p-methoxyphenylhydrazine | 114693-48-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-methoxyphenylhydrazine
• 英文别名: p-Methoxy-phenyl-diazen；4-Meth-oxyphenyldiazene；(4-methoxyphenyl)diazene
• CAS: 114693-48-0
• 化学式: C₇H₈N₂O
• 分子量: 136.153
• InChiKey: XYEDWKJIWCXMIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  45.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  p-methoxyphenylhydrazine 、 phenyl(5-phenyl-1,2-oxazol-3-yl)methanone 以 溶剂黄146 为溶剂， 生成 N-(4-Methoxy-phenyl)-N'-[1-phenyl-1-(5-phenyl-isoxazol-3-yl)-meth-(Z)-ylidene]-hydrazine
  参考文献：
  名称：

  Frenna, Vincenzo; Vivona, Nicolo; Macaluso, Gabriella, Journal of the Chemical Society. Perkin transactions II, 1987, p. 537 - 540

  摘要：

  DOI：
• 作为产物：
  描述：

  4-methoxybenzenediazonium hexafluorophosphate 在 trans,trans-W(H)(CO)2(NO)(PPh3)2 、 四丁基溴化铵 作用下， 生成 p-methoxyphenylhydrazine
  参考文献：
  名称：

  Stereoselective synthesis of monosubstituted cis-aryldiazenes, NH:NR

  摘要：

  DOI：

  10.1021/ja00220a072

文献信息

• [EN] COLORED CURABLE COMPOSITION, COLOR RESIST, INK-JET INK, COLOR FILTER AND METHOD FOR PRODUCING THE SAME, SOLID-STATE IMAGE PICKUP DEVICE, IMAGE DISPLAY DEVICE, LIQUID CRYSTAL DISPLAY, ORGANIC EL DISPLAY, AND COLORANT COMPOUND AND TAUTOMER THEREOF<br/>[FR] COMPOSITION COLORÉE DURCISSABLE, RÉSINE COLORÉE, ENCRE POUR IMPRESSION À JET D'ENCRE, FILTRE DE COULEUR ET PROCÉDÉ DE PRODUCTION ASSOCIÉ, DISPOSITIF DE PRISE D'IMAGES À SEMI-CONDUCTEURS, DISPOSITIF D'AFFICHAGE D'IMAGES, AFFICHEUR À CRISTAUX LIQUIDES,
  申请人：FUJIFILM CORP

  公开号：WO2010143745A1

  公开（公告）日：2010-12-16

  A colored curable composition including: at least one selected from the group consisting of a compound represented by the following Formula (1a) and a tautomer thereof; and at least one polymerizable compound, wherein R11, R12, R13, R14, R15, and R16 each independently represent a hydrogen atom or a monovalent substituent; and R11 and R12, and R15 and R16 independently may bond to each other in each pair to form a ring.

  包含至少以下之一的彩色可固化组合物：由以下公式（1a）表示的化合物及其互变异构体之一；以及至少一种可聚合化合物，其中R11、R12、R13、R14、R15和R16各自独立代表一个氢原子或单价取代基；并且R11和R12，以及R15和R16各自可以相互结合形成环。
• [EN] AZO PIGMENTS, AND PIGMENT DISPERSION, COLORING COMPOSITION AND INK FOR INKJET RECORDING CONTAINING THE AZO PIGMENT<br/>[FR] PIGMENTS AZOÏQUES, DISPERSION DE PIGMENTS, COMPOSITION COLORANTE ET ENCRE POUR IMPRESSION À JET D'ENCRE CONTENANT LE PIGMENT AZOÏQUE
  申请人：FUJIFILM CORP

  公开号：WO2009110643A1

  公开（公告）日：2009-09-11

  Provided is an azo pigment represented by the following general formula (1), a tautomer of the azo pigment, and a salt or a hydrate thereof: General formula (1) wherein Q represents the non-metallic atoms necessary to complete a 5- to 7-membered heterocyclic group, W represents an alkoxy group, an amino group, an alkyl group, or an aryl group, X1 and X2 each independently represents a hydrogen, an alkyl group, an acyl group, an alkylsulfonyl group, or an arylsulfonyl group, R1 represents a hydrogen or a substituent, R2 represents a heterocyclic group, n represents an integer of from 1 to 4 and the general formula (1) represents a dimer formed through Q, W, X1, X2, R1, or R2 when n=2, a trimer formed through Q, W, X1, X2, R1, or R2 when n=3, and a tetramer formed through Q, W, X1, X2, R1, or R2 when n=4.

  提供的是以下一般式（1）所代表的偶氮颜料，偶氮颜料的互变异构体，以及其盐或水合物：一般式（1）中，Q代表必要的非金属原子，以完成一个5-至7-成员杂环基团，W代表烷氧基、氨基、烷基或芳基，X1和X2分别独立地代表氢、烷基、酰基、烷基磺酰基或芳基磺酰基，R1代表氢或取代基，R2代表杂环基团，n代表1至4的整数，一般式（1）代表当n=2时通过Q、W、X1、X2、R1或R2形成的二聚体，当n=3时通过Q、W、X1、X2、R1或R2形成的三聚体，以及当n=4时通过Q、W、X1、X2、R1或R2形成的四聚体。
• Fluorogenic compounds converted to fluorophores by photochemical or chemical means and their use in biological systems
  申请人：Tweg Robert J.

  公开号：US20100029952A1

  公开（公告）日：2010-02-04

  Fluorophores derived from photoactivatable azide-pi-acceptor fluorogens or from a thermal reaction of an azide-pi-acceptor fluorogen with an alkene or alkyne are disclosed. Fluorophores derived from a thermal reaction of an alkyne-pi-acceptor fluorogen with an azide are also disclosed. The fluorophores can readily be activated by light and can be used to label a biomolecule and imaged on a single-molecule level in living cells.

  从可光活化的叠氮-π-受体荧光发色团或从叠氮-π-受体荧光发色团与烯烃或炔烃的热反应中衍生的荧光色团被披露。还披露了从炔烃-π-受体荧光发色团与叠氮的热反应中衍生的荧光色团。这些荧光色团可以很容易地被光激活，并可用于标记生物分子，并在活细胞中以单分子水平进行成像。
• [EN] NEW PROCESS FOR PREPARING ARYLBORANES BY ARYLATION OF ORGANOBORON COMPOUNDS<br/>[FR] NOUVEAU PROCÉDÉ POUR LA PRÉPARATION D'ARYLBORANES PAR ARYLATION DE COMPOSÉS ORGANOBORÉS
  申请人：UNIV BORDEAUX 1

  公开号：WO2014009169A1

  公开（公告）日：2014-01-16

  The present invention relates to a new process for the preparation of an arylborane compound, by arylation of a B-H bond, which comprises a step (1) of contacting an arenediazonium salt or a heteroarenediazonium salt with an organoboron compound containing at least one B-H bond, in a reaction medium containing a solvent, in the absence of base, in the absence or in the presence of an activating agent, for the preparation of an arylborane compound, and a possible step (2) of recovery and purification of said arylborane compound obtained at the step (1), said arylborane being in particular an aminoarylborane, and a possible step (3) of refunctionalisation of said arylborane obtained at step (1) or (2) for the preparation of aryl boronic derivatives or arylborates.

  本发明涉及一种制备芳基硼烷化合物的新工艺，通过芳基硼-氢键的芳基化，包括以下步骤：(1)将芳基重氮盐或杂环芳基重氮盐与至少含有一个硼-氢键的有机硼化合物在反应介质中接触，所述反应介质包含溶剂，在无碱的情况下，在缺乏或存在活化剂的情况下，用于制备芳基硼烷化合物，并可能进行(2)步骤以回收和纯化在步骤(1)中得到的所述芳基硼烷化合物，所述芳基硼烷化合物特别是氨基芳基硼烷，以及可能进行(3)步骤对在步骤(1)或(2)中得到的所述芳基硼烷进行重官能化，用于制备芳基硼酸衍生物或芳基硼酸酯。
• [EN] MOLECULAR SWITCHES BASED ON CIS/TRANS ISOMERIZATION OF BF2-COORDINATED AZO COMPOUNDS<br/>[FR] COMMUTATEURS MOLÉCULAIRES BASÉS SUR L'ISOMÉRISATION CIS/TRANS DE COMPOSÉS AZOÏQUES COORDONNÉS PAR BF2
  申请人：DARTMOUTH COLLEGE

  公开号：WO2015031518A1

  公开（公告）日：2015-03-05

  Provided herein are photochromic organic compounds of Formula I or Formula II, which are useful as molecular switches capable of being triggered via a cis/trans isomerization process. Methods of using the molecular switch compounds to form photopharmaceutical compounds that may be used to provide selective spatiotemporal activation of pharmaceutical agents are also disclosed.

  本文提供的是化学式I或化学式II的光致变色有机化合物，它们可作为分子开关使用，可通过顺反异构化过程触发。还公开了使用这些分子开关化合物形成光药物化合物的方法，这些化合物可用于提供药物代理的选择性时空激活。