(3-Ethyl-2,4,4-trimethylpentan-2-yl)oxy 2-ethylhexaneperoxoate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (3-Ethyl-2,4,4-trimethylpentan-2-yl)oxy 2-ethylhexaneperoxoate
• 英文别名: (3-ethyl-2,4,4-trimethylpentan-2-yl)oxy 2-ethylhexaneperoxoate
• 化学式: C₁₈H₃₆O₄
• 分子量: 316.5
• InChiKey: MXFKCOPKUSJLSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  22
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• [EN] MULTIFUNCTIONAL FLUORINATED COMPOUND, FLUORINATED POLYMERS MADE FROM THE COMPOUND, AND RELATED METHODS<br/>[FR] COMPOSÉ FLUORÉ MULTIFONCTIONNEL, POLYMÈRES FLUORÉS FABRIQUÉS À PARTIR DU COMPOSÉ, ET PROCÉDÉS ASSOCIÉS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020245724A1

  公开（公告）日：2020-12-10

  The multifunctional compound is represented by formula X-C(R)RF-Y, in which X and Y are each independently -C(O)-O-M, -C(O)-HAL, -C(O)-NR1 2, -C≡N, -C(O)NR1-SO2-Rf 1-W, or a fluorinated alkenyl group that is optionally interrupted by one or more -O- groups. HAL is -F, -Cl, or -Br. Rf 1 is a fluorinated alkylene group that is optionally interrupted by one or more -O- groups. W is -F, -SO2Z, -CF=CF2, -O-CF=CF2, or -O-CF2-CF=CF2. Z is -F, - Cl, -NR1 2, or -OM. Each R1 is a hydrogen atom or alkyl having up to four carbon atoms. M is an alkyl group, a trimethylsilyl group, a hydrogen atom, a metallic cation, or a quaternary ammonium cation. R is a bromine, chloride, fluorine or hydrogen atom; and RF is a fluorinated alkenyl group that is unsubstituted or substituted by at least one chlorine atom, aryl group, or a combination thereof or RF is a fluorinated alkyl group or arylalkylenyl group that is substituted by bromine or iodine and uninterrupted or interrupted by at least one -O- group. A process for making the compound is also disclosed. A fluoropolymer made from the compound and a method of making the fluoropolymer are also disclosed.

  多功能化合物由公式X-C（R）RF-Y表示，其中X和Y分别独立为-C（O）-O-M，-C（O）-HAL，-C（O）-NR1 2，-C≡N，-C（O）NR1-SO2-Rf1-W或者是一种可选地由一个或多个-O-组分隔的氟代烯基。HAL为-F，-Cl或-Br。Rf1是一种可选地由一个或多个-O-组分隔的氟代烷基。W为-F，-SO2Z，-CF=CF2，-O-CF=CF2或-O-CF2-CF=CF2。Z为-F，-Cl，-NR1 2或-OM。每个R1是一个氢原子或具有最多四个碳原子的烷基。M是一种烷基，三甲基硅基，氢原子，金属阳离子或季铵阳离子。R是溴，氯，氟或氢原子；RF是一种未被取代或被至少一个氯原子，芳基或两者的组合所取代的氟代烯基，或者RF是一种被溴或碘取代并且被至少一个-O-组所中断或未中断的氟代烷基或芳基烷基。还公开了制备该化合物的方法。还公开了由该化合物制成的氟聚合物以及制备氟聚合物的方法。
• Composite particles including a fluoropolymer, methods of making, and articles including the same
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10351694B2

  公开（公告）日：2019-07-16

  A composite particle includes a discrete, hollow, ceramic spheroid and a fluoropolymer layer disposed thereon. The fluoropolymer is a homopolymer or copolymer of a perfluoroalkyl vinyl ether; a perfluoroalkoxy vinyl ether; at least one fluoroolefin independently represented by formula C(R)2═CF—Rf, wherein Rf is fluorine or a perfluoroalkyl having from 1 to 8 carbon atoms and R is hydrogen, fluorine, or chlorine; or a combination thereof. Methods of making the composite particles, composite materials, and articles including them are also disclosed.

  一种复合微粒包括一个离散的中空陶瓷球体和置于其上的含氟聚合物层。氟聚合物是全氟烷基乙烯基醚、全氟烷氧基乙烯基醚、至少一种由式 C(R)2═CF-Rf 独立表示的氟烯烃的均聚物或共聚物，其中 Rf 是氟或具有 1 至 8 个碳原子的全氟烷基，R 是氢、氟或氯；或它们的组合。还公开了制造复合颗粒、复合材料和包括它们的物品的方法。
• Peroxide-curable fluoropolymer composition including solvent and method of using the same
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US11130829B2

  公开（公告）日：2021-09-28

  A curable composition that includes an amorphous, peroxide-curable fluoropolymer having a first solubility parameter, a solvent having a second solubility parameter, and a peroxide. The amorphous, peroxide-curable fluoropolymer is present from 60 percent to 97.5 percent by weight versus the weight of the curable composition, and the solvent is present from 1 percent to 39 percent by weight versus the weight of the curable composition. The absolute value of the first solubility parameter minus the second solubility parameter is less than or equal to 8.2 (MPa)1/2. The solvent may have a solubility parameter in a range from 9.6 (MPa)1/2 to 26 (MPa)1/2. Methods of making a cured fluoroelastomer from the curable composition are also disclosed.

  一种可固化组合物，包括具有第一溶解度参数的无定形过氧化物可固化含氟聚合物、具有第二溶解度参数的溶剂和过氧化物。无定形过氧化物可固化含氟聚合物的含量占可固化组合物重量的 60% 至 97.5%，溶剂的含量占可固化组合物重量的 1% 至 39%。第一溶解度参数减去第二溶解度参数的绝对值小于或等于 8.2 (MPa)1/2。溶剂的溶解度参数范围为 9.6 (MPa)1/2 至 26 (MPa)1/2。还公开了用可固化组合物制造固化氟橡胶的方法。
• PEROXIDE-CURABLE FLUOROPOLYMER COMPOSITION INCLUDING SOLVENT AND METHOD OF USING THE SAME
  申请人：3M Innovative Properties Company

  公开号：EP2914659B1

  公开（公告）日：2018-10-03
• COMPOSITE PARTICLES INCLUDING A FLUOROPOLYMER, METHODS OF MAKING, AND ARTICLES INCLUDING THE SAME
  申请人：3M Innovative Properties Company

  公开号：EP2935444B1

  公开（公告）日：2019-09-18