3-(acryloyloxy)-1-propanesulfonic acid | 39121-78-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-(acryloyloxy)-1-propanesulfonic acid
• 英文别名: γ-Acryloxypropansulfonsaeure；3-Acryloyloxypropane-1-sulfonic acid；3-sulphopropyl acrylate；acrylic acid (3-sulphopropyl) ester；acryl-(3-sulfopropyl)-ester；3-sulfopropyl acrylate；3-prop-2-enoyloxypropane-1-sulfonic acid
• CAS: 39121-78-3
• 化学式: C₆H₁₀O₅S
• 分子量: 194.208
• InChiKey: NYUTUWAFOUJLKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  89
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-(acryloyloxy)-1-propanesulfonic acid 、 三(3,6-二氧杂庚基)胺 以 水 为溶剂， 反应 10.0h， 以99%的产率得到
  参考文献：
  名称：

  聚电解质作为溶剂和反应介质

  摘要：

  通过丙烯酸酯型离子液体单体的自由基聚合合成了一种玻璃化转变温度相当低（-57°C）的聚（离子液体）。它在从室温到热分解阈值的宽温度范围内表现出流体行为。我们证明它可以作为一种独特的大分子溶剂来溶解各种化合物和聚合物并分离物质。此外，这种聚电解质可以成功地用作催化和胶体颗粒合成的反应介质。溶剂化和稳定特性的协同作用是这种聚合物的显着特征，可缩小原位生成的颗粒尺寸。

  DOI：

  10.1021/ja409395y

文献信息

• Copolymers Based on N-Vinylpyrrolidone and Branched Aliphatic Carbonxylic Acids, and Their Use as Solubilizers
  申请人：Angel Maximilian

  公开号：US20080200564A1

  公开（公告）日：2008-08-21

  Copolymers comprising: (a) 60 to 99% by weight of at least one monomer selected from the group consisting of N-vinyllactams, N-vinylamides, and mixtures thereof; (1) 1 to 40% by weight of at least one monomer selected from the group consisting of vinyl esters of aliphatic branched C 8 -C 30 -carboxylic acids; (c) 0 to 30% by weight of vinyl acetate; and (d) 0 to 39% by weight of at least one additional free-radically copolymnerizable monomer; wherein the % by weight content of components (a), (b), (c) and (d) totals 100%, and with the proviso that the total amount of component (b) and component (c) combined is 1 to 40% by weight based on the copolymer, are described along with methods of using such copolymers to solubilize substances which are insoluble in water, substances which are only sparingly soluble in water, and combinations thereof.

  共聚物包含：（a）60至99重量百分比的至少一种单体，选自N-乙烯基内酰胺、N-乙烯酰胺和它们的混合物；（b）1至40重量百分比的至少一种单体，选自支链的C8-C30脂肪族羧酸的乙烯酯；（c）0至30重量百分比的乙酸乙烯酯；和（d）0至39重量百分比的至少一种额外的自由基共聚单体；其中，组分（a）、（b）、（c）和（d）的重量百分比总和为100%，并且有条件规定组分（b）和组分（c）的总和基于共聚物为1至40重量百分比。还描述了使用这样的共聚物来增溶水不溶性物质、水微溶性物质以及它们的组合的方法。
• [EN] FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME<br/>[FR] POLYMERSOMES ET NANORÉACTEURS SENSIBLES À LA FORCE; PROCÉDÉS LES UTILISANT
  申请人：ADOLPHE MERKLE INSTITUTE UNIV OF FRIBOURG

  公开号：WO2019034597A1

  公开（公告）日：2019-02-21

  The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled into polymersomes. The nucleobases formed hydrogen bonds which were disrupted upon force stimulation. The exposure of the disconnected nucleobases to the hydrophobic matrix of the membranes lead to a change of permeability which permitted the exchange of water-soluble molecules throughout the polymer matrix. Moreover, the encapsulation of horseradish peroxidase enabled the reaction of luminol with hydrogen peroxide to yield a luminescence producing species similar to the marine bioluminescence. Moreover, the same nano-reactors were employed to catalyze the formation of a polyacrylamide gel when force was applied. Insights into the change of permeability of supramolecular networks upon force are provided. These systems are useful for drug delivery, as nanoreactors and for the selective release of curing agents for 3D printing, or fragrances.

  DNA的机械诱导熔化特性被用来实现易受力破裂的膜。核碱基对被用作机械感受器。腺嘌呤和胸腺嘧啶功能化的互补两性分块共聚物自组装成聚合体囊。核碱基形成氢键，在受力刺激下被破坏。断开的核碱基暴露在膜的疏水基质中，导致渗透性的改变，从而允许水溶性分子在聚合物基质中交换。此外，封装辣根过氧化物酶使得辣根酰胺与过氧化氢反应产生类似海洋生物发光的发光物种。此外，当施加力时，相同的纳米反应器被用来催化聚丙烯酰胺凝胶的形成。提供了关于受力下超分子网络渗透性变化的见解。这些系统可用于药物传递、纳米反应器以及用于3D打印的固化剂或香料的选择性释放。
• [EN] POLYMERIZABLE COMPOSITION COMPRISING AN OXIME SULFONATE AS THERMAL CURING AGENT<br/>[FR] COMPOSITION POLYMÉRISABLE COMPRENANT UN SULFONATE D'OXIME EN TANT QU'AGENT DE DURCISSEMENT THERMIQUE
  申请人：BASF SE

  公开号：WO2012101245A1

  公开（公告）日：2012-08-02

  The present invention relates to a polymerizable composition comprising at least one ethylenically unsaturated, polymerizable compound and at least one oxime sulfonate compound of the formula (I) QAaBbCc where a is 0, 1, 2, 3, 4 or 6, b is 0, 1, 2, 3, 4 or 6, and c is 0, 1, 2, 3, 4 or 6, where the sum of a + b + c is 1, 2, 3, 4 or 6 where (A) is a group (B) is a group (C) is a group where # denotes the point of attachment to Q; X is S or NR14 and Q, R1, R2, R3 and R14 are as defined in claim 1 and in the description. The present invention also relates to the use of the this composition, to novel oxime sulfonates and the use of the oxime sulfonates as thermal curing promoter.

  本发明涉及一种可聚合的组成，包括至少一种乙炔基不饱和的可聚合化合物和至少一种具有公式（I）QAaBbCc的亚硝基亚磺酸酯化合物，其中a为0、1、2、3、4或6，b为0、1、2、3、4或6，c为0、1、2、3、4或6，其中a+b+c的总和为1、2、3、4或6，其中（A）是一个基团，（B）是一个基团，（C）是一个基团，其中#表示与Q连接的点；X是S或NR14，Q、R1、R2、R3和R14如权利要求1和说明书中所定义。本发明还涉及使用这种组成物，新型亚硝基亚磺酸酯及其作为热固化促进剂的应用。
• Ionic hydrogels with controlled aqueous fluid absorption
  申请人：Munro Semple Hugh

  公开号：US20060068014A1

  公开（公告）日：2006-03-30

  A cross-linked plasticised polymeric hydrogel suitable for use in mammalian body tissue (e.g. skin) contacting applications, which comprises a cross-linked copolymer formed from a first monomer comprising one or more pendant anionic group and a second monomer comprising one or more pendant cationic group, the relative amounts of the said monomers in the copolymer being such that the anionic groups and cationic groups are present in essentially equimolar quantities.

  一种适用于哺乳动物体组织（例如皮肤）接触应用的交联增塑聚合物水凝胶，包括由第一单体形成的交联共聚物，该第一单体包括一个或多个偏挂阴离子基团，以及由第二单体形成的交联共聚物，该第二单体包括一个或多个偏挂阳离子基团，所述单体在共聚物中的相对量使得阴离子基团和阳离子基团以基本等摩尔量存在。
• [EN] SOLUTIONS OF TRIALKALI METAL SALTS OF AMINOCARBOXYLIC ACIDS, THEIR MANUFACTURE AND USE<br/>[FR] SOLUTIONS DE SELS DE MÉTAL TRIALCALIN D'ACIDES AMINOCARBOXYLIQUES, LEUR FABRICATION ET LEUR UTILISATION
  申请人：BASF SE

  公开号：WO2016058875A1

  公开（公告）日：2016-04-21

  Aqueous solution containing in the range of from 60.5 to 75 % by weight of a mixture of trialkalimetal salts of the L-and D-enantiomers of methyl glycine diacetic acid (MGDA), said mixture containing predominantly the respective L-isomer with an enantiomeric excess (ee) in the range of from 3 to 97%, wherein said trialkali metal salts have the general formula (I) [CH3-CH(COO)-N(CH2-COO)2]K3-xNax (I) wherein x is in the range of from zero to 2.9.

  含有从60.5%到75%重量比的三碱金属盐混合物的水溶液，该混合物主要包含甲基甘氨酸二乙酸(L和D对映体)的相应L异构体，其对映体过量（ee）范围为3%到97%，其中所述的三碱金属盐具有通式(I) [CH3-CH(COO)-N(CH2-COO)2]K3-xNax (I)，其中x在0到2.9的范围内。