6-methacryloyloxyhexyl phosphonoacetate | 141451-39-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 6-methacryloyloxyhexyl phosphonoacetate
• 英文别名: [2-({6-[(2-Methylacryloyl)oxy]hexyl}oxy)-2-oxoethyl]phosphonic acid；[2-[6-(2-methylprop-2-enoyloxy)hexoxy]-2-oxoethyl]phosphonic acid
• CAS: 141451-39-0
• 化学式: C₁₂H₂₁O₇P
• 分子量: 308.268
• InChiKey: LZNOVPCVDYEFID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  110
• 氢给体数：
  2
• 氢受体数：
  7

文献信息

• Two paste-type glass ionomer cement
  申请人：Takano Satosi

  公开号：US20060247330A1

  公开（公告）日：2006-11-02

  An object of the present invention is to provide a paste-type cement composition which while retaining adhesion to tooth substance, biocompatibility, surface curability and fluorine sustained-releasability which are the characteristics derived from the conventional glass ionomer cement, reduces water sensitivity which is shortcoming of the conventional glass ionomer cement, enables simple mixing operation, does not adversely affect on the various properties of a cured cement depending on a difference in operators or a skill degree, and can afford various stable properties. There is provided a two paste-type glass ionomer cement comprising a resin-based paste containing a hydrophobic polymerizable monomer and a polymer of acidic group-containing polymerizable monomers which are insoluble to each other, and a water-based paste containing a hydrophilic polymerizable monomer and water which are soluble to each other, in which an acid reactive filler is contained in at least one of pastes.

  本发明的一个目的是提供一种浆糊型水泥组合物，该组合物在保持对牙齿物质的粘附性、生物相容性、表面可固化性和氟释放性这些传统玻璃离子水泥的特性的同时，减少了传统玻璃离子水泥的水敏感性这一缺点，实现了简单的混合操作，不会对已固化水泥的各种性质产生不利影响，不会受到操作者差异或技能水平的影响，并且可以提供各种稳定的性质。提供了一种双浆糊型玻璃离子水泥，包括一种含有疏水性可聚合单体和含有酸性基团可聚合单体聚合物的树脂基浆糊，这些单体在彼此之间不溶解，以及一种含有亲水性可聚合单体和水的水基浆糊，这些单体在彼此之间可溶解，其中至少有一个浆糊中含有酸反应填料。
• Camphorquinone Derivative Having Acylphosphine Oxide Group, Photopolymerization Catalyst And Photo/Chemical Polymerization Catalyst Containing The Same And Hardenable Composition Contaning The Same
  申请人：Ikemura Kunio

  公开号：US20090105361A1

  公开（公告）日：2009-04-23

  A compound that exhibits excellent color tone stability and physical properties as well as excellent photopolymerization activity over a wide region from near-ultraviolet to visible region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry; and a relevant photopolymerization initiator and hardenable composition. In particular, there is provided a novel camphorquinone derivative having an acylphosphine oxide group [—(C═O)—(P═O)<] in each molecule. Further, there is provided a photopolymerization initiator comprising the camphorquinone derivative having an acrylphosphine oxide group [—(C═O)—(P═O)<] in each molecule as an indispensable component, loaded with at least one member selected from among a polymerization accelerator, a photoacid generator, a photosensitizer and a (bis)acylphosphine oxide, and provided a hardenable composition comprising the initiator. The thus provided photopolymerization initiator and hardenable composition exhibit excellent color tone stability and physical properties as well as excellent photopolymeritzaion activity over an ultraviolet and visible wide wavelength region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry.

  提供了一种化合物，其具有出色的色调稳定性和物理性能，以及在近紫外到可见光区域内具有优异的光聚合活性，使得在环境光线下可以放松操作，因此在牙科领域和光聚合工业中可以找到广泛的应用；以及相关的光聚合引发剂和可硬化组合物。特别地，提供了一种新型的萜烯酮衍生物，其每个分子中都具有一个酰基膦氧化物基团[—(C═O)—(P═O)<]。此外，还提供了一种光聚合引发剂，其中包含具有丙烯酰膦氧化物基团[—(C═O)—(P═O)<]的萜烯酮衍生物作为不可或缺的组分，装载有至少一种从聚合促进剂、光酸发生剂、光敏剂和(双)酰基膦氧化物中选择的成员，并提供了一种包含引发剂的可硬化组合物。因此，所提供的光聚合引发剂和可硬化组合物在紫外和可见光宽波长区域内表现出优异的色调稳定性和物理性能，以及优异的光聚合活性，使得在环境光线下可以放松操作，因此在牙科领域和光聚合工业中可以找到广泛的应用。
• Two-paste type dental self-adhesive resin cement
  申请人：Kohro Yoshiaki

  公开号：US20100010115A1

  公开（公告）日：2010-01-14

  The present invention provides a dental self-adhesive resin cement having clinically-acceptable adherability for various adherends without pre-treatment with primers. Specifically, there is provided the dental self-adhesive composite resin cement comprising: (a) a radical polymerizable monomer, (b) a polymerizable monomer having a phosphonic acid group and/or a phosphoric acid ester group, (c) a polymerizable monomer having a dibasic acid carboxyl group, (d) a filler, and (e) a polymerization catalyst.

  本发明提供了一种牙科自粘树脂水泥，具有临床可接受的粘附性，可在不使用底漆的情况下适用于各种被粘合物。具体而言，提供了一种牙科自粘复合树脂水泥，包括：（a）一种自由基聚合单体，（b）一种具有磷酸基和/或磷酸酯基的聚合单体，（c）一种具有二元酸羧基的聚合单体，（d）一种填料，和（e）一种聚合催化剂。
• Dental Composite Resin Cement, Dental Primer and Dental Adhesive Kit Containing Them
  申请人：Torii Keisuke

  公开号：US20090048366A1

  公开（公告）日：2009-02-19

  The present invention provides a dental resin cement which is excellent in a mechanical strength, workability and storage stability, and a dental primer which significantly improves adhesiveness of the dental resin cement both to enamel and dentin of a tooth. According to the present invention, a salt of barbituric acid is used as a polymerization initiator in the dual-cure two-paste type dental resin cement being excellent in workability and storage stability to improve the storage stability, and a primer containing barbituric acid and amine is applied to a surface of a tooth to significantly improve adhesiveness of the dental resin cement both to enamel and dentin of teeth.

  本发明提供了一种牙科树脂水泥，具有优异的机械强度、可操作性和储存稳定性，以及一种显著改善牙科树脂水泥对牙齿釉质和牙本质的粘附性的牙科底漆。根据本发明，在双重固化两种糊状型牙科树脂水泥中，使用戊二酰脲酸盐作为聚合引发剂，以提高储存稳定性，并且在牙齿表面涂抹含有戊二酰脲酸和胺的底漆，以显著提高牙科树脂水泥对牙齿釉质和牙本质的粘附性。
• ADHESIVE COMPOSITION FOR DENTAL USE
  申请人：Tokuyama Dental Corporation

  公开号：EP2123246A1

  公开（公告）日：2009-11-25

  An adhesive composition for dental use exhibiting acidic property, including a mixture of a polymerizable monomer component (A) containing a phosphoric acid-type polymerizable monomer having an acidic group derived from phosphoric acid, and a multivalent metal ion-releasing component (B), wherein the multivalent metal ion-releasing component (B) is capable of releasing at least earth metal ions, and in the composition, earth metal ions stemming from the component (B) are present together with the phosphoric acid-type polymerizable monomer in such an amount that a total valency ratio (RE) defined by the following formula (1) is in a range of 0.2 to 3.0. The adhesive composition is capable of strongly adhering and fixing a composite resin or a prosthetic material to a tooth for extended periods of time maintaining stability. RE=TVE/TVA wherein TVE is a total valency of the earth metal ions contained in said composition, and TVA is a total valency of the acidic groups of the phosphoric acid-type polymerizable monomer contained in said composition.

  一种具有酸性的牙科用粘合剂组合物，包括含有磷酸型可聚合单体的可聚合单体组分（A）和多价金属离子释放组分（B）的混合物、其中，多价金属离子释放组分（B）至少能释放出土金属离子，在组合物中，由组分（B）产生的土金属离子与磷酸型可聚合单体一起存在，其含量为下式（1）定义的总价比（RE）在 0.2 至 3.0。该粘合剂组合物能够长时间将复合树脂或修复材料牢固地粘附和固定在牙齿上，并保持稳定。RE=TVE/TVA 其中 TVE 为所述组合物中所含土金属离子的总价，而 TVA 是所述组合物所含磷酸型可聚合单体的酸性基团的总价。