV, (b) a distance of 0.5 mm to less than 10 mm between an electron beam window and the optical fiber surface, (c) an atmosphere of nitrogen or helium under atmospheric pressure, having (d) an oxygen concentration of up to 1,000 ppm, and (e) at least two directions of irradiation to the optical fiber.

  一种具有一种或多种树脂涂层的光纤的制造方法，包括将至少一种电子束固化树脂组合物施加到裸光纤上，并将树脂组合物暴露于电子束以固化树脂组合物。该EB-固化树脂组合物包含（A）10-90重量％的聚氨酯（甲基）丙烯酸酯低聚体和（B）90-10重量％的反应性稀释剂。电子束的暴露条件包括（a）50-150 kV的加速电压，（b）电子束窗口和光纤表面之间的距离为0.5毫米至小于10毫米，（c）氮气或氦气的大气压下，具有（d）高达1,000 ppm的氧气浓度，以及（e）对光纤进行至少两个方向的照射。
• PROCESS FOR PREPARING ANGELIC ACID OR ITS ESTER
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0112394A1

  公开（公告）日：1984-07-04

  A process for preparing angelic acid or its ester useful as perfume material, which comprises isomerizing tiglic acid using an organic sulfinic acid as a catalyst, and novel angelate esters represented by formula (I), wherein R represents 3-hexenyl,3-methyl-2-butenyl, 3-methyl-3-butenyl, 3-methyl-2-pentenyl, 3-methyl-4-pentenyl, CH3(CH2) (where is an integer of 5 to 9), cyclopentyl, cyclohexyl, 2-methylpentyl, a-methylbenzyl, neryl or furfuryl.

  一种制备用作香水材料的当归酸或其酯的工艺，包括使用有机亚硫酸作为催化剂使惕各酸异构化，以及由式（I）代表的新型当归酸酯，其中 R 代表 3-己烯基、3-甲基-2-丁烯基、3-甲基-3-丁烯基、3-甲基-2-戊烯基、3-甲基-4-戊烯基、CH3(CH2)（其中为 5 至 9 的整数）、环戊基、环己基、2-甲基戊基、a-甲基苄基、橙花酰基或糠酰基。
• Catalysts having alkoxide-modified supports
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0225953A1

  公开（公告）日：1987-06-24

  A catalyst composition comprises a catalytic metal and a support, the support being prepared by depositing a metal alkoxide salt on a core support, and then calcining the support.

  催化剂组合物由催化金属和载体组成，载体的制备方法是在核心载体上沉积金属烷氧基盐，然后煅烧载体。
• Fluorine-containing mono- or poly-alkylene glycol and method for producing same
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0297822A1

  公开（公告）日：1989-01-04

  The novel fluorine-containing mono- or poly-­alkylene glycol of this invention is a mono- or poly-alkylene glycol of the formula (I): wherein R¹, R² and R³ independently represent a hydrogen atom or an alkyl group having 1 to 30 carbon atoms, A represents a hydrogen atom, an unsaturated hydrocarbon group having 1 to 30 carbon atoms, a polar group or a polar group substituted with an unsaturated hydrocarbon group having 1 to 100 carbon atoms, B represents the same as the group selected from the group of A, provided that both A and B are not hyudrogen atom, or a hydro­carbon group having 1 to 30 carbon atoms which may contain an oxygen atom or fluorine atom, x represents an integer of 0 to 100, and n represents an integer of 1 to 1000, the mono- or poly-oxyalkylene group in the main chain of the mono- or poly-alkylene glycol having at least one fluorine-substituted hydrocarbon group with 2 to 30 carbon atoms having at least 3 fluorine atoms bonded thereto graft-bonded onto the mono- or poly-­oxyalkylene group in the main chain of the mono- or poly-alkylene glycol per one molecule of the mono- or poly-alkylene glycol.

  本发明的新型含氟单-或聚亚烷基二醇是式(I)的单-或聚亚烷基二醇： 其中 R¹、R² 和 R³ 独立地代表氢原子或具有 1 至 30 个碳原子的烷基，A 代表氢原子、具有 1 至 30 个碳原子的不饱和烃基、极性基团或被具有 1 至 100 个碳原子的不饱和烃基取代的极性基团，B 代表与选自 A 组的基团相同的基团，条件是 A 和 B 都不是偶氮原子，或具有 1 至 30 个碳原子的烃基，其中可含有氧原子或氟原子、x 代表 0 至 100 的整数，n 代表 1 至 1000 的整数，单亚或聚亚烷基二醇主链中的单亚或聚亚烷基二醇，每一个单亚或聚亚烷基二醇分子中至少有一个具有 2 至 30 个碳原子的氟取代烃基，其上至少键合有 3 个氟原子，接枝键合到单亚或聚亚烷基二醇主链中的单亚或聚亚烷基二醇上。
• Radiation-curable liquid resin composition suitable for coating optical fibers and optical fiber coated therewith
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0970978A1

  公开（公告）日：2000-01-12

  A radiation-curable liquid resin composition contains (A) an organopolysiloxane having a (meth)acryl group at either end of its molecular chain, containing at least 15 mol% of aromatic hydrocarbon groups based on the entire organic groups, and being free of a urethane bond, (B) a compound having at least one ethylenically unsaturated group in a molecule, and (C) a photopolymerization catalyst. The composition has a low viscosity and cures into a product having a low Young's modulus and experiencing a less change of Young's modulus at low temperatures. The composition is useful as a primary coating for optical fibers.

  一种辐射固化液体树脂组合物含有：(A) 分子链两端带有一个（甲基）丙烯酰基的有机聚硅氧烷，该有机聚硅氧烷含有至少 15 摩尔%的芳香烃基团（以整个有机基团计算），且不含氨基甲酸酯键；(B) 分子中含有至少一个乙烯不饱和基团的化合物；(C) 光聚合催化剂。该组合物粘度低，固化成的产品具有较低的杨氏模量，在低温下杨氏模量的变化较小。该组合物可用作光纤的主涂层。