9-acetoxymethyl-10-methylanthracene | 31688-71-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-acetoxymethyl-10-methylanthracene
• 英文别名: 9-Acetoxymethyl-10-methylanthracen；9-Methyl-10-acetoxymethyl-anthracen；acetic acid-(10-methyl-[9]anthrylmethyl ester)；Essigsaeure-(10-methyl-[9]anthrylmethylester)；9-Anthracenemethanol, 10-methyl-, acetate；(10-methylanthracen-9-yl)methyl acetate
• CAS: 31688-71-8
• 化学式: C₁₈H₁₆O₂
• 分子量: 264.324
• InChiKey: ONKVAYYBUYZODD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-acetoxymethyl-10-methylanthracene 在 N-溴代丁二酰亚胺(NBS) 、 18-冠醚-6 、 偶氮二异丁腈 、 potassium carbonate 、 正丁胺 作用下， 以 四氢呋喃 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 30.0h， 生成
  参考文献：
  名称：

  Construction of divergent anthracene arrays within dendritic frameworks

  摘要：

  This publication presents simple methodologies for construction of divergent anthracene arrays either within structural interior or at peripheral positions of dendritic frameworks. The synthetic approaches employed multiple coupling reactions between two types of 10-functionalized 9-anthryl chlorides and two types of polyphenolic linkers, resulting in four types of dendritic architectures. Successful implementation of the syntheses was confirmed by a range of spectroscopies along with elemental analyses and size exclusion chromatography studies. The resulting dendritic molecules showed a range Of Solubilities in chloroform fairly affected by the dendritic backbone structures. Fluorescence spectroscopic experiments of the multichromophoric dendritic systems indicated pronounced energy delocalization functionalities via an energy migration within the branched molecular frameworks as expressed in reduced fluorescence quantum yields and complex emission decay profiles. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.01.024

文献信息

• Construction of divergent anthracene arrays within dendritic frameworks
  作者：Masaki Takahashi、Hironao Morimoto、Yousuke Suzuki、Mitsuji Yamashita、Hideki Kawai、Yoshihisa Sei、Kentaro Yamaguchi

  DOI：10.1016/j.tet.2006.01.024

  日期：2006.3

  This publication presents simple methodologies for construction of divergent anthracene arrays either within structural interior or at peripheral positions of dendritic frameworks. The synthetic approaches employed multiple coupling reactions between two types of 10-functionalized 9-anthryl chlorides and two types of polyphenolic linkers, resulting in four types of dendritic architectures. Successful implementation of the syntheses was confirmed by a range of spectroscopies along with elemental analyses and size exclusion chromatography studies. The resulting dendritic molecules showed a range Of Solubilities in chloroform fairly affected by the dendritic backbone structures. Fluorescence spectroscopic experiments of the multichromophoric dendritic systems indicated pronounced energy delocalization functionalities via an energy migration within the branched molecular frameworks as expressed in reduced fluorescence quantum yields and complex emission decay profiles. (c) 2006 Elsevier Ltd. All rights reserved.