3-maleimidophenylacetylene | 105280-01-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: 3-maleimidophenylacetylene
• 英文别名: 1H-Pyrrole-2,5-dione, 1-(3-ethynylphenyl)-；1-(3-ethynylphenyl)pyrrole-2,5-dione
• CAS: 105280-01-1
• 化学式: C₁₂H₇NO₂
• 分子量: 197.193
• InChiKey: ZZZLOLMQTUYXDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-maleimidophenylacetylene 、 4,4'-二氨基二苯甲烷 以100%的产率得到
  参考文献：
  名称：

  HERGENROTHER, PAUL M.;CONNELL, JOHN W.;HAVENS, STEPHEN J.

  摘要：

  DOI：
• 作为产物：
  描述：

  3-氨基苯乙炔 、 马来酸酐 生成 3-maleimidophenylacetylene
  参考文献：
  名称：

  KLEMARCZYK, PHILIP

  摘要：

  DOI：

文献信息

• N-(3-ethynylphenyl)maleimide
  申请人：The United States of America as represented by the Administrator of the

  公开号：US04937356A1

  公开（公告）日：1990-06-26

  Acetylene terminated aspartimides are prepared using two methods. In the first, an amino-substituted aromatic acetylene is reacted with an aromatic bismaleimide in a solvent of glacial acetic acid and/or m-cresol. In the second method, an aromatic diamine is reacted with an ethynyl containing maleimide, such as N-(3-ethynylphenyl)maleimide, in a solvent of glacial acetic acid and/or m-cresol. In addition, acetylene terminated aspartimides are blended with various acetylene terminated oligomers and polymers to yield composite materials exhibiting improved mechanical properties.

  用两种方法制备乙炔端基的天冬氨酸酰胺。第一种方法是将含氨基取代的芳香炔与含双马来酰亚胺的芳香化合物在冰乙酸和/或间甲酚的溶剂中反应。第二种方法是将芳香二胺与含乙炔的马来酰亚胺（如N-(3-乙炔基苯基)马来酰亚胺）在冰乙酸和/或间甲酚的溶剂中反应。此外，将乙炔端基的天冬氨酸酰胺与各种乙炔端基的寡聚物和聚合物混合，可以得到具有改善机械性能的复合材料。
• Acetylene terminated aspartimides and resins therefrom
  申请人：The United States of America as represented by the Administrator of the

  公开号：US04889912A1

  公开（公告）日：1989-12-26

  Acetylene terminated aspartimides are prepared using two methods. In the first, an amino-substituted aromatic acetylene is reacted with an aromatic bismaleimide in a solvent of glacial acetic acid and/or m-c=resol. In the second method, an aromatic diamine is reacted with an ethynyl containing maleimide, such as N-(3-ethynylphenyl) maleimide, in a solvent of glacial acetic acid and/or m-cresol. In addition, acetylene terminated aspartimides are blended with various acetylene terminated oligomers and polymers to yield composite materials exhibiting improved mechanical properties.

  乙炔末端的天冬氨酸酰胺可以通过两种方法制备。第一种方法是，将氨基取代的芳香乙炔与芳香双马来酰亚胺在冰乙酸和/或m-甲酚溶剂中反应。第二种方法是，将芳香二胺与含有乙炔的马来酰亚胺（例如N-（3-乙炔基苯基）马来酰亚胺）在冰乙酸和/或m-甲酚溶剂中反应。此外，乙炔末端的天冬氨酸酰胺与各种乙炔末端的寡聚物和聚合物混合，以产生具有改善机械性能的复合材料。
• Phosphine-catalyzed Rauhut–Currier reaction of γ-alkyl allenoate and subsequent trapping using the Diels–Alder reaction
  作者：Juan Zhang、Wei Hao、Ying Chen、Zhen Wang、Jinzhong Yao、Weijun Yao

  DOI：10.1039/d3cc03151a

  日期：——

  We have disclosed a Rauhut–Currier reaction of γ-alkyl-substituted allenoate, catalyzed by L-valine-derived amide phosphine, to form trisubstitued allenoate, which was trapped by maleimide or DMAD via the Diels–Alder reaction. Exo-bicyclic succinimide derivatives including three continuous stereocenters with an exo-carbon–carbon double bound were constructed in up to quantitative yields with high stereospecificity

  我们已经公开了γ-烷基取代的联烯酸酯的Rauhut-Currier反应，由L-缬氨酸衍生的酰胺膦催化，形成三取代的联烯酸酯，其通过Diels-Alder反应被马来酰亚胺或DMAD捕获。外型双环琥珀酰亚胺衍生物包括具有外型碳-碳双键的三个连续立体中心，以高达定量的产率和高立体特异性构建。
• Novel siloxane maleimides
  申请人：LOCTITE CORPORATION

  公开号：EP0283204A2

  公开（公告）日：1988-09-21

  Bis-maleimide compounds of the formula: where Rʹ is an alkenylene or alkylene group; the Rʺ groups are independently hydrocarbon or halohydrocarbon groups; and n is an integer, are hydrolytically stable compounds which may be thermally cured, or co-cured with other radically cureable monomers, to provide crosslinked polymer with good thermal properties. Compounds of the formula where n is above about 9 can be used as additives for radically cureable silicone formulations.

  式中的双马来酰亚胺化合物：其中 Rʹ 是烯基或亚烷基；Rʺ 基团独立地是烃基或卤代烃基；n 是整数，是水解稳定的化合物，可以热固化，或与其他可辐射固化的单体共固化，以提供具有良好热性能的交联聚合物。 式中 n 大于约 9 的化合物可用作可辐射固化有机硅配方的添加剂。
• US4806608A
  申请人：——

  公开号：US4806608A

  公开（公告）日：1989-02-21