The present invention relates to a polyimide copolymer used in a precursor of heat resistant adhesive and methods for preparing the same, and more particularly, to a polyamic acid copolymer and methods for preparing the same obtained by controlling a polymerization degree of the tetracarboxylic acid dianhydride and aromatic diamine. The present invention also comprises a polyimide copolymer obtained by curing the polyamic acid copolymer, and methods for preparing the same. The present invention also provides a heat resistant adhesive composition comprising the polyamic acid copolymer and the polyimide copolymer, and a semiconductor device using the same. The polyamic acid copolymer used in a precursor and polyimide copolymer obtained therefrom of the present invention has superior adhesion strength and simultaneously satisfies physical properties like high heat resistance and low water absorption rate, etc. and thus it can be effectively adhered parts of semiconductor devices, etc.
本发明涉及一种用于耐热粘合剂前体的聚
酰亚胺共聚物及其制备方法,更具体地说,涉及一种通过控制四
羧酸二酐和芳香族二胺的聚合度而获得的聚酰胺共聚物及其制备方法。本发明还包括一种通过固化聚酰胺共聚物而获得的聚
酰亚胺共聚物,以及制备该共聚物的方法。本发明还提供了一种由聚酰胺共聚物和聚
酰亚胺共聚物组成的耐热粘合剂组合物,以及使用该组合物的半导体器件。本发明的前体中使用的聚酰胺共聚物和由此获得的聚
酰亚胺共聚物具有优异的粘合强度,同时满足高耐热性和低吸
水率等物理性能,因此可以有效地粘合半导体设备等的部件。