Henicos-2-enamide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Henicos-2-enamide
• 英文别名: henicos-2-enamide
• 化学式: C₂₁H₄₁NO
• 分子量: 323.6
• InChiKey: ZYHFGJHFDUQXEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  23
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Fluoropolymer
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP2045276A1

  公开（公告）日：2009-04-08

  Various fluoropolymers have been proposed for imparting oil and water repellency to leather. Commonly, these fluoropolymers are amphiphilic; i.e., they are made from at least one monomer which is hydrophobic and at least one monomer which is hydrophilic. The present invention identifies and remedies disadvantages associated with the ability of amphiphilic fluoropolymers to impart oil and water repellency to leather. Contrary to conventional thinking, it has now been discovered that the incorporation of hydrophilic groups in a fluoropolymer undesirably reduces its ability to impart water resistance to leather. Correspondingly, it has also been discovered that a fluoropolymer incorporating fewer or no hydrophilic groups imparts superior oil and water repellency to leather when compared to fluoropolymers incorporating more hydrophilic groups. Therefore, this invention provides fluoropolymers which incorporate reduced levels of hydrophilic groups.

  人们提出了各种含氟聚合物，用于赋予皮革拒油性和拒水性。通常，这些含氟聚合物都是两亲性的；也就是说，它们是由至少一种疏水性单体和至少一种亲水性单体制成的。本发明发现并解决了与两亲性含氟聚合物赋予皮革防油防水性能有关的缺点。与传统想法相反，现在人们发现，在含氟聚合物中加入亲水基团会降低其赋予皮革防水性的能力，这是不可取的。相应地，人们还发现，与含有较多亲水基团的含氟聚合物相比，含有较少亲水基团或不含亲水基团的含氟聚合物可赋予皮革优异的憎油性和憎水性。因此，本发明提供了含有较少亲水基团的含氟聚合物。
• Polysaccharide and/or polypeptide based graft polymers as synthetic tannins
  申请人：LANXESS Deutschland GmbH

  公开号：EP2824125A2

  公开（公告）日：2015-01-14

  Process for the manufacturing of graft polymers of polysaccharides or polypeptides or its respective derivatives, obtainable by free radical induced co-polymerization of A) a monomer selected from or a monomer mixture of (a) from 20 to 100% by weight of acrylic acid or methacrylic acid or of a mixture thereof or of the alkali metal, alkaline earth metal or ammonium salts thereof, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least 2 ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of either B1) polysaccharides, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidized hydrolytically degraded or oxidized enzymatically degraded polysaccharides, or such chemically modified degraded products, chemically modified mono-, oligo- or polysaccharides or mixtures of the stated compounds or B2) polypeptides, hydrolytically or enzymatically degraded and optionally chemically modified polypeptides or mixtures of the stated compounds in a weight ratio A:(B1 or B2) of from 1:99 to 18:82, wherein the components of the monomers of A) are added to B1) or B2) in an inert solvent at a temperature of 40 to 150 °C in the presence of a free radical-forming initiator, characterized in that at least 50% of the radical-forming initiator are with the component B1) or B2) before the addition of the monomers A) and the rest is added together with the monomers of A).

  多糖或多肽接枝聚合物或其各自衍生物的生产工艺，可通过以下物质的自由基诱导共聚合获得 A) 以下单体或单体混合物 (a) 重量百分比为 20%至 100%的丙烯酸或甲基丙烯酸或其混合物或其碱金属盐、碱土金属盐或铵盐、 (b) 0 至 80%（以重量計）可與單體(a)共聚的其他單乙烯不飽和單體，及 (c) 0-5%（按重量计）分子中至少有 2 个乙烯不饱和非共轭双键的单体、 在以下任一种物质存在的情况下 B1) 多糖，氧化、水解或酶降解多糖，氧化水解降解或氧化酶降解多糖，或此类化学修饰降解产物，化学修饰单糖、寡糖或多糖，或上述化合物的混合物，或 B2) 多肽、经水解或酶降解的多肽或经化学修饰的多肽或上述化合物的混合物 A:(B1 或 B2) 的重量比为 1:99 至 18:82、 其中 A)单体的组分在 40 至 150 °C的温度下，在惰性溶剂中，在自由基形成引发剂的存在下加入到 B1)或 B2)中，其特征在于在加入 A)单体之前，至少 50%的自由基形成引发剂与 B1)或 B2)组分在一起，其余的与 A)单体一起加入。
• Use of copolymers of monoethylenically unsaturated carboxylic acids as solubilizers
  申请人：——

  公开号：US20020037318A1

  公开（公告）日：2002-03-28

  The invention relates to the use of copolymers comprising a) 82 to 99.9 mol % of at least one monoethylenically unsaturated C 3 -C 8 -carboxylic acid; b) 0.1 to 18 mol % of at least one monomer selected from the group b 1 ) N-C 8 -C 30 -alkyl-substituted amides of monoethylenically unsaturated C 3 -C 8 -carboxylic acids, b 2 ) N,N-C 8 -C 30 -dialkyl-substituted amides of mono-ethylenically unsaturated C 3 -C 8 -carboxylic acids, b 3 ) C 8 -C 30 -alkyl esters of monoethylenically unsaturated C 3 -C 8 -carboxylic acids; c) 0 to 17.9 mol % of at least one monomer selected from the group of c 1 ) vinyl esters of aliphatic C 8 -C 30 -carboxylic acids, c 2 ) C 8 -C 30 -alkylvinyl ethers, the mol % data for the individual components adding up to 100%, as solubilizer.

  本发明涉及共聚物的使用，共聚物包括 a) 82 至 99.9 摩尔%的至少一种单乙烯不饱和 C 3 -C 8 -羧酸； b) 0.1 至 18 摩尔%的至少一种选自以下组别的单体 b 1 ) N-C 8 -C 30 -烷基取代的单乙烯基不饱和 C 3 -C 8 -羧酸的烷基取代酰胺、 b 2 ）N,N-C 8 -C 30 -二烷基取代的单乙烯基不饱和 C 3 -C 8 -羧酸的二烷基取代酰胺、 b 3 )C 8 -C 30 -单乙烯基不饱和 C 3 -C 8 -羧酸的烷基酯； c) 0 至 17.9 摩尔%的至少一种选自以下组别的单体 c 1 ) 脂肪族 C 8 -C 30 -羧酸的乙烯基酯、 c 2 )C 8 -C 30 -烷基乙烯基醚、 作为增溶剂，各成分的摩尔百分比数据相加为 100%。
• POLYMERS DERIVED FROM N-VINYL FORMAMIDE, VINYL AMIDES OR ACRYLAMIDES, AND REACTION SOLVENT, AND THE USES THEREOF
  申请人：Isp Investments Inc.

  公开号：EP2346909B1

  公开（公告）日：2018-05-16
• POLYSACCHARIDE AND/OR POLYPEPTIDE BASED GRAFT POLYMERS AS SYNTHETIC TANNINS
  申请人：LANXESS Deutschland GmbH

  公开号：EP2714756B1

  公开（公告）日：2018-05-02