| 1108157-30-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1108157-30-7
• 化学式: C₃₆H₄₈N₂O₆S
• 分子量: 636.853
• InChiKey: CAPVJZYVAWWQFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.97
• 重原子数：
  45.0
• 可旋转键数：
  21.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  103.29
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  在 sodium methylate 作用下， 以 吡啶 为溶剂， 反应 0.25h， 生成
  参考文献：
  名称：

  Synthesis of a π-conjugated oligomer–fullerene dyad through a versatile [6,6]diphenylmethanofullerene carboxylic acid

  摘要：

  In this article we describe the synthesis of an electron donor-acceptor dyad containing a [6,6]diphenylmethanofullerene moiety as the electron acceptor and a dialkylamino-substituted oligo-p-phenyl-enevinylene as the electron donor. The synthesis of this material has been successfully accomplished by an esterification reaction between a [6,6]diphenylmethanofullerene functionalized with a carboxylic acid and the corresponding oligomer substituted with a benzyl alcohol. Cyclic voltammetry and absorption spectroscopy show that both electroactive units preserve their nature in the ground state, whereas preliminary photophysical investigations show a strong fluorescence quenching. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.10.077
• 作为产物：
  描述：

  Ethyl 2-[4-(4-dodecoxybenzoyl)phenoxy]acetate 、 对甲苯磺酰肼 在 对甲苯磺酸 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 72.0h， 以53%的产率得到
  参考文献：
  名称：

  Synthesis of a π-conjugated oligomer–fullerene dyad through a versatile [6,6]diphenylmethanofullerene carboxylic acid

  摘要：

  In this article we describe the synthesis of an electron donor-acceptor dyad containing a [6,6]diphenylmethanofullerene moiety as the electron acceptor and a dialkylamino-substituted oligo-p-phenyl-enevinylene as the electron donor. The synthesis of this material has been successfully accomplished by an esterification reaction between a [6,6]diphenylmethanofullerene functionalized with a carboxylic acid and the corresponding oligomer substituted with a benzyl alcohol. Cyclic voltammetry and absorption spectroscopy show that both electroactive units preserve their nature in the ground state, whereas preliminary photophysical investigations show a strong fluorescence quenching. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.10.077

文献信息

• Synthesis of a π-conjugated oligomer–fullerene dyad through a versatile [6,6]diphenylmethanofullerene carboxylic acid
  作者：Rafael Gómez、José L. Segura

  DOI：10.1016/j.tet.2008.10.077

  日期：2009.1

  In this article we describe the synthesis of an electron donor-acceptor dyad containing a [6,6]diphenylmethanofullerene moiety as the electron acceptor and a dialkylamino-substituted oligo-p-phenyl-enevinylene as the electron donor. The synthesis of this material has been successfully accomplished by an esterification reaction between a [6,6]diphenylmethanofullerene functionalized with a carboxylic acid and the corresponding oligomer substituted with a benzyl alcohol. Cyclic voltammetry and absorption spectroscopy show that both electroactive units preserve their nature in the ground state, whereas preliminary photophysical investigations show a strong fluorescence quenching. (C) 2008 Elsevier Ltd. All rights reserved.